High performance framework-integrated Ni(OH)2 anodes for membraneless decoupled water splitting

Decoupled water splitting offers a safe and efficient route for hydrogen production. However, its practical application remains constrained by issues such as low electrode discharge capacity and poor structural stability. In this study, framework-integrated Ni(OH)2 anodes for membrane-free decoupled water splitting are fabricated. The framework-integrated electrode structure with a carboxymethyl cellulose-based binder affords a well-developed conductive network and robust interfacial contact. This architecture delivers higher discharge capacity and enhanced cycling stability relative to conventional coated electrodes. In addition, the use of nickel powder as the conductive additive improves electronic conductivity, resulting in higher discharge capacity and excellent hydrogen-production performance. The framework-integrated Ni(OH)2 anode maintains a stable structure and electrochemical performance over 100 decoupled cycles, achieving a Faradaic efficiency of 97.3%. The electrical energy consumption for hydrogen production is 3.40 kWh m-3 H2 at 50 mA cm-2.