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Nitrogen-doped-carbon-coated SnO2 nanoparticles derived from a SnO2@MOF composite as a lithium ion battery anode material

Journal 2017 · IF 3.108 · 7(32): 20062-20067 · 发表于 2017 年 4 月 5 日
作者: Fengcai Li,Jia Du,Hao Yang,Wei Shi,Peng Cheng
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摘要

N-Doped-carbon-coated 2–4 nm SnO2 nanoparticles were synthesized via a facile metal–organic framework (MOF) coating process followed by a calcination of the SnO2@MOF composite. The as-prepared SnO2 nanoparticles are well dispersed and coated with a uniform nitrogenous carbon structure, which can effectively prevent volume expansion during discharge and charge processes. Benefiting from the advantages of a synergistic effect of SnO2 nanoparticles and carbon structure, these materials exhibit excellent electrochemical performance. For the optimized material SOC-3, a reversible specific capacity of 1032 mA h g−1 was maintained at 100 mA g−1 after 150 cycles with a coulombic efficiency of 99%. When the current was increased to 500 mA g−1, a capacity of 600 mA h g−1 was still attained.