Experiments and simulations on separating a CO2/CH4 mixture using K-KFI at low and high pressures

Separation of CO 2 from CH 4 is needed in order to use low-quality biogas or landfill gas and to reduce greenhouse gas emissions. To study the separation of a CO 2 /CH 4 gas mixture , K-KFI (Si/Al   =   4.59) sorbent was synthesized and pelletized. We performed breakthrough experiments at flow rates of 16.6 and 30   N   mL/min under ambient temperature and pressure (298   K, 100   kPa). The breakthrough experiments results showed that K-KFI separated a 40%/60% mixture of CO 2 /CH 4 better than a 50%/50% mixture. Furthermore, the separation performance of K-KFI is superior to that of commercial sorbents zeolite-5A and 13X under the same conditions. Simulations of the breakthrough of binary mixed gases CO 2 /CH 4   =   40%/60%, yield results that are in good agreement with our experimental data. By performing breakthrough simulations at a total pressure of 2   MPa, we demonstrated that pure CH 4 can be separated from CO 2 /CH 4 gas mixtures under high pressure, and that pure CH 4 can be recovered in the initial stages of the breakthrough.