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High performance In2(MoO4)3@In2O3 nanocomposites gas sensor with long-term stability

Journal 2019 · IF 4.175 · 发表于 2019 年 7 月 4 日
作者: Feng-Hua Zhang,Yu-Chong Wang,Lei Wang,Jian Liu,Hong-Liang Ge,Bin Wang,Xin-Yu Huang,Xue-Dong Wang,Zong-Tao Chi,Wan-Feng Xie
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摘要

Metal oxide semiconductor (MOSC) sensors based on nanocrystalline MoO 3 , In 2 O 3 , and their composites are considered to be very sensitive to detect low concentrations of ethanol, ozone, hydrogen, formaldehyde, and nitrogen dioxide . Here, we firstly introduced In 2 (MoO 4 ) 3 phase, which has excellent negative thermal expansion and high electric conductivity properties, into In 2 (MoO 4 ) 3 @In 2 O 3 crystalline nanocomposites . The gas-sensing performance of the In 2 (MoO 4 ) 3 @In 2 O 3 nanocomposites was studied upon exposure to the ethanol gas with different concentration from 5 to 300 ppm at the optimum temperature (300 °C). What's more, the device possesses ultra-high response of 110 and selectivity to ethanol. Particularly, it can effectively work in high humidity (RH = 80%) with super long-term stability of as long as 90 days, compared with the pristine In 2 O 3 sensor and previous reports. The presented novel In 2 (MoO 4 ) 3 @In 2 O 3 sensor offers great opportunities for future ethanol detection under harsh conditions.