Cr doping regulates FeNi alloy nanoparticles exsolution on Sr2Fe1.1Ni0.2Cr0.2Mo0.5O6-δ cathode to facilitate CO2 electrolysis

Metal exsolution in perovskite oxide has emerged as an effective way to boost CO2 electrolysis activity in solid oxide electrolysis cells (SOECs). It is crucial to precisely tailor the exsolution characteristics to optimize the catalytic functionality and boost the catalytic activity. Herein, we reveal that the Cr cations doping effectively modify the crystal defects and regulate the metal exsolution of Sr2Fe1.1Ni0.2Cr0.2Mo0.5O6-δ (SFNCM). FeNi alloy nanoparticles with an average particle size of ~10 nm and a particle density of exceeding 1500 μm-2 were exsolved on the surface of SFNCM perovskite, which increases the active sites and enhances CO2 electrolytic activity. The SFNCM based SOEC decorated with abundant FeNi alloy nanoparticles achieves a high current density of 2.57 A cm-2 at 1.6 V, superior to other Sr2Fe1.3Ni0.2Mo0.5O6-δ counterparts.The experimental and theoretical calculation results demonstrate the controllability of the exsolution via engineering of the perovskite structural feature. This work offers a new perspective on lattice doping strategy for the regulation of metal exsolution.