JOURNAL OF HAZARDOUS MATERIALS
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2018
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IF 6.434
Sujuan Zhang,Weixin Huang,Xianliang Fu,Gaoli Chen,Sugang Meng,Shifu Chen
A series of Pt nanoparticles (with size of 3–4 nm) decorated CdS nanorods were prepared via a simple solvothermal method. The samples were then used for photocatalytic selective oxidation (SO) of aromatic alcohols and reduction (SR) of nitroarenes in one reaction system. The platinized samples showed enhanced activity for the conversions than pristine CdS as Pt can serve as e − trapping and reaction sites, by which the recombination of photoinduced charge carriers can be suppressed and the adsorption of reactants and the SR of nitroarenes can be promoted. The sample loaded with only of 0.03% Pt showed the highest performance and, after irradiation for 4 h, the conversions of p-methoxybenzyl alcohol and nitrobenzene are as high as 92.7% and 94.8%, while the yields of p-methoxybenzaldehyde and aniline are 80.5% and 36.0%. The activities are about 2.0 times higher than that of CdS. The coupling reaction mechanism for the SO of aromatic alcohols to aldehydes and SR of nitroarenes to anilines in the reaction system was finally proposed.
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JOURNAL OF MEMBRANE SCIENCE
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2026
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IF 8.8
Yuxing Han,Yingqing Zhan,Jie Liu,Jia Luo,Jing Yang,Sama M. Al-Jubouri,Xiaoming Gao,Xinyue Duan,Wei Zhao,Ping Zhang,Yajie Lei
Hydrogel-based polymer separation membranes are widely applied in the purification of oily emulsified wastewater. However, the traditional hydrogel layer on the membrane surface encounters major obstacles of poor structural stability and difficulty in addressing complex fouling issues. Herein, the 3D raspberry-like CdS@MXene heterojunction microsphere was prepared via a combined strategy of template-assisted and hydrothermal methods, which was applied as a functional nanofiller to reinforce the polyvinyl alcohol-tannic acid (PVA-TA) hydrogel decorated poly (arylene ether nitrile) (PEN) membrane with photothermal-catalytic functionality. Benefiting from the multi-scale synergistic stabilization strategy of multiple bonding, gradient functionalization, and nano-interpenetration enhancement, the hydrogel layer demonstrated robust structural stability under harsh conditions and physical damage. Furthermore, the 3D hierarchical heterojunction microsphere provided a rapid transport pathway for photogenerated electrons and effectively suppressed electron-hole recombination, conferring on the membrane high degradation efficiency of organic dyes under simulated sunlight conditions within 60 min (degradation rate: up to 96.88%). Simultaneously, the membrane surface temperature reached 85.34 °C via rapid photothermal conversion within 30 s, significantly reducing the viscosity of highly viscous oil pollutants attached to the membrane surface and achieving efficient self-cleaning capability. Moreover, 3D MXene-based heterojunction microsphere overcame the compact physical stacking of 2D nanosheets, enabling the efficient separation of oil-in-water emulsions (flux: 215.15 L m −2 h −1 ; rejection rate: 99.56%). This work provides a new approach for preparing robust and multiple antifouling hydrogel-based polymer separation membrane with photothermal-catalytic synergy for treating complex oily emulsified wastewater.
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MICROCHIMICA ACTA
·
2026
·Vol. 193
·期 1
·60
·
IF 5.3
Yang Yu Zhu,Li Gui Yong,Zhang Pu,Cui Linyun,Liu Huan Li,Chen Shi,Dai Xin
In this study, N-CDs were combined with Eu 3+ to construct a ratiometric fluorescence sensor (N-CDs@Eu 3+ ) for the determination of tetracycline (TC). The nitrogen-doped carbon dots (N-CDs) with good water solubility, excellent fluorescence performance, and high stability successfully prepared by using the leaves of Mahonia fortunei leaf as the carbon source and ethylenediamine as the nitrogen source through a one-step thermal solvent method. In the presence of TC, the fluorescence intensity of N-CDs at 510 nm was quenched due to fluorescence resonance energy transfer (FRET), while the fluorescence intensity of Eu 3+ at 616 nm was significantly enhanced through the antenna effect (AE). This ratiometric fluorescence sensor enables rapid, sensitive and highly selective detection of TC, with a detection limit as low as 7.5 nM. Moreover, a distinct color change from green to red can be observed under a 365 nm UV lamp. With the assistance of a smartphone sensing platform, visual semi-quantitative monitoring of TC was achieved. This method was successfully applied to the detection of TC in milk, pork, and honey, with recoveries ranging from 90.6% to 105.0%. This research demonstrates that this sensor holds potential application value in the field of real-time visualization detection and semi-quantitative determination of TC in biomedical and food safety sensing fields. Graphical abstract
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高影响因子
MICROCHEMICAL JOURNAL
·
2023
·
IF 4.8
Jiaodi Li,Linzi Huang,Minghui Huang,Yaqi Yang,Zhifang Liu,Chenxi Wang,Yixi Xie,Pengcheng Zhao,Junjie Fei
Copper (II) ion (Cu 2+ ) is a typical heavy metal ion that not only harms the soil and water environment, but also causes neurological disorders, liver cirrhosis and other diseases. Here, we have successfully synthesized three-dimensional CdS/rGO@Au heterojunction using a simple physical mixing technique, characterized the material synthesis by X-ray diffraction spectroscopy (XRD), Transmission electron microscopy (TEM), and finally used it for selective photoelectrochemical detection of Cu 2+ . In this system, the synergistic interaction of the three creates a channel that is ideal for charge carrier separation and transfer. The cauliflower-shaped CdS possesses a large surface area and acts as a Cu 2+ probe. rGO@Au acts as a sensitizer and amplifies the current change. The photocurrent of the CdS/rGO@Au heterojunction is 7 times higher than that of CdS, indicating that CdS/rGO@Au has a good photoresponse intensity. Under the optimized detection conditions, the proposed photoelectrochemical sensor was able to detect Cu 2+ concentration in the range of 5 nM to 4 μM with a very low limit of detection (LOD) of 2.88 nM. Moreover, the application feasibility of the developed CdS/rGO@Au heterojunction sensor was verified by the detection of Cu 2+ in real water samples.
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OPTICAL MATERIALS
·
2022
·
IF 3.754
Yang Wang,Sheng Feng,Changchang Ma,Yun Zhou,Zhiwei Ye,Xiaojun Dai,Xun Cao
In this paper, a novel Mn-doped CdS@NH 2 -MIL-125(Ti) (MC@NT) photocatalytic composites was synthetized through hydrothermal method . Hydrogen desorption and tetracycline and oxytetracycline degradation were performed under visible light to test their photocatalytic activities . The composites were characterized by XRD , FTIR, SEM, TEM, XPS , UV–Vis diffuse reflectance spectroscopy (DRS), EPR , EIS, and transient photocurrent response. From the characterization consequence, it could be seen that Mn-doped CdS was tightly attached to the surface of tetragonal NT in the form of nanoparticles . The MC@NT composites exhibited more promising catalytic activity than pristine monomeric materials. The photocatalytic hydrogen evolution rate reached 3.61 mmol g −1 h −1 . Within 110 min, the degradation efficiencies of TC and OTC were 90% and 88%, respectively. The free radical trapping experiments proved that ·O 2 − and h + were decisive role for degrading pollutants in the degradation catalysis process. Radical trapping experiments and electron spin resonance (ESR) indicated that the Z-scheme heterojunction was formed between Mn-doped CdS and NT, leading to facilitate the migration and shift of photogenerated carriers and holes. Cycling experiments showed that the as-prepared composites have good stability and have good prospects for practical applications. We believe this work will offer new ideas on the future development of efficient heterojunction catalysts for light energy conversion and other applications.
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Materials Today Nano
·
2022
·
IF 13.364
X. Cui,Y. Zhou,Y. Zheng,L. Cao,L. Gao,J. Duan,H. Yin,S. Ai
N 6 -methyladenosine (m 6 A) is the most abundant and dynamic reversible modification of mRNA in eukaryotes discovered in the mid-1970s, which is widely involved in various physiological processes. Fat mass and obesity-associated protein (FTO protein) is not only a demethylase for m 6 A, but also a carcinogenic factor for many human cancers. Therefore, it is very important to build a simple and sensitive platform for simultaneous detection of m 6 A and FTO protein. To achieve this aim, a novel photoelectrochemical biosensor was constructed with the antibody-free detection strategy of DTT mediated –SH functionalization of m 6 A triggered by FTO protein catalyzed m 6 A oxidation . To achieve high detection sensitivity, CdS/Bi 2 MoO 6 /MoSe 2 system with matched energy gap was employed as photoactive material. To achieve high detection selectivity , the –CH 3 of m 6 A in the captured RNA sequence (m 6 A RNA) on the electrode surface was oxidized by FTO protein to form hydroxymethyl, followed with the covalent reaction of DTT with hydroxymethyl, making the labeling of m 6 A with –SH. Finally, a CdS nanoparticle was modified on the electrode through the specific covalent reaction between –SH and Cd, achieving the improvement of the photocurrent with the matched energy band . Under the optimal experimental conditions, the biosensor showed linear range from 0.001 to 50 nM and 0.0005–500 μg/L with the detection limit of 0.37 pM and 0.034 ng/L (S/N = 3) for m 6 A RNA and FTO protein, respectively. The applicability of the developed method was assessed by investigating the effect of entacapone on FTO protein activity.
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JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS
·
2021
·
IF 3.995
Zhiyu Liu,Jianhe Tang,Congcong Piao,Xing Zhang,Xiaochen Qi,Ying Tian,Dawei Fang,Jun Wang
A novel Z-scheme CaF 2 :Yb 3+ ,Er 3+ @ZnTiO 3 /Au/CdS photocatalyst has been prepared. In this system, an excellent up-conversion luminescent agent, CaF 2 :Yb 3+ ,Er 3+ , is introduced to broaden the light response range. The Au surface plasmon resonance effect endows the system with highly efficient charge transfer. The photocatalytic activity of the Z-scheme CaF 2 :Yb 3+ ,Er 3+ @ZnTiO 3 /Au/CdS photocatalyst has been evaluated in the degradation of norfloxacin (NOR) with simultaneous hydrogen production . Some influencing factors, such as solar light irradiation time, sacrificial agent concentration, and number of reuse cycles, are discussed. The emission spectrum and energy conversion mechanism of CaF 2 :Yb 3+ ,Er 3+ have also been studied. The prepared photocatalyst facilitated a significant degree of degradation (92.05%) of NOR and considerable hydrogen production (513.39 μmol/g) under solar light irradiation for 5.0 h. Moreover, it showed high stability in photocatalytic NOR degradation with simultaneous hydrogen production over five cycles. A possible mechanism for photocatalytic degradation of NOR with simultaneous hydrogen production promoted by the Z-scheme CaF 2 :Yb 3+ ,Er 3+ @ZnTiO 3 /Au/CdS photocatalyst is proposed.
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SENSORS AND ACTUATORS B-CHEMICAL
·
2020
·
IF 7.1
Nian Cao,Faqiong Zhao,Baizhao Zeng
In this study, a novel potential-resolved ratiometric electrochemiluminescence (ECL) sensor, using Ru(bpy) 3 2+ doped TiO 2 nanoparticles (TiO 2 -Ru(bpy) 3 2+ NPs) with polyethyleneimine (PEI) capped CdS quantum dots (PEI-CdS QDs) as new ECL emitter unit and molecularly imprinted polymer (MIP) as recognition element, was proposed for the first time. Owing to the large specific surface area and porosity of TiO 2 NPs plentiful Ru(bpy) 3 2+ was well immobilized on them. The obtained TiO 2 -Ru(bpy) 3 2+ NPs were able to catalyze the reduction of coreactant H 2 O 2 of PEI-CdS QDs, while the PEI-CdS QDs could serve as the coreactant of TiO 2 -Ru(bpy) 3 2+ NPs, thus their ECL was promoted by each other. Additionally, graphene oxide (GO) was used to facilitate the electron transfer and sialic acid (SA) imprinted poly(3-aminophenylboronic acid) was electrodeposited on the resulting GO/TiO 2 -Ru(bpy) 3 2+ @PEI-CdS/GCE. When SA concentration increased the anodic ECL signal from TiO 2 -Ru(bpy) 3 2+ NPs increased, while the cathodic ECL signal from PEI-CdS QDs declined. The sensor exhibited high sensitivity, selectivity and stability. Under the optimized conditions, the linear range was 1.0 nM - 0.1 mM and the detection limit was low to 0.017 nM (S/N = 3). Its good practical feasibility was confirmed by detecting SA in real samples with satisfactory results.
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APPLIED SURFACE SCIENCE
·
2019
·
IF 5.155
Wei Chen,Rui-Qiang Yan,Jian-Qun Zhu,Guo-Bo Huang,Zhong Chen
All-solid-state Z-scheme CdS/QDs/ZnIn 2 S 4 architectures with MoS 2 quantum dots as solid-state electron mediator were successfully designed and constructed by optimally combining one-dimensional CdS nanorods, zero-dimensional MoS 2 quantum dots (QDs) and two-dimensional ZnIn 2 S 4 nanosheets. The photocatalytic water splitting for hydrogen evolution demonstrated that such structural design can synergistically trigger remarkably improved visible-light-driven photocatalytic activity. Photocatalytic H 2 -evolution at 2107.5 μmol g −1 h −1 was achieved on this CdS/QDs/ZnIn 2 S 4 architectures under visible light irradiation, exceeding those of bare CdS nanorods and pure ZnIn 2 S 4 nanosheets by a factor of 26 and 62, respectively. This highly efficient photocatalytic activity arises from the effective charge separation and favourable electron mediator of MoS 2 QDs. The Z-scheme charge separation mechanism was verified by the ESR, PL-TA and organic electron acceptor test.
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MICROCHIMICA ACTA
·
2019
·Vol. 186
·期 12
·1-8
·
IF 5.479
Niu Yanyan,Luo Guiling,Xie Hui,Zhuang Yujiao,Wu Xianqun,Li Guangjiu,Sun Wei
A photoelectrochemical (PEC) aptasensor for Pb(II) detection is described. A nanocomposite consisting of CdS (2.5 μm) and TiO 2 nanoparticles (10 nm) was used as a photoactive material, and gold nanochains (Au NCs) as the support for immobilization of the Pb(II)-binding aptamer. The quercetin-copper(II) complex was further employed as the intercalator for the improvement of the photoactivity by embedding it into dsDNA. In the presence of Pb(II), a Pb(II)-stabilized G-quadruplex was formed between Pb(II) and DNA S1. This is accompanied by unwinding of the dsDNA and the release of the quercetin-copper(II) complex from the surface of the sensor. This results in a decrease of the photocurrent that drops linearly from 5.0 × 10 −12 to 1.0 × 10 −8 mol·L −1 Pb(II) concentration range with a detection limit of 1.6 × 10 −12 mol·L −1 . The method was applied to the determination of Pb(II) in various samples and gave satisfactory results.
A photoelectrochemical aptasensor was fabricated for the detection of Pb(II) based on CdS-TiO 2 nanocomposite modified indium tin oxide (ITO) electrode. Gold nanochains (AuNCs) were used as anchor to immobilize the aptamers S1 and S2 that form a double helix structure by DNA hybridization. After embedding of quercetin-copper(II) complex as intercalator and electron donor, the concentrations of Pb(II) were determined by the changes of photocurrents.
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JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
·
2019
·Vol. 96
·期 1
·69-79
·
IF 1.429
Duan Nannan,Ye Lin,Zhang Ai-ying,Feng Zeng-guo
Abstract A series of PPR-based multiblock copolymers were prepared by using a PPR self-assembled from a distal 2-bromoisobutyryl end-capped ferrocenyl containing derivative Br-TEG-Fc-TEG-Br with 4 β-CDs as initiator to initiate the in situ ATRP of NIPAAm in aqueous solution at room temperature. After the ATRP, about 2 β-CDs were resided on the polymeric backbone through a 7 day dialysing purification, but those β-CDs were all slipped off the polymeric chain through a further 7 day dialysing treatment. It suggested that the resulting multiblock copolymers are really the PPR-based instead of the PR-based ones showing an impeded dethreading behavior of β-CDs and the PNIPAAm blocks attached are not bulky enough as polymeric stoppers to end-cap the β-CD-TEG-Fc-TEG PPRs into the PR-based multiblock copolymers. Graphic abstract A series of PPR-based multiblock copolymers were prepared by using a PPR self-assembled from Br-TEG-Fc-TEG-Br with 4 β-CDs as initiator to initiate the aqueous ATRP of NIPAAm. After the polymerization there are about 2 β-CDs still entrapped on the polymeric chain through a 7 day dialyzing purification. Those threaded β-CDs are all slipped off the polymeric backbone through a further 7 day dialyzing treatment.
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SENSORS AND ACTUATORS B-CHEMICAL
·
2020
·
IF 7.1
Dezhi Yang,Qiulan Li,Sai Kumar Tammina,Zhe Gao,Yaling Yang
The construction of highly efficient nanozyme activities in a simple means is vital for the wide biological and chemical applications. Present work describes a Cu-based carbon dots (Cu-CDs) with oxidase- and peroxidase-like activity for the catalytic oxidation of o -phenylenediamine (OPD) at neutral pH. The peroxidase-like activity of Cu-CDs was finely tuned and enhanced by changing the ascorbic acid (AA) content and reduction temperature to increase the Cu + content. The oxidation of OPD was significantly accelerated by the addition of Fe 2+ ions (i.e., Cu-CDs + Fe 2+ /H 2 O 2 system) and presented a smaller K m (Michaelis constant) and a higher V max (maximum rate) than horseradish peroxidase (HRP) at the same mass concentration. The Cu-CDs with oxidase- and peroxidase-like activities could catalyze to produce the superoxide radical ( · O 2 - ) and hydroxyl radical (·OH) in the system. Interestingly, the catalytic oxidation of OPD to 2,3-diaminophenazine (DAP) could be inhibited by Cr(III) ions in Cu-CDs + Fe 2+ /H 2 O 2 system. Therefore, a new fluorescent detection strategy was developed for the detection of Cr(III) with the linear range of 0.2−100 μM, and the detection limit of 36 nM (S/N = 3). This work provides new insight into the mechanism and kinetics of low-valence copper–carbon dots peroxidase-like and Fenton co-catalyst system.
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