Effects of CoO and Bi2O3 single/dual sintering aids doping on structure and properties of Ce0.8Nd0.2O1.9

Nd 0.2 Ce 0.8 O 3-δ (NDC) is one of the most common solid electrolyte materials used in solid oxide fuel cells (SOFCs). However, the densification temperature of NDC electrolyte is above 1400 °C. In this work, Bi 2 O 3 and CoO sintering aids were individually or synergistically added to Nd 0.2 Ce 0.8 O 3-δ (NDC) electrolytes through the sol-gel method to lower its sintering temperature . Effects of Bi 2 O 3 -CoO dual sintering aid on the sintering behavior, phase composition, microstructure, and electrochemical properties of NDC electrolyte were all investigated. The data revealed that Bi 2 O 3 -CoO dual-sintering aid doped-NDC (labeled as NDC-CB) possessed high density and superior conductivity at low temperatures, better than that of Bi 2 O 3 or CoO single sintering aid. NDC electrolyte doped with Bi 2 O 3 -CoO dual-sintering aid achieved highest relative density of 95.3% at 1100 °C and total conductivity of 5.765 × 10 -2  S cm -1 at 800 °C. Furthermore, NDC-CB displayed excellent physical and chemical compatibility with La 0.6 Sr 0.4 Co 0.8 Fe 0.2 O 3-δ (LSCF) cathode and NiO-NDC anode. Oxygen reduction reaction at LSCF/NDC-CB interface was improved by about 40% when compared to NDC. In sum, Bi 2 O 3 -CoO looks promising as dual-sintering additive for lowing sintering temperature and increasing electrical conductivity of NDC. Therefore, NDC-CB might be potential electrolyte for future intermediate-temperature solid oxide fuel cells (IT-SOFCs).