High Sensitivity Detection of Copper Ions in Oysters Based on the Fluorescence Property of Cadmium Selenide Quantum Dots

Cadmium selenide (CdSe) quantum dots (QDs) were synthesized by water phase synthesis method using 3-mercaptopropionic acid (3-MPA) as a stabilizer, and they were applied to the detection of copper ions (Cu2+). The results showed that CdSe QDs have excellent selectivity and sensitivity toward Cu2+. The fluorescence intensity of CdSe QDs decreased with the increase of Cu2+concentration. The linear range was from 30 nM to 3 μM, and the detection limit was 30 nM. Furthermore, CdSe QDs were used for detecting the concentration of Cu2+in oysters. The content of Cu2+was 40.91 mg/kg, which was close to the one measured via flame atomic absorption spectrometry (FAAS), and the relative error was 1.81%. Therefore, CdSe QDs have a wide application prospect in the rapid detection of copper ions in food.