JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
·
2021
·Vol. 32
·期 13
·18205-18211
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IF 2.478
Jin Ding Hao,Hu Cheng Chao,Liu Bing
CaAl 2 − 2 x Zn x Ti x O 4 ( x = 0.05, 0.10, 0.15) ceramics with low permittivity have been prepared via a standard solid-state reaction method. The partial co-substitution of (Zn 0.5 Ti 0.5 ) 3+ for Al 3+ can effectively lower the sintering temperature of CaAl 2 O 4 ceramics by approximately 200 °C. Meanwhile, the large negative temperature coefficient of resonant frequency ( τ f = − 55 ppm/°C) of CaAl 2 O 4 ceramics can be simultaneously modified toward zero. With increasing x , the quality factor ( Q f ) indicates a downward changing trend owing to the appearance of ZnAl 2 O 4 and CaTiO 3 secondary phases. The optimum microwave dielectric properties ( ε r = 11.9, Q f = 28,090 GHz, and τ f = − 1.2 ppm/°C) are achieved at x = 0.15. Moreover, a microstrip patch antenna is fabricated using the x = 0.15 ceramic as the dielectric substrate. The fabricated antenna demonstrates a S 11 value of − 17.8 dB at 4.9 GHz and a measured − 10 dB bandwidth of 86 MHz. The good antenna performances suggest that the present ceramics are good candidates for 5G antenna applications at the sub-6 GHz band.
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高影响因子
JOURNAL OF MATERIALS SCIENCE
·
2021
·Vol. 56
·期 31
·17601-17614
·
IF 4.22
Weng Chengjie,Li Wen,Wu Jian,Shen Liming,Yang Wenzhong,Deng Cong,Bao Ningzhong
Abstract The fabrication of epoxy/graphene composites with greatly enhanced thermal conductivity ( K ) in terms of efficient thermal dissipation of electronic devices has drawn much interest. However, the lack of continuous thermal conductive paths and thermal interface resistances generated between matrix and fillers limit the further enhancement of the K value. Here, a siloxane cross-linked graphene framework (SGF) with highly conductive paths is prepared by a simple way, i.e. , thermal-shock exfoliation of graphene oxide film followed by self-polymerization of silanol inside GF. The epoxy (EP) resin was then impregnated into SGF to form the EP/SCF composite. The mutual percolation of EP and SGF in the composite eliminates the distribution issue of graphene sheets. The siloxane molecular network not only cross-links adjacent graphene sheets, but also forms chemical bonding with EP matrix, resulting in significantly decreased inter-sheet and interface thermal resistances. The EP/SGF composite containing 20.2 wt% graphene exhibits an in-plane K of 54.2 W m –1 K –1 , which is about twice higher than that of EP/GF without siloxane and 270 times higher than pure EP. Graphical Abstract
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GLYCOCONJUGATE JOURNAL
·
2021
·Vol. 38
·期 5
·527-537
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IF 2.916
Zhang Xin,Wang Chen,Han Qing,Chen Xuan,Li Guoyun,Yu Guangli
Mucins are the major proteins that distributed on the intestinal mucosa layer and protect the intestine from pathogens infection. The composition of intestinal mucin O -glycans can affect the health of the gastrointestinal tract in pigs. Porcine intestinal mucosa is widely used as the main raw material of heparin extraction. The heparin extraction residues rich in mucins were usually wasted. The structure of mucin derived O -glycans in porcine intestinal mucosa are currently unknown. In this study, we isolated the mucins from the heparin extraction residues and profiled the O -glycans. After heparin extraction, mucin was digested with trypsin, and separated by strong anion exchange chromatography. The mucin derived O -glycans were release by alkaline β elimination, and analyzed by ultra high performance liquid chromatography-porous graphitized carbon-Fourier transform mass spectrometry (UPLC-PGC-FTMS/MS). Thirty five kinds of O -glycans were identified, most of which were Core 3-derived glycans. In particular, the O -glycans containing sialic acid Neu5Ac accounted for 71.93% of the total O -glycans, which were different from that of other species, including mouse intestine, fish intestine, and porcine colon. The high content sialylated mucin may explain its effect in biological processes. Furthermore, the immunological activity results indicated that the porcine intestinal mucin could promote phagocytosis and proliferation without any cytotoxic effects, which may aid in the development of immunomodulators.
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PubMed
高影响因子
WATER AIR AND SOIL POLLUTION
·
2021
·Vol. 232
·期 9
·1-21
·
IF 2.52
Cano-Viveros Selene,Galar-Martínez Marcela,Gasca-Pérez Eloy,García-Medina Sandra,Ruiz-Lara Karina,Gómez-Oliván Leobardo Manuel,Islas-Flores Hariz
Aluminum, mercury, and iron have been found in high concentrations in various freshwater bodies around the world and have been shown to be very harmful contaminants to hydrobionts, causing metabolic dysfunction and damage at various levels. However, studies on mixtures of these pollutants are scarce, particularly in younger or developing organisms, which are more sensitive to damage. Therefore, the objective of this work was to evaluate the toxicity of Al, Fe, and Hg, in isolation and in mixture, on common carp embryos exposed to the maximum permissible limits described in the Mexican regulations for the protection of aquatic life, correlating the biomarkers of oxidative stress with the effects on embryonic development. For this purpose, the Cyprinus carpio embryos were exposed to iron (0.1 mg L −1 ), mercury (0.00001 mg L −1 ), aluminum (0.05 mg L −1 ), and their mixture, throughout their development and until hatching. The activity of the antioxidant enzymes (SOD, CAT, and GPx), the degree of lipoperoxidation, and the content of hydroperoxides and total proteins, as well as the morphological development of the embryos were evaluated at 12 h, 24 h, 48 h, 72 h, and 96 h of exposure. The results showed that the metals under study are toxic to C. carpio embryos and that their interaction modifies the toxic response. Thus, iron generates alterations in the activity of antioxidant enzymes and modification in embryonic development to a lesser extent than aluminum and the mixture of metals, while mercury exerts its toxicity on embryos by mechanisms other than oxidative stress, but the modification to the activity of antioxidant enzymes may contribute to the changes observed in embryonic development. The changes in the response of biomarkers of embryotoxicity and oxidative stress suggest that the combination of metals produces an antagonism-type interaction, so this study provides a precedent for future research to determine the type of interaction that a mixture of contaminants generates in developing aquatic organisms. Graphical abstract
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CHINESE JOURNAL OF POLYMER SCIENCE
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2021
·Vol. 39
·期 10
·1299-1309
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IF 3.603
Wu Hai-Tao,Jin Bi-Qiang,Wang Hao,Wu Wen-Qiang,Cao Zhen-Xing,Yuan Zhao-Yang,Huang Yue,Li Wei-Hang,Huang Guang-Su,Liao Lu-Sheng,Wu Jin-Rong
Elastomers with outstanding strength, toughness and healing efficiency are highly promising for many emerging fields. However, it is still a challenge to integrate all these beneficial features in one elastomer. Herein, an asymmetric alicyclic structure adjacent to aromatic disulfide was tactfully introduced into the backbone of polyurethane (PU) elastomer. Specifically, such elastomer (PU-HPS) was fabricated by polycondensing polytetramethylene ether glycol (PTMEG), isophorone diisocyanate (IPDI) and p -hydroxydiphenyl disulfide (HPS) via one-pot method. The molecular mobility and phase morphology of PU-HPS can be tuned by adjusting the HPS content. Consequently, the dynamic exchange of hydrogen and disulfide bonds in the hard segment domains can also be tailored. The optimized sample manifests outstanding tensile strength (46.4 MPa), high toughness (109.1 MJ/m 3 ), high self-healing efficiency after fracture (90.3%), complete scratch recovery (100%) and good puncture resistance. Therefore, this work provides a facile strategy for developing robust self-healing polymers.
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ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
·
2021
·Vol. 28
·期 46
·65487-65498
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IF 4.223
Zhou
Jiacheng,Shen Qicheng,Yang Jie,Tariq Muhammad,Sun Wei,Cao Limei,Yang Ji
Co 3 O 4 is a promising Hg 0 removal catalyst for industrial application. Operating temperature and low sulfur resistance are two of the main problems that hinder its industrial application in Hg 0 removal. Herein, a metal-organic framework (Co-BDC) was introduced as a sacrificial template to obtain the catalyst nano-sized Co 3 O 4 @C by calcination. Part of the organic ligands is carbonized during the calcination. Carbon wrapped Co 3 O 4 and reduced metal agglomeration. The optimal Hg 0 removal temperature of the existing cobalt oxide catalysts was always around 150 °C, but H 2 -TPR showed that the oxygen atoms on the Co 3 O 4 @C were more active than those on Co 3 O 4 , causing the Hg 0 removal temperature window of Co 3 O 4 @C to shift to lower temperatures. The Hg 0 removal efficiency of Co 3 O 4 @C could reach almost 100% even at 25 °C. In the meanwhile, Co 3 O 4 @C also showed a strong SO 2 resistance at ambient temperature. Experimental results and characterization proved that SO 2 did not compete with Hg 0 on the surface of Co 3 O 4 at low temperatures. On the contrary, it participated in the oxidation of Hg 0 . This is a great improvement for Co 3 O 4 catalyst in Hg 0 removal. It reduces the restrictions on the application of Co 3 O 4 in Hg 0 removal. Co 3 O 4 @C shows considerable potential as an Hg 0 removal catalyst.
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PubMed
高影响因子
COLLOID AND POLYMER SCIENCE
·
2021
·Vol. 299
·期 9
·1459-1468
·
IF 1.931
Guan Peiwen,Ren Cong,Shan Houchao,Cai Di,Zhao Peimian,Ma Dongze,Qin Peiyong,Li Shufeng,Si Zhihao
To meet the increasing requirements toward biobutanol, pervaporation membrane with high separation performance needs to be developed. In this work, a hydrophobic MAF-6 (RHO-[Zn(eim) 2 ]) was synthesized and its adsorption properties for 1-butanol was systematically studied, which are supposed to benefit the separation performance of polydimethylsiloxane (PDMS) membrane. The hydrophobic MAF-6 particles were therefore doped into PDMS to fabricate mixed matrix membrane. The morphology, chemical structure, and other properties of particles and hybrid membrane were fully studied by SEM, PXRD, FT-IR, TGA, and BET. Results demonstrate that the hydrophobicity of PDMS membrane is improved with the water contact angle increasing from 112.7° to 118.1° after being doped with MAF-6, as well as enhanced adsorption ability toward 1-butanol. More importantly, when doping MAF-6 into PDMS layer, the enhancements of 23.30% and 41.93% are separately observed in the separation factor and total flux to separate 1.5 wt% 1-butanol solution, compared with the PDMS membrane. In addition, the heat energy consumption of pervaporation process is decreased from 4.27 to 3.71 kJ g −1 via the doping of MAF-6. Overall, this work confirms that the hydrophobic particle such as MAF-6 is not only conductive to enhance the separation performance of PDMS membrane but also helpful to decrease the energy consumption.
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高影响因子
Journal of Inorganic and Organometallic Polymers and Materials
·
2021
·Vol. 31
·期 11
·4195-4208
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IF 3.543
Wang Lulu,Zeng Xiangrui,Wang Haiyan,Wang Yujia
Abstract A series of porous confined ionic liquid phosphotungstate were synthesized by encapsulated of N-(3-sulfopropyl)morpholinium phosphotungstate ([C 3 SO 3 Hnhm] 3 -PW 12 O 40 ) into MIL-101. Then the aforementioned porous confined ionic liquid phosphotungstate as heterogeneous catalyst will be used together with H 2 O 2 for the catalytic synthesis of adipic acid from cyclohexene. During the experiment, the effect of weight content of [C 3 SO 3 Hnhm] 3 PW 12 O 40 on the catalytic performance was investigated in detail. And the chemical structure of the catalyst was also characterized by XRD, FT-IR, 1 H-NMR, SEM–EDX and N 2 adsorption–desorption isotherms. Experimental results revealed that the desired products has been successfully prepared, and the best catalytic performance (81.2% yield of the adipic acid) was obtained under the dose of [C 3 SO 3 Hnhm] 3 PW 12 O 40 was 31wt%, which was almost close to the catalytic activity of original [C 3 SO 3 Hnhm] 3 PW 12 O 40 (85.3% yield of the adipic acid), which was also proved the strategy of packaging ionic liquid phosphotungstate with MIL-101 in this research is feasible. Furthermore, recycled catalytic performance of the catalyst under repeat 6 times was evaluated and the result revealed that the yield in adipic acid was still higher than 80.0%, which also proved that the catalytic active component was stable in the catalyst. Graphic Abstract
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Advanced Composites and Hybrid Materials
·
2021
·Vol. 4
·期 4
·1292-1301
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IF 5.693
Zhang Pengxiang,Zhang Xihua,Li Bin,Xu Lingan,Dang Feng,Li Bao-Wen
Improving the interfacial impedance matching and attenuation ability of a microwave absorber is an important strategy to obtain excellent microwave absorbing performance. Here, we prepared an ultralight, hierarchical porous single-atom Co–N–C microwave absorber, in which evenly distributed single-atom Co is anchored in a porous N-doped carbon framework by N–Co bond via a facile bio-inspired method. These doped single atoms provide abundant highly active atomic absorption sites on the carbon skeleton, and considerable defects including pyridinic-N, pyrrolic-N, oxidized N, and so forth are introduced into the carbon framework owing to single Co atom doping. These doped single Co atoms and introduced defects act together as strong dipolar/interfacial polarization units, which lead to better impedance matching and a significant increase in attenuation capability of the absorber. The metal Co exists in form of a single atom, benefiting light weight of the absorber. Therefore, an extremely strong reflection loss (RL) value of − 60.9 dB is achieved at a lower filler content of 10 wt% with the absorber thickness of 2.5 mm, and the effective frequency bandwidth covered from 10.4 to 15.1 GHz with a thickness of 2.0 mm at a low filler content of 10 wt%. This research offers a novel route for designing a microwave absorber to improve microwave absorption performance and is expected to a wider range of absorbing materials with different structures. Graphical abstract
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Science China-Technological Sciences
·
2021
·Vol. 64
·期 9
·2023-2032
·
IF 3.572
Pang Long,Zhong Wei,Wang QiuBo,Feng HaoHui,Dong HaoNan,Wang Song,Cong HaiLin,Shen YouQing,Yu Bing
Disulfide (DSF) has been proved good anti-tumor effect and even better with coadministration of Cu 2+ . In this work, we report the use of hyaluronic acid (HA) based materials to construct vectors for the delivery of both DSF and Cu 2+ . HA was firstly modified with polyethylene glycol monomethyl ether (mPEG) and polycaprolactone (PCL) to synthesize an amphiphilic polymer (HA-PEG-PCL). DSF could be loaded in the hydrophobic core and Cu 2+ could be cooperated to the negative hydrophilic segment. The Cu 2+ also played a role as crosslinking agent, which prevented DSF leakage prematurely, avoiding the bad side effects to normal tissues. The interaction between HA and CD44 improved the distribution of nanodrugs in tumor cells. When the nanodrugs were delivered to the cancer cell, the acidic micro-environment would separate the Cu 2+ from the surface, leading to the disintegration of the micelles, promoting the release of DSF from the micelle core. The results of in vitro and in vivo experiments showed that the DSF and Cu 2+ co-delivery vector constructed in this work could enhance the antitumor effect and have low biological toxicity.
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高影响因子
FIBERS AND POLYMERS
·
2021
·Vol. 22
·期 12
·3298-3308
·
IF 2.153
Wen Wen,Zhang Zaixing,Jing Lingxiao,Zhang Tonghua
Due to the structure of hierarchical aligned cellulose fibrils, cotton fabric used in clothing possesses excellent moisture and thermal managements. Such structure yet may retain metabolic excrements and sebum secretions discharged from the human skin, which reproduce microorganisms harmful for human health. However, incorporating the antimicrobial coating into the cotton fabric can sufficiently resist the microorganism growth. In this work, a water-soluble antibacterial coating named N-(4-(allyloxy) benzylidene)-2-(piperazin-1-yl) ethanamine (NABPE) was synthesized to produce a rechargeable and fast sterilization cotton fiber fabric (M-cotton/NABPE). M-cotton/NABPE exhibited a high effective antibacterial activity, and the inhibition ratios against Escherichia coli ( E. coli ) and Staphylococcus aureus ( S. aureus ) were 94 % and 93 %, respectively. Chlorination was performed with sodium hypochlorite solution to form N-Cl bond on the M-cotton/NABPE fabrics, resulting in a high biocidal efficacy of up to 100 % via contact killing for a duration of 5 min. After 25 washing cycles, the antibacterial fabric still maintained an antibacterial rate of 91.95 % and 92.15 % against E. coli and S. aureus , respectively. Furthermore, the fabrics showed integrated properties of excellent UV stability, long-term stability, robust rechargeable biocidal activity (chlorine recharging >5000 ppm) and washing durability. This research provides fundamental insights into the synthesis of the NABPE and prolonged biocidal efficacy of the M-cotton/NABPE, and thereby pave a pathway to incorporate an economic and environmental-friendly antibacterial coating suitable for finishing cotton fabric.
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JOM
·
2021
·Vol. 73
·期 11
·3451-3459
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IF 2.474
Chen Ben,Li Zhi-Bo,Zhang Guo-Hua,Chou Kuo-Chih
To improve the performance of Mo-based cermets, Mo-(Ni)-Al 2 O 3 cermets were prepared with raw materials of nano-sized Al 2 O 3 powder. The effects of Al 2 O 3 and Ni additions on the densification behavior, microstructure, bending strength, and hardness of the Mo-(Ni)-Al 2 O 3 cermets were experimentally analyzed. The results showed the content of Al 2 O 3 had a great influence on the degree of densification of Mo-Al 2 O 3 cermets at the sintering temperature of 1600°C. In addition, the Al 2 O 3 particles were distributed evenly in the matrix of Mo-based cermets, which refined the grains of Mo and increased the hardness of cermets. Because of the weak interfacial bonding strength between Al 2 O 3 ceramic phase and Mo metal phase, the bending strength decreased continuously with increasing Al 2 O 3 content. However, Ni addition improved the wetting and adhesion of Al 2 O 3 and Mo. With the addition of Ni, the relative density increased, and thus hardness and bending strength were improved.
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