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Equilibrium solubility of sodium 2,4-diaminobenzene sulfonate in liquid mixtures (methanol + water, isopropanol + water, and 1,2-propanediol + water) from 273.15 K to 323.15 K

Journal 2016 · IF 2.196 · 发表于 2016 年 4 月 12 日
作者: Rongrong Li,Jiaqi Weng,Cuihong Ye,Anguo Ying,Qizhong Zhou,Aiguo Zhong,Hao Chen,Jianguo Yang
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摘要

The equilibrium solubility of sodium 2,4-diaminobenzene sulfonate in liquid mixtures (methanol   +   water, isopropanol   +   water, and 1,2-propanediol   +   water) were determined at temperatures ranging from (273.15 to 323.15)   K. The solubility of sodium 2,4-diaminobenzene sulfonate increased with temperature increment but decreased with the concentrations of methanol, isopropanol or 1,2-propanediol in liquid mixtures. The obtained solubility data were correlated by Apelblat equation and Sun model. On the base of the measured solubility, the dissolution enthalpy ( Δ H sol o ) of the dissolution process were calculated.