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Journal of Materials Chemistry A · 2015 ·Vol. 3 ·期 33 ·17217-17223 · IF 7.443

HxMoO3−y nanobelts with sea water as electrolyte for high-performance pseudocapacitors and desalination devices

Liang Huang,Xiang Gao,Qiang Dong,Zhimi Hu,Xu Xiao,Tianqi Li,Yongliang Cheng,Bin Yao,Jun Wan,Dong Ding,Zheng Ling,Jieshan Qiu,Jun Zhou

Pseudocapacitors, which store charge through fast reversible redox reactions occuring at the surface of the electrode, could offer higher specific capacitance than electrochemical double-layer capacitors (EDLCs). However, the prime pseudocapacitive phase, transition metal oxides usually have poor electronic conductivity, limiting their practical application. Here, we fabricated highly conductive HxMoO3−y nanobelts as electrode materials for pseudocapacitors. This electrode has demonstrated great electrochemical activity in various aqueous cation solutions with the highest volumetric capacitance of over 350 F cm−3. Significantly, this electrode has high specific capacitance as well as excellent cycling stability in sea water. Moreover, this hybrid composite also exhibits remarkable ion electrosorptive capacity (4 mg g−1) as a desalination electrode.

研究领域: 材料科学 · 电化学
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FLAVOUR AND FRAGRANCE JOURNAL · 2025 · IF 2

A Novel Visualisation Approach for Assessing Flavour Characteristics of Sea Cucumber Intestines Using Chord Diagram

Zhiquan Gao,Junjie Du,Yuxuan Li,Wenhui Zhu,Ying Bu,Menglin Han,Xuepeng Li

This study employed the flavour variations in sea cucumber intestines through sensory and instrumental analyses following different boiling and steaming treatments with water (WB, WS) or green tea water (GB, GS). A dictionary comprising eight descriptors was employed for sensory evaluation. Attributes such as tea flavour, sweet, fishy, briny, fatty, fresh, dark appearance and moist appearance were identified using Free Choice Profiling and Check-all-that-apply methods. A total of 57 volatile compounds were identified by gas chromatography-ion mobility spectrometry. According to the taste activity value (TAV), malic acid and succinic acid were identified as important flavour substances. Glutamic acid (Glu) exhibited a TAV > 1 only in the CON, WS20 and GS20 groups. Steaming exerted a less pronounced impact on flavour compared to boiling. Chord diagram analysis revealed superior efficacy for the GS20 treatment, affirming its utility in flavour assessment of sea cucumber intestines.

CAS / MDL: 64-19-7
研究领域: 食品科学 · 海洋生物学
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JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY · 2021 · IF 5.279

Comprehensive Analysis of Mouse Hippocampal Lysine Acetylome Mediated by Sea Cucumber Peptides Preventing Memory Impairment

Zhiqiang Lu,Xiaomeng Xu,Dongmei Li,Na Sun,Songyi Lin

Memory impairment is becoming a potential health issue with the delicacy of diet and social stress. Sea cucumber peptides (SCP) prevent memory impairment, as previously reported. In this study, further research was performed using hippocampal lysine-acetylome to explore molecular regulation mechanisms. C57BL/6 mice were treated with scopolamine via intraperitoneal injection to simulate memory impairment. To determine the influence of SCP on the total acetylated-protein level of the hippocampus, acetylated-proteomics was performed. SCP increased the acetylation level of histone (H3 and H4). Meanwhile, for non-histones, the differentially acetylated proteins were involved in multiple memory-related pathways, as shown by KEGG enrichment analysis. Additionally, long-term potentiation was confirmed by western blotting. Finally, a combined analysis of proteome and lysine acetylome revealed that SCP contributed to synaptic vesicle cycle regulation and dopamine metabolism. Consequently, our findings revealed that SCP was potentially neuroprotective by regulating post-transcriptional hippocampal protein acetylation.

CAS / MDL: 51-34-3
研究领域: 神经科学 · 蛋白质组学 · 分子生物学 · 药理学
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MOLECULES · 2020 ·Vol. 25 ·期 3 ·744 · IF 3.267

Identification and Characterization of Nematicidal Volatile Organic Compounds from Deep-Sea Virgibacillus dokdonensis MCCC 1A00493

Dian Huang,Chen Yu,Zongze Shao,Minmin Cai,Guangyu Li,Longyu Zheng,Ziniu Yu,Jibin Zhang

Root-knot nematode diseases cause severe yield and economic losses each year in global agricultural production.Virgibacillus dokdonensisMCCC 1A00493, a deep-sea bacterium, shows a significant nematicidal activity againstMeloidogyne incognitain vitro. However, information about the active substances ofV. dokdonensisMCCC 1A00493 is limited. In this study, volatile organic compounds (VOCs) fromV. dokdonensisMCCC 1A00493 were isolated and analyzed through solid-phase microextraction and gas chromatography–mass spectrometry. Four VOCs, namely, acetaldehyde, dimethyl disulfide, ethylbenzene, and 2-butanone, were identified, and their nematicidal activities were evaluated. The four VOCs had a variety of active modes onM. incognitajuveniles. Acetaldehyde had direct contact killing, fumigation, and attraction activities; dimethyl disulfide had direct contact killing and attraction activities; ethylbenzene had an attraction activity; and 2-butanone had a repellent activity. Only acetaldehyde had a fumigant activity to inhibit egg hatching. Combining this fumigant activity against eggs and juveniles could be an effective strategy to control the different developmental stages ofM. incognita. The combination of direct contact and attraction activities could also establish trapping and killing strategies against root-knot nematodes. Considering all nematicidal modes or strategies, we could useV. dokdonensisMCCC 1A00493 to set up an integrated strategy to control root-knot nematodes.Keywords:virgibacillus dokdonensis;Meloidogyne incognita;volatile organic compound;fumigant;attraction;repellent;integrated strategy

CAS / MDL: 75-07-0
研究领域: 农业 · 植物病理学 · 微生物学
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JOURNAL OF ALLOYS AND COMPOUNDS · 2022 · IF 6.371

Sea urchin-like K2Ti8O17 substrate: Facile synthesis and improved Surface-Enhanced Raman scattering (SERS) performance

Jiaxi Sui,Dongdong Liu,Chunyu Wang,Lijuan Wang,Bo Zhong,Yuanyuan Ma

Non-metallic Surface-Enhanced Raman Scattering (SERS) substrate materials with unique structures are considered as promising candidates for detection of dyes in the environment. In this work, a sea urchin-like K 2 Ti 8 O 17 (KTO) nanomaterial was prepared by a facile and efficient hydrothermal method . The enhancement factors of the sea urchin-like KTO for crystal violet and methylene blue are 3.8 × 10 5 and 2.45 × 10 5 respectively, and the minimum detection limits of both can reach 10 −8 M, which means the sea urchin-like KTO a promising non-metallic SERS substrate for detecting dyes in the environment. The excellent SERS performance of the sea urchin KTO was attributed to the excellent charge transfer and probe adsorption capability of KTO by energy band and zeta potential analysis. Finally, the excellent application potential of the sea urchin KTO was verified by simulating a practical use scenario.

研究领域: 材料科学 · 环境科学
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FOOD CONTROL · 2022 · IF 6.652

Identification of sea bass freshness grades using laser-induced breakdown spectroscopy coupled with multivariable analysis

Zilin Yue,Hong Lin,Xiu Fang,Ye Tian,Wenqian Yan,Jiayi Yao,Xiaohui Chen,Kaiqiang Wang

Rapid detection of marine fish freshness is of great importance, as aquatic products are susceptible to spoilage during storage. In this work, for the first time, the laser induced breakdown spectroscopy (LIBS) coupled with multivariable analysis was used for the rapid identification of the freshness of sea bass ( Lateolabrax japonicus ) without using of organic solvents. Results suggested that the principal component analysis (PCA) could accurately differentiate the sea bass samples stored for different days, and the three freshness grades (first-grade, second-grade, and spoilage) of sea bass were separately clustered together. The overall classification accuracy of partial least squares-discriminant analysis (PLS-DA) reached 91.50% ± 1.49% and 97.33% ± 1.90% for differentiating sea bass samples stored for different days, and authenticating different freshness grades, respectively. As storage period increased, the degradation of high-molecular-weight proteins and micromorphology changes were observed in fish muscles using SDS-PAGE and SEM, respectively. In addition, the laser energy absorbed by sea bass increased with the longer storage periods, as shown by the plasma temperature and plasma electron density. The present study demonstrated the capability of LIBS combined with chemometrics for the rapid and eco-friendly identification of marine fish freshness in the food supply chain.

研究领域: 食品科学 · 分析化学 · 光谱学 · 海洋生物学
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NANOTECHNOLOGY · 2022 ·Vol. 33 ·期 48 ·485404 · IF 3.953

Sea urchin-like CoNi2S4 materials derived from nickel hexamyanocobaltate for high-performance asymmetric hybrid supercapacitor

Shang Wu,Xin Xu,Xiangtao Yan,Huanlei Zhao,Chaoyang Liu,Yanbin Wang,Qiong Su,Fenping Yin,Quanlu Yang

In this work, a mild chemical precipitation method and simple hydrothermal treatment of the nickel hexamyanocobaltate precursor strategy are developed to prepare a sea urchin-like CoNi2S4 compound with remarkable specific capacity and excellent cycling stability. The prepared CoNi2S4 has an outstanding specific capacity of 149.1 mA h g−1 at 1 A g−1 and an initial capacity of 83.1% after 3000 cycles at 10 A g−1. Moreover, the porous carbon nanospheres (PCNs) with exhibit cycling stability (94.7% of initial specific capacity after 10 000 cycles at 10 A g−1) are selected as negative electrode to match CoNi2S4 positive electrode for assembly of CoNi2S4//PCNs asymmetric supercapacitor (ASC). Satisfactorily, the as-assembled CoNi2S4//PCNs ASC exhibits an impressive energy density of 41.6 Wh kg−1 at 797 W kg−1, as well as the suitable capacity retention of 82.8% after 10 000 cycles. The superior properties of the device demonstrated that the as-prepared material is potential energy storage material.

研究领域: 材料科学 · 电化学能源存储
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Food Science & Nutrition · 2022 ·Vol. 11 ·期 3 ·1212-1222 · IF 3.553

Phenolic compounds, antioxidant activity and sensory evaluation of sea buckthorn (Hippophae rhamnoides L.) leaf tea

Qian He,Kailin Yang,Xinyan Wu,Chunhong Zhang,Chunnian He,Peigen Xiao

Sea buckthorn leaf tea, an emerging potential functional beverage product, has not yet had appropriate product standards and corresponding quality evaluation methods, and its poor taste directly affects the acceptance of the population, thus limiting its market consumption potential. In this study, two major packaging forms of sea buckthorn leaf tea available in the Chinese market were selected. The contents of total phenolics, total flavonoids, and 10 phenolic compounds, as well as the in vitro antioxidant capacity and sensory characteristics of sea buckthorn leaf tea were analyzed. Results showed that the quality of sea buckthorn leaf tea in the Chinese market varied widely. The total phenolic content, total flavonoid content, antioxidant activity, and consumer acceptance of bagged sea buckthorn leaf tea were higher than those of bulk sea buckthorn leaf tea. Multifactorial statistical analysis showed that the taste astringency of sea buckthorn leaf tea was closely related to ellagic acid and isorhamnetin-3-O-neohesperidin. Furthermore, isorhamnetin-3-O-neohesperidin had a greater effect on the antioxidant activity of sea buckthorn leaf tea. Therefore, ellagic acid and isorhamnetin-3-O-neohesperidin can be used as potential quality markers for sea buckthorn leaf tea. This work provides a reference for taste improvement and quality control of sea buckthorn leaf tea.

CAS / MDL: 64-18-6
研究领域: 食品科学 · 营养学 · 农业化学
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Polymers · 2021 ·Vol. 13 ·期 13 ·2072 · IF 4.329

Research on the Anticorrosion Properties of CeO2-GO/EP Nanocomposite Coating in Simulated Sea Water

Xiaoyan Liu,Ruidan Liu,Tianyu Li,Yanqi Liu,Li Liu,Kai Lyu,Surendra P. Shah

Graphene is a two-dimensional sheet of regular hexagonal honeycomb lattice formed by sp2hybrid orbital bonding, with only one layer thickness of a single atom, which is known as the “super king” of the 21st century. Previous studies have shown that cerium oxide-graphene oxide (CeO2-GO(4:1)) nanocomposites eliminated the agglomeration of graphene to some extent and the CeO2-GO(4:1) epoxy coating could be prepared with good anti-corrosion performance. In this paper, CeO2-GO(4:1) nanocomposites were prepared by the hydrothermal synthesis method, and the three-electrode method was used for electrochemical tests. The state evolution of CeO2-GO(4:1)/EP coating and the synergy between CeO2-GO(4:1)/EP and corrosion inhibitor in simulated seawater solution with different concentrations (20%, 40%, 60%) were analyzed and illustrated by Optical Microscope (OM) characterization, Open Circuit Potential (OCP), Electrochemical alternating current Impedance Spectroscopy (EIS), Mott–Schottky curve and Tafel curve. The results indicated that CeO2-GO(4:1) nanocomposites showed good corrosion resistance in a marine environment. This research lays a solid theoretical foundation for the application of cerium oxide-modified graphene oxide anticorrosive coating in marine engineering.Keywords:CeO2-GO;corrosion inhibitor;simulated seawater;corrosion area

CAS / MDL: 10294-41-4
研究领域: 材料科学 · 海洋工程
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MOLECULES · 2023 ·Vol. 28 ·期 6 ·2634 · IF 4.6

Sea-Cucumber-like Microstructure Polyoxometalate/TiO2 Nanocomposite Electrode for High-Performance Electrochromic Energy Storage Devices

Xiaoshu Qu,Lili Zhou,Zefeng Liu,Zeyu Wang,Jilong Wang,Xiaoyang Yu,Hua Jin,Yanyan Yang

The key challenge in the practical application of electrochromic energy storage devices (EESDs) is the fabrication of high-performance electrode materials. Herein, we deposited K7[La(H2O)x(α2-P2W17O61)] (P2W17La) onto TiO2nanowires (NW) to construct an NW–P2W17La nanocomposite using a layer-by-layer self-assembly method. In contrast to the pure P2W17La films, the nanocomposite exhibits enhanced electrochromic and electrochemical performance owing to the 3D sea-cucumber-like microstructure. An EESD using the NW–P2W17La film as the cathode exhibited outstanding electrochromic and energy storage properties, with high optical modulation (48.6% at 605 nm), high switching speeds (tcoloring= 15 s, tbleaching= 4 s), and high area capacitance (5.72 mF cm−2at 0.15 mA cm−2). The device can reversibly switch between transparent and dark blue during the charge/discharge process, indicating that electrochromic contrast can be used as a quantitative indicator of the energy storage status.Keywords:electrochromism;energy storage;polyoxometalate;nanostructures;EESD

研究领域: 材料科学 · 电化学
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FOOD CHEMISTRY · 2023 · IF 8.8

Quality and flavor characteristics evaluation of red sea bream surimi powder by different drying techniques

Ying Bu,Yue Zhao,Yang Zhou,Wenhui Zhu,Jianrong Li,Xuepeng Li

The present study investigated the effects of five different drying methods, namely hot-air drying (HAD), cold-air drying (CAD), microwave combined oven drying (MCOD), infrared radiation drying (IRD) and vacuum freeze drying (VFD) on the physicochemical properties and flavor of red sea bream surimi. The L* value of the VFD treatment group (77.17) was significantly higher compared to other treatments ( P  < 0.05). The TVB-N content of the five surimi powder remained within an acceptable range. A total of 48 volatile compounds were identified in surimi powder, with the VFD and CAD groups exhibiting superior odor and taste characteristics, as well as a more a more uniformly smooth surface. The gel strength (4402.00  g.mm ) and water holding capacity (92.21%) of rehydrated surimi powder in CAD group were the highest, followed by the VFD group. In conclusion, CAD and VFD can be considered as an effective technique for preparing surimi powder.

CAS / MDL: 64-19-7
研究领域: 食品科学 · 生物化学
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JOURNAL OF ALLOYS AND COMPOUNDS · 2023 · IF 6.2

Sea urchin-like PdCuAu nanoclusters mediated photothermal enhanced Fenton catalysis for degradation of dye pollutants

Jianbo Zhang,Kun Lei,Ji Cheng,Lingqing Luo,Xiaojun Liu,Jinghua Li

This study focused on preparing sea urchin palladium-copper nanospines (PdCuAu NAs) using a one-step reduction method. PdCuAu NAs is a highly branched nanomaterial composed of nanospines, and its unique structure and trimetallic composition give it excellent Fenton catalytic activity and photothermal properties. The characterization of PdCuAu NAs was carried out using SEM, XPS , and UV-Vis techniques. Under near-infrared light, PdCuAu NAs were quickly heated to 50 ℃. Compared to traditional photocatalysts , PdCuAu NAs showed better Fenton catalytic activity in the degradation of organic dyes such as MB. Furthermore, it exhibited good photothermal stability and reusability after multiple thermal cycles and repeated use. Thus, the results showed that PdCuAu NAs had a good degradation effect on organic wastewater.

研究领域: 材料科学 · 环境科学 · 化学
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