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Equilibrium solubility of sodium 2-naphthalenesulfonate in binary (sodium chloride + water), (sodium sulfate + water), and (ethanol + water) solvent mixtures at temperatures from (278.15 to 323.15) K

Journal 2014 · IF 2.423 · 发表于 2014 年 11 月 26 日
作者: Rongrong Li,Hao Chen,Huayue Zhu,Ru Jiang,Stephen Louis Romano,Xiaoying Chen,Deman Han
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摘要

The equilibrium solubility of sodium 2-naphthalenesulfonate in binary (sodium chloride   +   water), (sodium sulfate   +   water), and (ethanol   +   water) solvent mixtures was measured at elevated temperatures from (278.15 to 323.15)   K using a steady-state method. With increasing temperatures, the solubility increases in aqueous solvent mixtures. The results of these results were regressed by a modified Apelblat equation. The dissolution entropy and enthalpy determined using the method of the least-squares and the change of Gibbs free energy calculated with the values of Δ diff S o and Δ diff H o at T   =   278.15   K.