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Iron(III) Chloride-Mediated Regio- and Stereoselective Chlorosulfonylation of Alkynes and Alkenes with Sodium Sulfinates

Journal 2017 · IF 5.646 · 359(5): 841-847 · 发表于 2017 年 2 月 6 日
作者: Kui Zeng,Lang Chen,Yi Chen,Yongping Liu,Yongbo Zhou,Chak-Tong Au,Shuang-Feng Yin
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摘要

The atom-economic and one-pot regio- and stereoselective addition of sodium arenesulfinates to either alkynes or alkenes can be achieved with an iron(III) chloride hexahydrate [FeCl 3 ⋅6 H 2 O] catalytic system to afford β-haloalkenyl and β-chloroalkyl sulfones in moderate to good yields.