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Ecofriendly β-N-butyl amino propionic acid as green corrosion inhibitor for N80 steel in CO2-saturated brine water

Journal 2024 · IF 3.5 · 59(8): 3604-3623 · 发表于 2024 年 2 月 9 日
作者: Wang Xintong,Yang Jiang,Chen Xu,Wang Yefei,Yang Zhen,Ding Wei
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摘要

To mitigate CO 2 corrosion in the oil and gas industry, a green non-toxic β -N-butyl amino propionic acid (BAA) was synthesized using a low-energy and zero-waste one-pot method. The effectiveness of BAA as a corrosion inhibitor for N80 steel in CO 2 -saturated brine water was investigated through experimental measurements and theoretical modeling. The results demonstrate that BAA functions as an effective mixed-type corrosion inhibitor. BAA molecules interact with F (1 1 0) with the–COO– and–NH 2 + -moiety in the hydrophilic head group, and the hydrophobic groups are adsorbed on the steel surface in a configuration 45° away from the steel surface. The adsorption is a mixture of physical and chemical processes and is consistent with the Langmuir isothermal adsorption formula. When the concentration is greater than 50 ppm, a complete corrosion inhibitor film with high hydrophobicity can be adsorbed on the steel surface, which can effectively impede the diffusion of corrosive species from brine to the steel surface. Graphical abstract