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Orange-red persistent luminescence in Mn2+-Doped Sr3Y2Ge3O12 films for dynamic anti-counterfeiting

Journal 2023 · IF 5.2 · 发表于 2023 年 8 月 3 日
作者: Chenxi Guo,Weikang Peng,Dongxin Shi,Fengfeng Li,Mingxi Zhang,Junrong Chen,Jindi Feng
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摘要

The research focus in the field of anti-counterfeiting has shifted toward the secure luminescent label technology, which has gained prominence. The exceptional luminescence properties of persistent luminescence materials are important in the achievement of effective anti-counterfeiting measures. It is in this context that Sr 3 Y 2 Ge 3 O 12 can serve as an excellent matrix material . In this study, it is found that Sr 3 Y 2 Ge 3 O 12 : 4.00% Mn 2+ exhibits a luminescence intensity, persistence time, and stability that meet the practical requirements for applications. It is shown that the fabricated persistent luminescence film can be used in anti-counterfeiting applications, thereby, demonstrating the possibility to broaden the application scope of persistent luminescence materials. An emission band centered at 634 nm and a high-energy inflection point at 578 nm are observed in the samples excited at 260 nm. Fluorescence emission at 634 nm is also achieved through X-ray excitation. Through thermoluminescence , photoluminescence , and phosphorescence spectroscopy, a comprehensive investigation of the trap characteristics and inherent mechanisms of the long persistent phosphorescence has been conducted. The novel orange-red Sr 3 Y 2 Ge 3 O 12 : Mn 2+ phosphor is extensively examined.