Nickel-Loaded, MXene-Derived Defective Titanium Dioxide Catalysts for Improved Solar-Driven Photothermal CO2 Methanation

Photothermal CO2 hydrogenation harnesses light and heat synergistically to convert CO2 into value-added chemicals, representing an emerging pathway toward carbon-neutral energy systems. Layered MXene, with its large specific surface area and moderate conductivity, is ideal for enhancing photothermal performance. In this work, Ni nanoparticles (NPs) were loaded onto the MXene-derived TiO2 (MTiO2) surface via a hydrothermal method to synthesize Ni@MTiO2 composites with high photothermal CO2 methanation performance. The solar-light-driven methane (CH4) production of the 30Ni@MTiO2 catalyst was 66.03 mmol gcat–1 h–1, with a selectivity approaching 100%. The superior catalytic performance can be primarily attributed to the high dispersion of Ni NPs, the substantial concentration of oxygen vacancies, enhanced charge-carrier separation efficiency, and the robust adsorption capacity. This study provides a feasible strategy for synthesizing efficient photothermal CO2 methanation catalysts derived from MXene.