Efficient and stable TiO2/Sb2S3 planar solar cells from absorber crystallization and Se-atmosphere annealing

Inorganic Sb 2 S 3 thin film solar cells show wide application prospects in low cost, non-toxicity and high stability solar cells comparing with well-developed CIGS , CdTe and organohalide perovskite materials. The present work successfully fabricated Sb 2 S 3 film utilizing rapid thermal evaporation (RTE) method. By optimizing the crystal growth technique, smooth and non-pinhole Sb 2 S 3 film was deposited on compact TiO 2 substrate. The corresponding planar TiO 2 /Sb 2 S 3 solar cells without hole transport material (HTM) assistance achieved an efficiency of 2.5%. To eliminate S-shape J-V curves and improve the fill factor, the as-deposited Sb 2 S 3 film was further annealed in selenium atmosphere. The efficiency and fill factor of Se-atmosphere annealed Sb 2 S 3 devices were improved to 3.2% and 55%, respectively. The device improvement mechanism of Se-annealing process were systematically illustrated by cryogenic measurements, impedance analysis and capacitance-voltage characterizations. The post-annealing could help to improve junction quality, passivate absorber defects and decrease back contact barrier. The Se-atmosphere annealed Sb 2 S 3 devices could stand continuous one sun illumination for 400 h and the efficiency was almost the same. After storing in air for six months, the average efficiencies still hold more than 90% of initial value . The present developed environment-friendly stable devices and efficient treatment technique were expected to enrich the research of thin film solar cell.