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Enhanced ultraviolet resistance of polypropylene random copolymer filled by ZnO-supported mesoporous zeolite

Journal 2015 · IF 1.835 · 33(7): 976-987 · 发表于 2015 年 5 月 12 日
作者: Li Mei,Li Gu,Zhang Zi-shou,Dai Xin,Yang Yue-wen,Mai Kan-cheng
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摘要

To enhance the ultraviolet resistance of ZnO based polymer materials, ZnO-supported mesoporous zeolite (M-ZnO) was prepared and characterized by atomic absorption spectroscopy and scanning electron microscopy. The ultraviolet resistance, crystallization behavior and melting characteristics of ZnO and M-ZnO filled PPR composites were compared by FTIR spectra and differential scanning calorimetry. The ultraviolet resistance of M-ZnO filled PPR composites is higher than that of ZnO filled PPR composites, indicating higher ultraviolet resistance of M-ZnO than that of ZnO. The crystallization temperatures of mesoporous zeolite filled PPR were higher than those of M-ZnO and decreased with increasing UV-irradiation time. But the crystallization temperatures of M-ZnO filled PPR composites were not influenced by UV-irradiation time. The ZnO supported on the surface of zeolite is effective in enhancing the ultraviolet resistance of ZnO based polymer materials.