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Improvement the near-infrared luminescence properties of double perovskite phosphor La(Mg0.5Sn0.5In0.5Sc0.5)0.5O3:Cr3+ via co-doping Yb3+

Journal 2022 · IF 5.532 · 49(4): 6246-6253 · 发表于 2022 年 11 月 18 日
作者: Jingxin Li,WenYan Zhang,XueFang Wang,RunQiu Peng,BingKai Gao,Qian Wu,Zicai Zhang,Zhijun Wang
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摘要

In recent years, the broadband near-infrared (NIR) spectroscopy technology has been widely used in the field of nondestructive testing . However, these existing NIR phosphors showed relatively short emission wavelengths , narrower half-maximum full-width (FWHM), and narrower half-peak widths, importantly, few phosphors presented the emission from 950 nm to 1100 nm. In order to solve these problems, the Yb 3+ /Cr 3+ ions codoped La(Mg 0.5 Sn 0.5 In 0.5 Sc 0.5 ) 0.5 O 3 (LMSIS) was synthesized by the solid-state method, and the emission spectrum of LMSIS:Cr 3+ can be extended to the NIR long-wave region due to the energy transfer of Yb 3+ and Cr 3+ , and the thermal stability of the phosphor can be improved due to the inherent temperature stability of the Yb 3+ f-f transition. The NIR phosphor converted light emitting diodes (pc-LEDs) were fabricated by combining the LMSIS:0.003Cr 3+ , 0.0015Yb 3+ with blue LED chip, which can be expected to be used in the field of broadband near-infrared non-destructive detection.