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Highly sensitive and selective acetylene sensors based on p-n heterojunction of NiO nanoparticles on flower-like ZnO structures

Journal 2019 · IF 3.45 · 45(16): 19635-19643 · 发表于 2019 年 6 月 21 日
作者: Zihao Song,Weigen Chen,He Zhang,Yanqiong Li,Wen Zeng,Sirui Tang,Chengzhi Zhu
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摘要

Acetylene (C 2 H 2 ) gas concentration is a key parameter in transformer monitoring. In current work, the selective acetylene sensors which based on flower-like ZnO structures with NiO nanoparticles were successfully fabricated. The NiO–ZnO composites were synthesized by two-step hydrothermal method . And various of characterization analyses had been applied to the exploration of crystal structure and the p-n heterojunction . According to the systematic gas sensitivity tests, the response of NiO–ZnO (5%) to 50 ppm C 2 H 2 was 15.23 at 200 °C whereas the response of pure ZnO was 4.1 in the same condition. In addition, the response value of NiO–ZnO (5%) to 50 ppm C 2 H 2 was 3.6 times to 50 ppm H 2 . Such a good gas-sensing property of NiO–ZnO composites is due to p-n heterojunction and high catalytic activity of NiO.