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Simultaneously accomplishing selective catalytic reduction of NO and catalytic oxidation of CO in a catalyst coupling system

Journal 2023 · IF 7.4 · 发表于 2023 年 12 月 17 日
作者: Xue Li,Xiaolong Liu,Hao Tang,Yang Zou,Wanglai Cen,Tingyu Zhu
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摘要

Considering that nitrogen oxides (NO x ) and carbon monoxide (CO) usually meantime exist in industrial flue gas, it is meaningful to develop a collaborative control technology for the simultaneous purification of NO x and CO. In this work, the catalysts xCu-1V-5W/Ti were evaluated in the simultaneously selective catalytic reduction by NH 3 (NH 3 -SCR) and CO oxidation . The introduction of CuO provided the active sites for the oxidation of CO, while inhibited the NH 3 -SCR process and facilitated the generation of N 2 O by-product at high temperature. Accordingly, a catalyst coupling system was designed by employing 1V-5W/Ti and 2Cu-1V-5W/Ti catalysts in one reactor, and high NO conversion (>90 %) and CO removal efficiency (>80 %) could be simultaneously realized within 350–500 °C. This work would provide valuable insights for achieving simultaneous removal of NO x and CO using the catalyst coupling method.