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Selective recognition of “solvent” molecules in solution and the solid state by 1,4-dimethoxypillar[5]arene driven by attractive forces

Journal 2013 · IF 2.966 · 38(2): 845-851 · 发表于 2013 年 12 月 10 日
作者: Li-Li Tan,Yumo Zhang,Bao Li,Kai Wang,Sean Xiao-An Zhang,Yanchun Tao,Ying-Wei Yang
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摘要

Highly selective binding of “solvent” molecules by 1,4-dimethoxypillar[5]arene (DMP[5]A) and their host–guest complexation in solution and the solid state have been investigated by multiple methods. Enthalpy changes and the size-fit effect play an important role in the high selectivity.