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An efficient synthetic strategy for high performance polysulfone: ionic liquid/zwitterion as reaction medium

Journal 2012 · IF 6.32 · 14(11): 3204-3210 · 发表于 2012 年 9 月 12 日
作者: Jing Wang,Zhengping Liu
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摘要

Herein we report the novel use of ionic liquid (IL)/zwitterion (ZI) as a reaction medium for the efficient synthesis of polysulfones (PSFs) with high molecular weight and high yield. The results showed that ZI can significantly improve the solubility of 2,2-bis(4-hydroxyphenyl) propane (bisphenol A), and an intermediate sulphonic-type IL with high acidity was formed by ZI and bisphenol A, resulting in 80% reduction in dehydration time compared with conventional methods.