Enhanced Thermal Shock Resistance of Porous Ca2Mg2Al28O46 Ceramic Filter via Nano-Sized ZrO2 Toughening

Porous Ca2Mg2Al28O46(C2M2A14) ceramics are highly competitive candidates in the field of critical metal filtration due to their attractive non-metallic-inclusions removal capacity. However, the low mechanical strength and inadequate thermal shock resistance (TSR) of these materials restrict their further application. In this work, ZrO2-toughened C2M2A14-based porous ceramics are fabricated by using the polymer sponge replica method. Nano-sized ZrO2particles derived from nano-ZrO2sol are beneficial to enhance the mechanical properties and TSR of porous ceramics. The optimized porous C2M2A14ceramics exhibit robust compressive strength (2.15 MPa), good residual strength ratio (66.4%) and excellent filtration efficiency in the reduction in total oxygen content (68.4%) by adding 3 wt% ZrO2sol. These excellent comprehensive properties show that as-prepared porous C2M2A14ceramics are promising candidate materials for application in the field of critical metal filtration.