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Synthesis and electrochemical performance of WS2 nanosheet for thermal batteries

Journal 2019 · IF 3.019 · 发表于 2019 年 4 月 9 日
作者: Shengnan Guo,Hao Guo,Xueying Wang,Yongping Zhu,Ming Yang,Qing Zhang,Ying Chu,Jianyong Wang
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摘要

Cathode materials that have better thermal stability, larger specific capacity and higher conductivity can efficiently improve the electrochemical performance of the batteries. In this work, we synthesized tungsten disulfide (WS 2 ) nanosheet and investigated its applicability as cathode material for thermal battery. The WS 2 is thermally stable up to 1200 °C. The open-circuit voltage is 1.43 V versus Li-B anode. At a current density of 150 mA cm −2 , the Li-B/WS 2 single cell exhibits a specific capacity of 334.7 mA h g −1 with a cut-off voltage of 1.0 V. The end discharge products are proved to be W and Li 2 S. This work provides a beginning for further applying WS 2 as a promising cathode material for long-life thermal batteries.