Structure and ion transport in an ethylene carbonate-modified biodegradable gel polymer electrolyte

The influence of ethylene carbonate (EC) addition on 85poly(ε - caprolactone):15Lithium thiocyanate (85PCL:15LiSCN) polymer electrolyte is investigated using X-ray diffraction, impedance spectroscopy , Wagner's polarization and electrochemical measurements. The results reveal that the amorphicity of the 85PCL:15LiSCN system increases with increase of EC content up to an optimal level of 40 wt.%. This is reflected in the electrical properties of the gel polymer electrolytes, i.e., the 40 wt.% EC-incorporated gel polymer electrolyte exhibits both high amorphicity and high electrical conductivity as compared to the other samples. The EC concentration dependences of dielectric constant and electrical conductivity show a similar trend, indicating that these properties are closely related to each other. The total ionic transference numbers of EC-incorporated gel polymer electrolytes are in the range 0.989–0.993, demonstrating that they are almost completely ionic conductors . The electrochemical stability window of the 40 wt.% EC-incorporated gel polymer electrolyte is ∼4.1 V along with the electrical conductivity of 2.2 × 10 −4  S cm −1 , which is significantly improved as compared to the 85PCL:15LiSCN system (3.0 V and 1.04 × 10 −6  S cm −1 ). Consequently, the addition of EC in the 85PCL:15LiSCN polymer electrolyte leads to a promising improvement in its various properties.