Preparation and performance of silica/polypropylene composite separator for lithium-ion batteries

In an effort to improve thermal stability and mechanical properties of porous polypropylene (PP) separators for lithium-ion battery, SiO 2 /PP/SiO 2 composite separators were prepared by introducing SiO 2 layer on both sides of PP separator through a dip-coating process, with polyvinylidene fluoride–hexafluoropropylene (PVDF–HFP) as binder. SiO 2 nanoparticles are evenly distributed and closely packed in the coated layer, which features a porous honeycomb structure. This unique porous structure was quantitatively analyzed by Gurley value, and it can retain liquid electrolyte, leading to higher electrolyte uptake and ionic conductivity of the composite separator. The introduction of SiO 2 -coated layers can not only suppress thermal shrinkage but also improve mechanical properties of the composite separator. C-rate capability and cycle performance of composite separator were also investigated, and compared to those of pristine PP separator.