Stabilizing Na3SbS4/Na interface by rational design via Cl doping and aqueous processing

Solution-synthesis method is attractive for solid electrolytes because it is a facile and scalable process to be used to permeate electrodes and to construct a thin electrolyte coating layer on active materials. In this work, we report Cl-doped Na 3 SbS 4 prepared via aqueous-solution approach. Besides decent ionic conductivity , the aqueous-solution approached electrolyte demonstrates an improved interfacial stability toward Na metal compared to the solid-state sintered one because of the residual hydrate, nanosized microstructure, and Cl incorporation. All-solid-state batteries using the solution-prepared electrolytes have enhanced cycling performance, though the performance still needs to be further improved.