Novel multi-component hybrids through double luminescent lanthanide unit functionalized zeolite L and titania

Zeolite L (ZL) is functionalized with inside-outside double modification paths (gas disperse (“ship in bottle”) and covalently grafting) with two kinds of luminescent lanthanide species (Tb 3+ complex of acetylacetone (AA), lanthanide polyoxometalate (NaLnW 10 O 36 ·32H 2 O, abbreviated as LnW 10 , Ln   =   Eu, Tb)) to prepare the hybrid materials. The prepared hybrids show the red and green luminescence, which provides a useful path to obtain multi-component lanthanide hybrids.