INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
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2019
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IF 4.084
Zhuojun Duan,Mingyu Pi,Dingke Zhang,Peng Zhang,Junkai Deng,Shijian Chen
To promote hydrogen production through water splitting, novel porous 3D Al doped CoP 3 nanowire arrays on carbon fiber paper are successfully fabricated as an effective self-supported electrode for hydrogen evolution reaction . The results indicate that the electrocatalytic performance of CoP 3 can be dramatically enhanced via Al doping. It only needs an overpotential of only 40 mV to achieve the current density of 10 mA cm −2 with a small Tafel slop of 43 mV dec −1 for the Al (10%)-CoP 3 nanowire arrays. Moreover, the Al (10%)-CoP 3 NAs/CFP exhibit superior HER efficiency to Pt/C film at high overpotentials due to prompt release of hydrogen bubbles on the special nanowire arrays surfaces. This study demonstrates an avenue for further improving the electrocatalytic activity via tuning the electronic structures and adjusting the surface morphologies through heteroatoms doping.
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JOURNAL OF ALLOYS AND COMPOUNDS
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2018
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IF 3.779
Xinhua Li,Xin Wen,Huanhuan Zhao,Zongqing Ma,Liming Yu,Chong Li,Chenxi Liu,Qianying Guo,Yongchang Liu
The microstructure and phase evolution in Nb-Al system during MA are systemically studied. The existence of Nb-Al amorphous layer surrounding Nb nano-grains after short-time ball milling was confirmed by the HRTEM observation as well as the crystallization behavior in the annealing experiment. It was also found that after short time milling, only very little Al can enter the crystal lattice of Nb and substitute for Nb, whereas most of Al mainly concentrate in this amorphous layer surrounding Nb nano-grains. What's more, interface thermodynamic analysis and calculation were employed to investigate the phase formation and evolution of this amorphous layer in Nb-Al binary system during MA process. Accordingly, positive driving force (≡-ΔG) definitely exists for the formation of the amorphous layer {NbAl} surrounding Nb nano-grains. Thus, these amorphous layers can form and exist stably in the short-time milled Nb-Al system. With the milling time prolonging, this amorphous layer becomes unstable and can crystallize into Nb(Al) ss solid solution when its thickness increases beyond a critical thickness. The critical thickness of this amorphous layer is also predicted by the interface thermodynamics calculation and the corresponding calculated value (approximately 1.9 nm) is consistent with the observed thickness (about 2.2 nm) by the HRTEM within the error range. More importantly, the solubility of Al in the lattice of Nb can be significantly increased resulting from the crystallization of this amorphous layer {NbAl}. Our work provides a new and rational perspective to well understand the complicated microstructure and phase evolution in various nano-sized systems during MA process.
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CATALYSIS TODAY
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2019
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IF 4.888
Yiwen Jiang,Ling Zhang,Yiquan Xie,Shichao Han,Qiuyan Zhu,Xiangju Meng,Feng-Shou Xiao
A series of zeolite-supported Pt nanoparticles (Pt/NaZSM-5) have been prepared by adjusting Si/Al ratio of NaZSM-5 zeolite from 60 to pure silica. Catalytic tests in propene oxidation as an important model reaction for removal of hydrocarbons emitted from automobiles during cold-start, show that the catalytic activities significantly increase with Si/Al ratios of NaZSM-5 zeolite in these Pt/NaZSM-5 catalysts. As a typical example, Silicalite-1 supported Pt nanoparticles exhibits the highest activity, giving the 50% conversion temperature (T 50 ) and 90% conversion temperature (T 90 ) at 112 °C and 118 °C, respectively. Characterizations of these catalysts with multiple techniques show that the enhanced catalytic activities are strongly related to the zeolite Si/Al ratios of the catalysts, where an increase of zeolite Si/Al ratio is favorable for the adsorption of propene, promoting the propene oxidation. This feature might offer a good opportunity to design and prepare highly efficient heterogeneous catalysts for removal of light olefins in the future.
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APPLIED CLAY SCIENCE
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2019
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IF 3.89
Zilin Meng,Mi Wu,Shifeng Zhao,Ruisen Jing,Shutao Li,Yifei Shao,Xijuan Liu,Fengzhu Lv,Aiju Liu,Qian Zhang
A new approach to remove anionic dyes from wastewater was developed by forming Fe 3 O 4 @Zn-Al layered double hydroxides (ZnAl-LDH) in self-assembly process and naphthol green B (NG) with three negative charges was selected as target contaminant. In this process, the successful synthesis of compound and removal of contaminant were accomplished simultaneously. NG in wastewater can be totally removed and the removal efficiency reached the theoretical maximum of LDH removal capacity. The charge-limited removal process and the molecular arrangement of NG molecules in the ZnAl-LDH interlayer were analyzed experimentally and through simulation. The Fe 3 O 4 with small size was complete cover the layers of ZnAl-LDH making it easily separate from wastewater.
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JOURNAL OF ALLOYS AND COMPOUNDS
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2018
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IF 3.779
X.Q. Liu,C.J. Li,J.H. Yi,K.G. Prashanth,N. Chawake,J.M. Tao,X. You,Y.C. Liu,J. Eckert
Achieving effective load transfer at the interface between carbon nanotubes (CNTs) and aluminum (Al) is a crucial issue for fabricating high-performance CNTs reinforced Al matrix (CNT/Al) composites. In this work, CNT/Al composites with different Ti additions and the compared materials were prepared by powder metallurgy . Micro-sized Ti particles in which CNTs are well-dispersed firstly circumvent the difficulty of CNT dispersion, and subsequently act as nucleation site for sandwiched TiAl 3 layers that lock the dispersed CNTs in place and improve the CNT-Al interface bonding. Additionally, Ti addition not only allows modification of the dispersed CNTs but also enhances the strength of the composites by enhancing the load-bearing capacity of the CNTs through in situ formation of nano-sized titanium carbide (TiC). This work provides a new approach to improve the load transfer efficiency of CNTs by strengthening the interface bonding for fabricating high strength CNT/Al composites.
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Nanomaterials
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2018
·Vol. 8
·期 6
·446
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IF 3.504
Yuge Feng,Chengliang Wang,Fei Ke,Jianye Zang,Junfa Zhu
Slow and controlled release systems for drugs have attracted increasing interest recently. A highly efficient metal-organic gel (MOGs) drug delivery carrier, i.e., MIL-100(Al) gel, has been fabricated by a facile, low cost, and environmentally friendly one-pot process. The unique structure of MIL-100(Al) gels has led to a high loading efficiency (620 mg/g) towards doxorubicin hydrochloride (DOX) as a kind of anticancer drug. DOX-loaded MOGs exhibited high stability under physiological conditions and sustained release capacity of DOX for up to three days (under acidic environments). They further showed sustained drug release behavior and excellent antitumor effects in in vitro experiments on HeLa cells, in contrast with the extremely low biotoxicity of MOGs. Our work provides a promising way for anticancer therapy by utilizing this MOGs-based drug delivery system as an efficient and safe vehicle.Keywords:metal-organic gels;doxorubicin loading and release;pH-responsiveness;anticancer effect
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PubMed
高影响因子
CHEMICAL ENGINEERING JOURNAL
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2018
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IF 6.735
Hua Tian,Wentao Bao,Yang Jiang,Lin Wang,Lin Zhang,Ou Sha,Cunqi Wu,Faming Gao
The ingenious synthesis strategies have been highly desired to construct hybrid composites with intriguing properties for supercapacitors . Herein, Ni-Al LDH (layered double hydroxide)/NNDG (nitramine-N-doped graphene) hybrid composites with a layered structure were fabricated via a novel self-assembly process. Nitramine-N dopants anchored to graphene framework allow the self-immobilization of delaminated Ni-Al LDH nanolayers onto the surface of two-dimensional carbonaceous scaffolds and boost the abundance of Ni 3+ within hybrid composites along with the removal of interlayer anions within Ni-Al LDH-NO 3 . Remarkably, the combination of Ni-Al LDH with NNDG can not only enhance the utilization of electrochemically active matrixes in dependence on the increase of electrolyte accessible active sites, but also maximize the electrochemically active contact between inorganic macromolecules and carbonaceous matrixes in favor of the establishment of conductive architectures. Furthermore, Ni-Al LDH/NNDG hybrid composites achieve a specific capacity of 975 C g −1 at a specific current of 1.0 A g −1 with a capacity retention of 75% as the increase of specific currents to 10 A g −1 , superior to Ni-Al LDH-NO 3 and Ni-Al LDH/rGO hybrid composites. The hybrid supercapacitor comprised of Ni-Al LDH/NNDG hybrid composites as a positive electrode and activated carbon as a negative electrode attains a high energy density of 59 Wh kg −1 with a power density of 1991 W kg −1 at a specific current of 2.5 A g −1 and retains 95% of the initial capacitance after 10 000 cycles at a specific current of 10 A g −1 . The excellence electrochemical performance demonstrates clearly the potential application of self-assembled Ni-Al LDH/NNDG hybrid composites for hybrid supercapacitors.
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JOURNAL OF ALLOYS AND COMPOUNDS
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2019
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IF 4.175
Rongfa Ding,Hui Wang,Yan Jiang,Rui Liu,Ke Jing,Meng Sun,Ruiqian Zhang,Shaoyu Qiu,Zhuoming Xie,Haowei Deng,Xianping Wang,Mingguang Kong,Weibin Jiang,Qianfeng Fang,Changsong Liu
ZrC dispersion-strengthened FeCrAl alloys with enhanced high-temperature strength and good ductility were fabricated through spark plasma sintering (SPS) and hot-forging. Nanosized ZrC particles with an average particle size of 56 nm were homogeneously dispersed in the FeCrAl-ZrC alloys. The addition of a small proportion of ZrC nanoparticles effectively refines the grain size and improves the strength and hardness of FeCrAl alloys. However, the ductility of FeCrAl alloys decreases gradually when the ZrC content increases from 0 wt% to 2.0 wt%. The tensile strength of SPSed FeCrAl-1.0 wt% ZrC alloy at 800 °C is 91 MPa, which is about 69% higher than that of pure FeCrAl, while the percentage elongation after fracture of FeCrAl-1.0 wt% ZrC is 15.0%, which is lower than that of FeCrAl (48.2%). To improve the ductility of FeCrAl-ZrC alloys, the SPSed samples were subjected to hot forging at 1000 °C. Through hot-forging, significant enhancement in ductility of FeCrAl-ZrC alloys was achieved without reducing the strength. The mechanical properties and microstructure of FeCrAl-1.0 wt% ZrC are stable after annealing at 1000 °C for 5 h, exhibiting superior thermal stability as compared with FeCrAl.
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CHINESE JOURNAL OF CHEMICAL ENGINEERING
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2024
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IF 3.7
Sijia Wang,Ye Liu,Liang He,Yu Sun,Qing Huang,Shoudong Xu,Xiangyun Qiu,Tao Wei
Solid polymer composite electrolytes possess the benefits of superior compatibility with electrodes and good thermal characteristics for more secure energy storage equipment. Herein, a new gel polymer electrolyte (GPE) containing NH 2 -MIL-53(Al), [PP 13 ][TFSI], LiTFSI, and PVDF-HFP was prepared using a simple method of solution casting. The effects of encapsulating different ratios of ionic liquid ([PP 13 ][TFSI]) into the micropores of functionalized metal-organic frameworks (NH 2 -MIL-53(Al)) on the electrochemical properties were compared. XRD, SEM, Nitrogen adsorption-desorption isotherms and electrochemical measurements were conducted. This GPE demonstrates a superior ionic conductivity of 8.08×10 –4 S cm –1 at 60 °C and can sustain a discharge specific capacity of 156.6 mAh g –1 at 0.2 C for over 100 cycles. This work might offer a potential approach to alleviate the solid-solid contact with the solid-state electrolyte and electrodes, and broadens up new window for the creation of all-solid-state batteries.
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CERAMICS INTERNATIONAL
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2024
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IF 5.1
Xueyuan Yang,Linxuan Li,Minxian Shi,Zhixiong Huang,Zongyi Deng
The inherent susceptibility to oxidation limits the application of carbon fibre/phenolic resin composites (CF/Ph) in the thermal protection of hypersonic vehicle engines. Herein, TiB 2 -B 4 C modified Al-coated carbon fibre/boron phenolic resin ceramizable composites were fabricated. The optimal ceramizable composite (T 30 C 10 ) exhibited excellent ablation resistance and high-temperature insulation capacity at a linear ablation rate and bottom-surface temperature of −0.00768 mm/s and 129.8 °C, respectively. Oxygen consumption and inhibition, carbon fixation, and self-healing effects contributed to the excellent ablation resistance, and the effects of the Al coatings and carbothermal reduction reactions led to excellent high-temperature insulation capacities.
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ADVANCED FUNCTIONAL MATERIALS
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2024
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IF 18.5
Tao Jiang,Wenzhong Wang,Yue Bi,Yujie Liang,Junli Fu,Lijuan Wang,Qing Zhou
Photoelectrochemical (PEC) hydrogen evolution from water splitting of semiconductor photoanodes is intricately linked to their light-absorbing capacity, surface reaction kinetics, bulk charge carrier separation efficiency, and surface charge carrier injection efficiency. Harnessing the surface plasmon resonance effect of metals emerges as a promising approach to enhance PEC performance of semiconductor photoanodes. This work presents the first application of non-noble metal Al nanoparticles to sensitize a BiVO 4 nanoporous film (NPF) photoanode. This process significantly expedites the surface kinetics of water oxidation, and improves both bulk charge carrier separation and surface carrier injection efficiencies of BiVO 4 NPF photoanode. Additionally, the surface-formed Al 2 O 3 film effectively preserves the stability of photoanode, leading to a substantial improvement in PEC hydrogen evolution of BiVO 4 NPF photoanode in a three-electrode PEC cell with sulfite scavenger. The constructed BiVO 4 /Al NPF heterojunction photoanode exhibits a hydrogen evolution rate of 73.9 µmol cm⁻ 2 h⁻¹ at 1.23 V versus reversible hydrogen electrode, 1.68 times of BiVO 4 photoanode. Additionally, BiVO 4 /Al NPF photoanode exhibits excellent stability under long-time light irradiation of 8 h. This study provides valuable insights into the design of nonnoble-metal-based plasmonic photoanodes for efficient hydrogen generation through PEC cell from the perspectives of surface reaction kinetics, charge carrier injection, and separation.
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TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
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2016
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IF 1.34
Shan-guang SONG,Shi-lei TAN,Xiao-xiao QI,Wei WANG,Li-li WANG
YSZ/(Ni, Al) composite coatings were deposited on Inconel600 superalloy with ball peening (BP) and without (non BP) treatment using the electrophoretic deposition (EPD) technique, followed by vacuum sintering method. The structures and phase evolution of the coatings were studied with X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectrometry (EDS). The relation between microstructures and properties of the BPs-coated samples was discussed. The results show that the adhesion strength and gain mass of the BPs-coated samples with isothermal oxidation at 1100 °C for 100 h are 3.3 N and 0.00817 mg/cm 2 , respectively, while those of the non-BPs-coated sample are 2.6 N and 0.00559 mg/cm 2 , respectively. The EDS mapping analysis indicates that an obvious outward diffusion of Cr from the substrate to BPs coated samples occurs after isothermal oxidation. The BPs-coated sample shows the superior adhesion and oxidation resistance compared with non-BPs-coated samples.
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危险品化学品经营许可证（带存储）