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Layered array Al2O3-LuAG: Ce composite ceramic phosphors for high-brightness display

Journal 2022 · IF 6.364 · 发表于 2022 年 12 月 19 日
作者: Qi Zhang,Ruilin Zheng,Haiyang Wu,Guoyu Zhao,Jianyong Ding,Kehan Yu,Wei Wei
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摘要

Thermally robust and efficient composite ceramic phosphors (CCPs) combined both the merits of matrix and phosphor have received growing interests. However, high matrix content (e.g., Al 2 O 3 >40 wt%) brings diluted activated ion concentration and dropped photoluminescence (PL) quantum yield (QY). Here, a novel layered array Al 2 O 3 -LuAG: Ce CCP, where Al 2 O 3 and LuAG: Ce thin layers (10–250 µm) are alternately arranged, was presented. Owing to the special structure, thermal phonons and photons are respectively routed into Al 2 O 3 layers and LuAG: Ce layers, which weakens the influence of Al 2 O 3 and heat accumulation on PL properties. Consequently, it exhibits high PLQY (84.1%) and good thermal conductivity (17.1 W·m −1 ·K −1 ). When it is irradiated under high-power density (27.2 W·mm −2 ) blue laser , the luminous efficiency and lumen-density are promoted to 220 lm·W −1 and 5994 lm·mm −2 , respectively. This work provides a promising new microstructure in developing novel phosphor converters for high-brightness laser phosphor display.