Carbon-based nanomaterials mediated adsorption and photodegradation of typical organic contaminants in aqueous fulvic acid solution

View large Download slide View large Download slide Close modal In this work, the formation of carbon-based nanomaterials–fulvic acid (CNMs-FA) composites and their capacities for the adsorption and photodegradation of typical organic contaminants in aqueous solutions were investigated. The results suggested that the formation of CNMs-FA composites was dominated by adsorbing FA on CNMs via the physisorption process, which fit the pseudo-first-order kinetic model and the Langmuir isotherm model. The formed CNMs-FA composites were characterized by using the Brunauer–Emmett–Teller, scanning electron microscopy, and infrared spectroscopy techniques and further applied for examining their effects on the adsorption and photodegradation of selected organic contaminants in aqueous solutions. The adsorption of organic contaminants on CNMs-FA composites is mainly involved in hydrogen bonding and electrostatic interactions between organic contaminants and FA species adhering to CNMs. In addition, the CNMs-FA composites are able to promote the photosensitive degradation of organic contaminants due to the photogenerated reactive species including ROS and CNMs-3FA* under sunlight irradiation. This study provided a deeper and more comprehensive understanding of the environmental behavior of CNMs in real natural surface water and clarified the underlying mechanisms. Carbon-based nanomaterials (CNMs) preferentially adsorb fulvic acid to form CNMs-FA in environmental water. Adsorption of FA on CNMs fits pseudo-first-order kinetic and Langmuir isotherm models. CNMs-FA can adsorb organic pollutants via hydrogen bonding and electrostatic interactions. CNMs-FA promotes the photodegradation of organic pollutants under sunlight irradiation.