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Synergic improvement on thermal dehydrogenation of the LaH3-MgH2-KBH4 system

Journal 2018 · IF 1.686 · 发表于 2018 年 11 月 2 日
作者: Huaiwei Zhang,Jianbo Qi,Zhenguo Ji
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摘要

Synergic effects of rare earth-magnesium based hydrides (LaH 3 -MgH 2 ) on thermal dehydrogenation of potassium borohydride (KBH 4 ) are discussed in the paper. Comparing to above 675 K for the LaH 3 -MgH 2 or KBH 4 , the dehydrogenation temperature can be decreased to 346 K for the composites (LaH 3 -MgH 2 -KBH 4 ). The apparent activation energy of desorption process for the mixture is also greatly reduced. On the other hand, the products in the temperature programmed desorption process are also illustrated.