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Facile, low-cost, and large-scale synthesis of CsPbBr3 nanorods at room-temperature with 86 % photoluminescence quantum yield

Journal 2019 · IF 3.355 · 发表于 2019 年 12 月 9 日
作者: Jun Cui,Fanfan Xu,Quan Dong,Junjie Jia,Lili Liu,Shuifu Liu,Fengli Yang,Xinyu Ye
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摘要

All inorganic cesium lead halide perovskite nanocrystals have attracted widespread attention due to their excellent optical properties. However, large-scale synthesis of high photoluminescence quantum yield (PLQY) CsPbBr 3 nanorods (NRs) is still challenging. Herein, we report a facile, low-cost and large-scale synthesis of CsPbBr 3 NRs with 86 % PLQY at room temperature, in which the employment of acetic acid as precursor solvent promoted the concentrations of Cs + and Pb 2+ in the precursor solution and dominated the formation of CsPbBr 3 NRs. The synthesized CsPbBr 3 NRs with an average width of around 8 nm and average lengths of 18–30 nm have an excellent narrow-band (FWHM = 17 nm) green emission peaked at 517 nm.