MATERIALS CHEMISTRY AND PHYSICS
·
2024
·
IF 4.3
Yang Qu,Hongrui Jin,Li Lu,Yumei Wang,Kotobuki Mashashi,Binggong Yan
In all-solid-state batteries , the rigid point contact between the solid electrolyte and electrode results in poor cell interface wettability and generates large interfacial impedance, which hinders the application of solid-state batteries. To enhance ionic conductivity and interfacial wettability of NASICON-structured solid-state electrolyte Li 1.5 Al 0.5 Ge 1.5 (PO 4 ) 3 (LAGP), microporous LAGP with a hexagonal surface pattern is prepared using femtosecond laser followed by filling an ionic liquid electrolyte to form a solid-liquid composite electrolyte (HPL&IL). The effect of surface textures on the electrolyte-electrode interface is investigated. Experimental results demonstrate that cycling stability for Li|HPL&IL|Li cells can reach up to 350 h at a constant current density of 0.05 mA cm −2 at room temperature, and hexagonal surface textures promote uniform interfacial film formation while increasing contact area between electrode and electrolyte, providing more space for charge transfer at the interface.
研究领域:
材料科学
·
能源技术
✓ 已验证
产品关联
DOI
高影响因子
Energy Material Advances
·
2023
·
IF 12.9
Zhongyue Wang,Cheng Tang,Zhi Wang,Qing Zhang,Peng Lv,Kehan Yu,Jiajin Zheng,Wei Wei
Developing high-energy cathode for sodium ion batteries (SIBs) that enables 3-electron reaction is the most effective way to reduce high cost and solve range anxiety and safety hazards. Here, a novel NASICON-type Na 4 MnCr(PO 4 ) 3 (NMCP) is synthesized as a high-energy cathode for SIBs. The as-prepared 6.4 wt% carbon-coated NMCP (NMCP@C) cathode annealed at 700 °C delivers a discharge capacity of 107.3 mA h g −1 @0.1C, high rate capability up to 15C, and well capacity retention of 69.3% after 500 cycles at 5C within 1.4 ~ 4.3 V. Meanwhile, it also provides an exciting reversible capacity of 164.3 mA h g −1 @0.1C within 1.4 ~ 4.6 V and an ultrahigh energy density of 523.6 Wh kg −1 . Moreover, high sodium ion diffusion coefficients ( D Na+ , 10 −12 ~ 10 −9 cm 2 s −1 ) demonstrate the superior electrode process kinetics, and both solid solution and 2-phase reactions are involved in the sodium ion extraction/insertion process through ex situ x-ray diffraction analyses. Na 3.3 La 0.3 Zr 1.7 Si 2 PO 12 with 3 wt% Na 2 B 4 O 7 additive (NLZSP(NBO3)) ceramic electrolyte is utilized to assemble NMCP@C//NLZSP(NBO3)//Na solid-state sodium metal batteries for the first time, which reveals an initial discharge capacity of 99.1 mA h g −1 (1.4 ~ 4.3 V) and 121.7 mA h g −1 (1.4 ~ 4.6 V) at 0.1C and an excellent cycling performance (capacity retention of 75.8%/72.6% after 100 cycles at 0.2C) at 30 °C. All these confirm that NMCP@C is a high-energy cathode with great practical potential for all-solid-state SIBs.
✓ 已验证
DOI
高影响因子
ACS Nano
·
2024
·
IF 15.8
Yujin Li,Yu Mei,Yujie Huang,Xue Zhong,Zhenglei Geng,Zidong He,Hanrui Ding,Wentao Deng,Guoqiang Zou,Tongchao Liu,Xiaobo Ji,Khalil Amine,Hongshuai Hou
The carbon coating strategy has emerged as an indispensable approach to improve the conductivity of polyanionic cathodes. However, owing to the complex reaction process between precursors of carbon and cathode, establishing a unified screening principle for carbonaceous precursors remains a technical challenge. Herein, we reveal that carbonaceous precursor pyrolysis chemistry undeniably influences the formation process and performance of Na3V2(PO4)3 (NVP) cathodes from in situ insights. By investigating three types of carbonaceous precursors, it is found that O/H-containing functional groups can provide more bonding sites for cathode precursors and generate a reducing atmosphere by pyrolysis, which is beneficial to the formation of polyanionic materials and a uniform carbon coating layer. Conversely, excessive pyrolysis of functional groups leads to a significant amount of gas, which is detrimental to the compactness of the carbon layer. Furthermore, the substantial presence of residual heteroatoms diminishes graphitization. In this case, it is demonstrated that carbon dots (CDs) precursors with suitable functional groups can comprehensively enhance the Na+ migration rate, reversibility, and interface stability of the cathode material. As a result, the NVP/CDs cathode displays outstanding capacity retention, maintaining 92% after 10,000 cycles at a high rate of 50 C. Altogether, these findings provide a valuable benchmark for carbon source selection for polyanionic cathodes.
研究领域:
材料科学
·
电化学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
ELECTROCHIMICA ACTA
·
2018
·
IF 5.116
Jing Zeng,Zulai Cao,Yang Yang,Yunhui Wang,Yueying Peng,Yiyong Zhang,Jing Wang,Jinbao Zhao
The commercial applications of rechargeable magnesium batteries (RMBs) are hindered by the slow diffusion kinetic of Mg 2+ ions in cathode materials. To overcome this problem, we design a new Na-Mg hybrid battery with the NaTi 2 (PO 4 ) 3 @Carbon (NTP@C) nanoparticles as a cathode material, the Mg metal as an anode and the Mg(TFSI) 2 + NaBH 4 - triglyme/1,2-Dimethoxyethane (DME) as a hybrid electrolyte. For the first time, the Mg(TFSI) 2 is applied as a Mg 2+ ions source in the chlorine-free Na-Mg hybrid electrolyte with NaBH 4 as both Na + ions source and moisture scavenger. The NTP@C/Mg hybrid battery shows excellent electrochemical performance. The corresponding average capacity decay after 1000 cycles is only 0.004% and 0.008% per cycle at 2 C and 10 C, respectively. Even at 20 C, about 60 mAh g −1 can be obtained after 26000 cycles. The impressive capacity retention of 93.7% and 90.2% can be obtained at 5 and 10 C, respectively. The excellent electrochemical performance of the hybrid battery confirms the feasibility using Mg(TFSI) 2 in the chlorine-free hybrid electrolyte for long term cycle. The developed NTP@C/Mg hybrid battery possesses the advantages of excellent electrochemical performances, good safety and low cost, making it promising for the commercial applications, especially for the large-scale energy storages.
研究领域:
材料科学
·
电化学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF MATERIALS SCIENCE
·
2025
·
IF 3.9
Ma Junjie,Li Wei,Yang Deyi,Liu Zheng,Cao Yuyuan,Wang Shaocong,Han Guo-Cheng,Chen Qizhi
N-RGO/Na 3 V 2 (PO 4 ) 3 dual-modified Na 2 Fe 0.6 Mn 0.4 PO 4 F composites were prepared by sol–gel method combined with high-temperature calcination at 625 °C. Electrochemical tests show that the initial discharge specific capacity of N-RGO/Na 3 V 2 (PO 4 ) 3 -modified Na 2 Fe 0.6 Mn 0.4 PO 4 F composites is 149.27 mAh·g −1 at a current density of 0.05 C, and the discharge specific capacity can be maintained at approximately 101.89 mAh·g −1 after 100 cycles. This accounts for 68.26% of its initial discharge specific capacity. Rate performance tests showed that after cycling the current density back to 0.2 C, it was still able to recover to a discharge specific capacity close to 119 mAh·g −1 . At the same time, the interfacial properties of the N-RGO/Na 3 V 2 (PO 4 ) 3 dual-modified Na 2 Fe 0.6 Mn 0.4 PO 4 F composites were studied, and it was found that the capacity attenuation was due to irreversible structural changes such as agglomerated block cracking and structural collapse during multiple cycles, as well as the gradual thickening of the SEI film with the increase in cycle times. This study aims to apply N-RGO/Na 3 V 2 (PO 4 ) 3 dual-modified Na 2 Fe 0.6 Mn 0.4 PO 4 F composites to cathode materials for sodium-ion batteries, providing a theoretical basis for the development of fluorinated poly-anion compounds.
研究领域:
材料科学
·
电化学
·
储能技术
·
纳米材料
·
电池技术
✓ 已验证
产品关联
DOI
高影响因子
DALTON TRANSACTIONS
·
2025
·Vol. 54
·期 11
·4743-4754
·
IF 3.3
Zhenbo Peng,Bifen Chen,Shan Yu,Kaiyu Wu,Farao Zhang,Peng Gao
Na3V2(PO4)3 (NVP) suffers from poor ionic and electronic conductivity. Herein, a dual-optimized design with Cu2+ doping and wrapping in tubular carbon nanotubes (CNTs) is proposed for the first time. This strategy not only modifies the internal electronic structure but also regulates the morphological features of NVP material. Notably, Cu2+ occupying V3+ sites introduces favorable p-type doping effects. Consequently, newly generated holes can act as charge carriers to improve electronic conductivity. Meanwhile, to conserve the charge balance of the whole system, a series of distinctive Na3+xV2−xCux(PO4)3 cathode materials are designed. The Na-rich scheme maintains charge integrity, as well as supplying more active Na+ to take part in the reversible de-intercalation process. Due to the larger ionic radius of Cu2+, Cu2+ doping plays a great role as a pillar to support the crystal skeleton and then expand the Na+ migration channels, thus significantly elevating the ionic transport rate. Furthermore, moderate CNTs are wrapped around the active grains, functioning together with coated carbon layers to construct a highly conductive framework, enhancing electronic transfer. Meanwhile, the tubular CNTs and porous morphology effectively increase the contact areas between active particles and electrolyte, providing more active sites. Furthermore, in situ EIS measurement demonstrates that a stable SEI membrane covers the cycled Na3.07V1.93Cu0.07(PO4)3@CNTs grains to maintain electrode stability and prevent the occurrence of side-effects. Comprehensively, the Na3.07V1.93Cu0.07(PO4)3@CNTs sample releases 124.2 mA h g−1 at 0.1 C. It releases 101.9 and 98.6 mA h g−1 at 10 and 50 C, suggesting superior rate capability.
研究领域:
材料科学
·
电化学
·
储能
·
电池技术
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Communications Chemistry
·
2025
·
IF 6.2
Wang Yu,Li Lanxin,Bo Tao,Han Zhenyu,Tang Yongliang,Lin Wenwen,Zhang Meng,Qiu Jie,Zhang Lei
Langbeinite is proposed as a promising host matrix for radioactive wastes, but no structures incorporating actinides have been reported yet. In this work, a series of single crystals of Cs 2 U Ⅳ Ln(PO 4 ) 3 (Ln = Ce – Nd and Sm – Lu), the first reported langbeinite-type structure incorporating actinides (U IV ) which crystallizes in the cubic space group P 2 1 3, have been successfully prepared by optimizing the high-temperature molten salt method. Their 3D frameworks are characterized by a typical langbeinite structure with U/Ln co-occupying six-coordinated octahedra and Cs cations filling closed large-sized cavities. The compounds exhibit high thermal stability up to 1200 °C under N 2 and show outstanding leaching resistance, with the leaching rates of U and Nd at 10 −8 g·m −2 ·d −1 and Cs 10 −3 g·m −2 ·d −1 . This study highlights the potential of langbeinite-type structures for effectively immobilizing both tetravalent and trivalent actinides as promising waste forms.
研究领域:
材料科学
·
核化学
·
无机化学
·
环境科学
·
晶体学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
SEPARATION AND PURIFICATION TECHNOLOGY
·
2024
·
IF 8.1
Bingqin Li,Liangxing Jiang,Nan Xiao,Siliang Liu,Zongliang Zhang,Fangyang Liu,Michael L. Free
Traditional technologies of lithium extraction from salt lakes suffer the low efficiency of Li + /Mg 2+ separation and high energy consumption. We introduce a novel electrodialysis process that leverages Li 1.3 Al 0.3 Ti 1.7 (PO 4 ) 3 (LATP, one of lithium superionic conductors) and incorporates an aided charge balance (ACB) system, all under low voltage and ultra-low current conditions. The remarkable ion selectivity of LATP, coupled with the enhanced recovery ratio facilitated by ACB, collectively empower this technology to achieve extremely high separation efficiency and remarkably low energy consumption. In a simulated pristine brine, the average Li/Mg separation coefficient reached 5924, accompanied by an exceptionally low energy consumption of only 0.80 kWh·kg −1 Li . Furthermore, this technique enabled the production of battery-grade Li 2 CO 3 with an outstanding purity of 99.93 %, achieved through a streamlined process comprising only two stages.
研究领域:
材料科学
·
环境工程
✓ 已验证
DOI
高影响因子
CERAMICS INTERNATIONAL
·
2025
·
IF 5.6
Yuan Liu,Junxia Wang,Jin Wang,Die Liu,Kunqi Liu,Long Kang,Tongmin Zhang
Composite ceramics, which integrate the advantages of multiple crystal structures, are considered promising candidates for nuclear waste forms capable of simultaneously immobilizing various radionuclides. In this study, a series of 0.4Sr 0.5 Zr 2 (PO 4 ) 3 –0.6Ce 1- x Nd x PO 4 composite ceramics were designed to co-immobilize the simulated fission product Sr and actinide surrogates Ce and Nd. These composite ceramics exhibited homogeneous phase distribution and high densification. Among them, the irradiation-induced damage in the representative sample, 0.4Sr 0.5 Zr 2 (PO 4 ) 3 –0.6Ce 0.6 Nd 0.4 PO 4 composite ceramic, was systematically evaluated under both He 2+ and Xe 20+ irradiation. After He 2+ irradiation, the crystallinity of the irradiated layer was retained despite the disruption of Raman-active bonding groups by point defects. Notably, the Ce 0.6 Nd 0.4 PO 4 phase exhibited significantly higher resistance to He 2+ irradiation than the Sr 0.5 Zr 2 (PO 4 ) 3 phase, as confirmed by GIXRD patterns and geometric phase analysis (GPA). Furthermore, fragmentation of Ce 0.6 Nd 0.4 PO 4 grains was observed, which was attributed to defect accumulation, the thermal spike effect, and the thermal expansion mismatch. Following Xe 20+ irradiation, the irradiated layer of the composite ceramic exhibited reduced crystallinity without complete amorphization, while the Raman-active bonding groups remained largely intact. Additionally, pore formation at grain boundaries was likely caused by the segregation and accumulation of irradiation-induced defects.
研究领域:
核材料
·
陶瓷学
·
辐射效应
·
固态物理
·
材料科学
✓ 已验证
产品关联
DOI
高影响因子
SOLID STATE IONICS
·
2018
·
IF 2.751
Zhen Jiang,Lu Liu,Yuehua Li,Jing Zhu,Chuanchang Li,Zhangxing He,Wei Meng,Yingqiao Jiang,Lei Dai,Ling Wang
NaTi 2 (PO 4 ) 3 /C (NC) composites decorated by carbon nanotubes (CNTs) were prepared via a sol-gel way, and employed as anode in aqueous lithium ion batteries . An effective conductive network was obtained by decoration of CNTs, which can interconnect NC particles. CNTs decoration has no obvious effect on lattice structure for NaTi 2 (PO 4 ) 3 , and can enhance electrochemical properties for NC. Moreover, NC decorated by CNTs with optimal content of 8.8% (NC-CNTs-10) exhibits the highest electrochemical properties. NC-CNTs-10 delivers the discharge capacity of 96.4, 93.7, and 74.2 mAh g −1 at 0.5, 3, and 15C, respectively, with increase of 2.7, 15.1, and 38.2 mAh g −1 compared with NC. In addition, NC-CNTs-10 shows excellent cycling performance. Capacity retention for NC-CNTs-10 can reach 91.2% after 1000 cycles at a rate of 4C, 16.7% larger than that of pristine NC. Our study reveals that CNTs decoration is a simple way to raise electrochemical properties for NaTi 2 (PO 4 ) 3 /C in aqueous lithium ion batteries .
研究领域:
材料科学
·
电化学
✓ 已验证
DOI
高影响因子
SOLID STATE IONICS
·
2019
·
IF 2.886
Lehao Liu,Lihua Chu,Bing Jiang,Meicheng Li
The applications of solid polymer electrolytes in all-solid-state Li-ion batteries are restricted by their low ion conductivities at room temperature and poor mechanical and thermal stabilities. Herein, Li 1.4 Al 0.4 Ti 1.6 (PO 4 ) 3 (LATP) electrolyte nanoparticles were used as active fillers to improve the properties of polyethylene oxide (PEO)-based electrolytes. The ion conductivity of the composite electrolyte with 1 wt% LATP increased to 1.2 × 10 −5 S/cm at room temperature, because of the effective inhibition of the PEO matrix crystallization by the high-conductivity LATP nanofillers . The electrochemical, mechanical and thermal stabilities were also enhanced by the LATP nanofillers. The LATP-filled composite electrolytes can effectively block Li dendrites in symmetric Li/electrolyte/Li cells during repeated Li stripping/plating with a current density of 0.10 mA/cm 2 for 600 h at 30 °C. Furthermore, the LATP-based all-solid-state LiFePO 4 /Li cells exhibited higher reversible capacity (152 mAh/g at 0.10 C), cycling stability (84% after 20 cycles at 50 °C) and rate capability than the LATP-free cells.
研究领域:
材料科学
·
能源存储技术
✓ 已验证
产品关联
DOI
高影响因子
Journal of Nanoelectronics and Optoelectronics
·
2020
·Vol. 15
·期 5
·654-662
·
IF 0.771
Yin Xueai,Feng Weiwei,Zhang Xin
This research focuses on the fluorescent powder materials based on a single matrix of this type of LED. Taking Ba2CaWO6 as an example, mixing Dy3+ alone can produce blue and white light at 318nm UV excitation. At the same time, mixing Dy3+
with Eu3+ can make the fluorescent powders realize the emission of 491 nm/577 nm of Dy3+ and 588 nm of Eu3+. Dy3+ is set to 0.06 and the ratio of Eu3+ is adjusted to make the luminous color gradually close to white. In the study of Ba3Y(PO4)3
· xDy3+ · yEu3+, x is set as 0.07, and the content of y is set as 0.01∼0.08. Dy3+ alone will emit blue and white light under the laser at 391 nm. By increasing the content of Eu3+, polychromatic emission
can be carried out, and white light can be obtained by adjusting the concentration of Eu3+. At the same time, the application functions of white LED packaging are tested for the above materials. The results show that both Ba2CaWO6 · xDy3+
· yEu3+ and Ba3Y(PO4)3 · xDy3+ · yEu3+ materials can realize white lighting by adjusting the ratio of Eu3+ · Dy3+, increasing the proportion of Eu3+
can improve the color rendering of white LED.
研究领域:
材料科学
·
光电技术
·
发光学
·
照明技术
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）