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Effective Catalyst for Oxidation Synthesis of 2,4,6-Trimethylbenzoyldipenylphosphine Oxide: V/MCM-41

Journal 2018 · IF 2.911 · 148(3): 953-957 · 发表于 2018 年 1 月 23 日
作者: Wang Tingting,Wang Zhiming,Zhao Junjing,Yu Qing,Wang Zhongwei
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摘要

2,4,6-Trimethylbenzoyldipenylphosphine oxide (TPO) is an important photoinitiator, nevertheless some drawbacks exist in its synthesis. So V/MCM-41 catalysts were designed. Compared with commonly used VO(acac) 2 , V/MCM-41 catalysts exhibited excellent TPO yield (92.5%), which makes the usage of inorganic vanadium possible and is benefit both in academic and in industry. Graphical