SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
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2023
·
IF 4.4
Tao Xu,Rongyan Wang,Chenjie Gu,Tao Jiang
Surface-enhanced Raman scattering (SERS) technology enables to satisfy the increasing demand of clinical drug monitoring due to the superiority of fingerprint recognition, real-time response, and nondestructive collection. Here, a novel graphitic carbon nitride (g-C 3 N 4 )/ molybdenum disulfide (MoS 2 )/Ag composite substrate with a 3D surface structure was successfully developed for the recyclable detection of gefitinib in serum. Attributed to the uniform and dense “hotspots” on the shrubby active surfaces in conjunction with the potential synergistic chemical enhancement of g-C 3 N 4 /MoS 2 heterosystem, a remarkable SERS sensitivity with an attractive enhancement factor value of 3.3 × 10 7 was demonstrated. Meanwhile, a type-II heterojunction between g-C 3 N 4 and MoS 2 enabled more efficient diffusion of photogenerated e − -h + pairs assisted by the localized surface plasmon resonance of Ag NPs, which contributed to the reliable recyclable detection of gefitinib. The ultra-low limit of detection at 10 −5 mg/mL and high recycling rates of gefitinib beyond 90% in serum were successfully realized. The results demonstrated the as-prepared SERS substrate has tremendous potential to be untilized for in-situ drug diagnostics.
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APPLIED SURFACE SCIENCE
·
2023
·
IF 6.7
Rui Li,Shuoyang Liang,Aikelaimu Aihemaiti,Shun Li,Zuotai Zhang
Piezocatalysis technology is emerging as a promising strategy for removing organic pollutants from water by harvesting mechanical energy from the surrounding environment. Herein, 2H-MoS 2 flower-like nanosheets with tunable S vacancies was synthesized via a hydrothermal method by adjusting pH of the precursor solution, Mo and S molar ratio, reaction time and temperature. The results showed that the presence of S vacancy leads to significantly enhanced piezoelectric response in the MoS 2 nanosheets, as confirmed by both theoretical calculation using first-principle based density functional theory and probe force microscopy (PFM) measurements. As a result, the as-obtained MoS 2 nanoflower piezocatalyst exhibited excellent degradation efficiency for Orange Ⅱ solution (removal rate > 95 % in 1 h) under ultrasonic vibration (40 kHz and 110 W). Importantly, we demonstrated for the first time that the piezocatalytic performance was tightly related with the water level in ultrasonic cleaner. The present work not only reports a simple and effective strategy for improving the piezocatalytic degradation activity of MoS 2 by introducing vacancy, but also provides new insights and deeper understanding on the underlying mechanism.
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ACS Applied Nano Materials
·
2023
·
IF 5.9
Li Liu,Yang Gao,Qinghua Hu
Constructing heterogeneous interfaces on a nanoscale that can prominently improve the gas-sensing properties has been comprehensively reported. However, the effect of parallel heterostructures formed by unique synthetic means on nitrogen dioxide room-temperature sensing properties still needs to be clarified, which hinders the development of heterostructured hybrid materials in the field of gas sensing. In this study, large-sized MoS2 was parallel-wrapped on the surface of nanoscale Bi2S3 rods, and then, the Bi2S3/MoS2 nanocomposite aerogels were formed by freeze drying and calcination. The NO2 sensing performance of the hybrids and possible surface processes at room temperature have been investigated and deduced. The as-prepared nanocomposite aerogels (Bi2S3/MoS2-2) exhibited a larger specific surface area, a mass of active defect sites, and a higher charge density, thus possessing 15- and 20-times higher response than that of pristine MoS2 nanosheets and Bi2S3 nanorods, respectively. This study provides an efficient way to synthesize large-area parallel heterostructures between two bis-sulfides (Bi2S3 and MoS2), leading to excellent NO2 gas sensing performance.
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ACS Applied Nano Materials
·
2023
·
IF 5.9
Xiaorong Gan,Jianlin Zhang,Jiabei Liu,Yuanhe Bai,Xinyi Su,Weiqing Wang,Zhuang Cao,Huimin Zhao,Yanhui Ao,Peifang Wang
Simultaneously improving electron and mass transfer processes is full of challenges for electrode material design. To this end, three-dimensional (3D) porous electrode materials were obtained via covalent combination between defective 1T-MoS2 nanosheets and polyaniline (PANI) through hydrothermal/solvothermal processes and surface polymerization reactions. Our experimental results and density functional theory calculations jointly reveal that PANI molecules can not only intercalate into van der Waals (vdW) gaps of 1T-MoS2 nanosheets but also chemically adsorb onto S-vacancy clusters (via Mo–N covalent bonds), rather than single atomic S-vacancies due to steric effects. Similarly, the geometric structure of PANI in the vdW gaps of 1T-MoS2 nanosheets possesses a flat-lying configuration for better stability. Compared to surface functionalization, interlayer intercalation has more profound effects on electronic structures for improving electrochemical properties, including reduced band gaps, small effective electron masses, and high mobility. As a proof-of-concept application, the 1T-MoS2–PANI nanocomposites were used to construct an electrochemical sensor for trace Cu2+, which exhibits high sensitivity and selectivity with a wide linear range from 3 to 450 nM and a low detection limit because of excellent conductivity, a low contact barrier against electron transfer, high mass transfer, and strong coordination interactions between PANI and Cu2+.
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JOURNAL OF COLLOID AND INTERFACE SCIENCE
·
2023
·
IF 9.9
Kunjie Wang,Yan Jing,Shuang Gao,Xianrong Liu,Bingxin Liu,Yongcheng Li,Peng Zhang,Benhua Xu
Implanting the octahedral phase (1 T) into the hexagonal phase (2H) of the molybdenum disulfide (MoS 2 ) matrix is considered one of the effective methods to enhance hydrogen evolution reaction (HER) performances of MoS 2 . In this paper, hybrid 1 T/2H MoS 2 nanosheets array was successfully grown on conductive carbon cloth (1 T/2H MoS 2 /CC) via facile hydrothermal method and the 1 T phase content in 1 T/2H MoS 2 is regulated to gradually increase from 0 % to 80 %. 1 T/2H MoS 2 /CC with 75 % 1 T phase content exhibits optimal HER performances. The DFT calculation results show that S atoms in 1 T/2H MoS 2 interface exhibit the lowest hydrogen adsorption Gibbs free energies (ΔG H* ) compared with other sites. The improvement of HER performances are primarily attributed to activating the in-plane interface regions of the hybrid 1 T/2H MoS 2 nanosheets. Furthermore, the relationship between 1 T MoS 2 content in 1 T/2H MoS 2 and catalytic activity was simulated by a mathematical model, which shows that the catalytic activity presents a trend of increasing and then decreasing with the increase of 1 T phase content.
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JOURNAL OF HAZARDOUS MATERIALS
·
2023
·
IF 13.6
Enya Wu,Yang Yu,Jiayue Hu,Gang Ren,Mingshan Zhu
The conjugation of membrane filtration (MF) with advanced oxidation process (AOPs) is being considered as an alternative advanced treatment process for the potable reuse of wastewater. Beyond conventional MF/AOPs conjugation, a new downstream MF process with piezoelectric-channels induced piezo-activated peroxymonosulfate (PMS) is herein constructed to deal with antiepileptic carbamazepine (CBZ) pollutants through polyvinylidene fluoride (PVDF) membrane (PVDF-M10). Through a MF process, ca. 93.8% CBZ pollutants can be removed under an ultrasonic-assisted piezo-activation PMS, whereas only 18.3% and 60.2% CBZ can be removed by using pure PVDF membrane under the same condition and PVDF-M10 membrane without ultrasonic-assisted piezo-activation. Even after 9-cycles, CBZ removal efficiency was maintained at 56.4% under this MF process. These superior performances are attributed to the piezoelectric exfoliated-MoS 2 nanosheets (E-MoS 2 ) embedded PVDF nanofibers in PVDF-M10 membrane, which lead to rich piezoelectric-channels in the membrane. These piezoelectric-channels not only produced more charges to activate PMS to boost the yield of reactive oxide species (ROS) but also provided an ideal platform for the rapid reaction between CBZ and ROS during MF process. This investigation develops a new MF technique to conjugate piezo-activation of PMS-AOPs for the efficient removal of emerging pollutants for the potable reuse of wastewater.
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高影响因子
SENSORS
·
2023
·Vol. 23
·期 11
·5218
·
IF 3.9
Huiji Chen,Binbin Luo,Shengxi Wu,Shenghui Shi,Qin Dai,Zehua Peng,Mingfu Zhao
Simple SummaryA microfluidic biosensor based on a thin-core microfiber coated with molybdenum disulfide for immune detection ofToxoplasma gondiiwas illustrated. The detection range, limit of detection, detection sensitivity, specificity, and clinical properties of the proposed biosensor were explored.AbstractToxoplasma gondii(T. gondii) is a zoonotic parasite that is widely distributed and seriously endangers public health and human health. Therefore, accurate and effective detection ofT. gondiiis crucial. This study proposes a microfluidic biosensor using a thin-core microfiber (TCMF) coated with molybdenum disulfide (MoS2) for immune detection ofT. gondii. The single-mode fiber was fused with the thin-core fiber, and the TCMF was obtained by arc discharging and flame heating. In order to avoid interference and protect the sensing structure, the TCMF was encapsulated in the microfluidic chip. MoS2andT. gondiiantigen were modified on the surface of TCMF for the immune detection ofT. gondii. Experimental results showed that the detection range of the proposed biosensor forT. gondiimonoclonal antibody solutions was 1 pg/mL to 10 ng/mL with sensitivity of 3.358 nm/log(mg/mL); the detection of limit was calculated to be 87 fg/mL through the Langmuir model; the dissociation constant and the affinity constant were calculated to be about 5.79 × 10−13M and 1.727 × 1014M−1, respectively. The specificity and clinical characteristics of the biosensor was explored. The rabies virus, pseudorabies virus, andT. gondiiserum were used to confirm the excellent specificity and clinical characteristics of the biosensor, indicating that the proposed biosensor has great application potential in the biomedical field.Keywords:thin-core microfiber;microfluidic chip;molybdenum disulfide;optical fiber biosensor;toxoplasma gondii
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高影响因子
ANALYST
·
2023
·Vol. 148
·期 8
·1732-1742
·
IF 4.2
Chonghui Wei,Xuan Xie,Yue Mou,Shiqi Cheng,Jin Yang,Kaixin Xue,Kewei Yu,Xinru Lin,Chunfen Zhang,Yujie Zhao,Xingyu Luo,Yilin Wang
Dopamine (DA) plays an essential role in dopaminergic neuronal behavior and disease. However, current detection methods for discriminating the secretion of DA are hampered by the limitations of the requirement for bulky instrumentation and non-intuitive signals. Herein, we have controllably and proportionately integrated molybdenum disulfide (MoS2) with titanium dioxide (TiO2) to prepare MoS2@TiO2 nanocomposites (MoS2@TiO2 NCs) via a facile synthesis method. MoS2@TiO2 NCs with a certain reactant mass ratio have shown a significant enhancement in peroxidase-like activity with superiority of the nanocomposite structure compared to single MoS2 or natural enzyme. The method for catalyzing the decomposition of H2O2 by MoS2@TiO2 NCs and competition for hydroxyl radicals (˙OH) between the chromogenic agent and DA enable a sensitive, specific, and colorimetric DA analysis with a low detection limit of 0.194 μM and a wide linear detection range (0.8 to 100 μM). Because of the favorable detection performance, we were encouraged to explore and finally realize the visual detection of cellular DA secretion that is stimulated in a High-K+ neurocyte environment. Collectively, this method will provide a promising strategy for basic research in neuroscience with its portable, sensitive, and naked-eye detectable performance.
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Small
·
2023
·Vol. 19
·期 26
·2208291
·
IF 13.3
Guangsheng Dong,Lixin Li,Kai Zhu,Jun Yan,Guiling Wang,Dianxue Cao
MoS 2 , as a classical 2D material, becomes a capable anode candidate for sodium-ion batteries. However, MoS 2 presents a disparate electrochemical performance in the ether-based and ester-based electrolyte with unclear mechanism. Herein, tiny MoS 2 nanosheets embedded in nitrogen/sulfur-codoped carbon (MoS 2 @NSC) networks are designed and fabricated through an uncomplicated solvothermal method. Thanks to the ether-based electrolyte, the MoS 2 @NSC shows a unique capacity growth in the original stage of cycling. But in the ester-based electrolyte, MoS 2 @NSC shows a usual capacity decay. The increasing capacity puts down to the gradual transformation from MoS 2 to MoS 3 with the structure reconstruction. Based on the above mechanism, MoS 2 @NSC demonstrates an excellent recyclability and the specific capacity keeps around 286 mAh g −1 at 5 A g −1 after 5000 cycles with an ultralow capacity fading rate of only 0.0034% per cycle. In addition, a MoS 2 @NSC‖Na 3 V 2 (PO 4 ) 3 full cell with ether-based electrolyte is assembled and demonstrates a capacity of 71 mAh g −1 , suggesting the potential application of MoS 2 @NSC. Here the electrochemical conversion mechanism of MoS 2 is revealed in the ether-based electrolyte and significance of the electrolyte design on the promoting Na ion storage behavior is highlighted.
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高影响因子
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
·
2023
·
IF 4.5
Dong Liu,Qingfa Gong,Xixi Xu,Shuyun Meng,Yuye Li,Tianyan You
Photoelectrochemical (PEC) aptasensing has been extensively studied for hazardous material (e.g., pesticide residue) detection, with investigation on photoactive materials being their main focus of study. Herein, a cascade Z-scheme [email protected] 2 ( [email protected] 2 ) heterostructure was designed to fabricate a PEC aptasensor for carbendazim (CBZ) detection in tomato. The [email protected] 2 heterostructure was prepared by taking advantage of electrostatic adsorption between components. The cascade Z-scheme electron transfer was verified in [email protected] 2 , resulting in a significantly enlarged photocurrent (e.g., 2.7-fold higher of that at CdTe/MoS 2 ) for the efficient separation of electron-hole pair. The PEC aptasensor was developed based on the principle that the specific binding of aptamer to target on the surface of [email protected] 2 increased the steric hindrance for electron transfer, facilitating a “signal-off” detection mode for CBZ. The fabricated aptasensor offered a linear range of 0.523–5230 nM (0.1–100 ng mL −1 ) with a detection limit of 1.74 × 10 -10 M (0.033 ng mL −1 ) for CBZ detection, and it was successfully applied to tomato sample analysis. This work will stimulate exploration of cascade Z-scheme materials for sensing, and provides a high-performance PEC sensing platform for the detection of various species.
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Virtual and Physical Prototyping
·
2023
·
IF 10.6
Pei Feng,Saipu Shen,Liuyimei Yang,Ye Kong,Sheng Yang,Cijun Shuai
Graphene oxide (GO) and molybdenum disulphide (MoS2), have drawn more and more attention as reinforcement in polymer. However, their large specific surface area and strong van der Waals forces result in serious aggregations in polymer matrix, which restrains the reinforcement effect. In this study, MoS2 nanosheets were in situ synthesised vertically and uniformly on the surface of GO nanosheets with the help of a hexadecyl trimethyl ammonium bromide (CTAB) assisted hydrothermal process to facilitate their dispersion in polylactic acid (PLLA) scaffold manufactured via selective laser sintering (SLS). The experimental results revealed that the 1.5 wt% GO/MoS2 nanocomposite exhibited better dispersion state compared with the 1.5 wt% GO and 1.5 wt% MoS2 in PLLA matrix. Therefore, the PLLA scaffold loading 1.5 wt% GO/MoS2 presented 10.2 and 1461 MPa of tensile strength and modulus with enhancement of 61% and 58%, respectively, compared with the pure PLLA scaffold. The reinforcement mechanisms mainly included crack deflection, crack bridging, crack pinning and pulling out of GO/MoS2. What’s more, the GO/MoS2-PLLA scaffold possessed benign cytocompatibility for cell behaviour, suggesting hopeful applications in bone defect repair.
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Inorganic Chemistry Frontiers
·
2019
·Vol. 6
·期 2
·590-597
·
IF 5.934
Xiaoqing Cui,Wei Liu,Weihua Gu,Xiaohui Liang,Guangbin Ji
In recent years, two-dimensional inorganic materials (MoS2) have been promising candidates for EM wave absorber because of their high specific surface area, excellent electronic properties and dielectric loss caused by polymorphism. Nevertheless, the poor impedance matching of individual MoS2 limited its microwave absorption performance. Optimizing the impedance matching of microwave absorber can be an effective way to achieve electromagnetic wave attenuation. In this study, we deposited CoFe2O4 magnetic nanoparticles on the surface of MoS2 nanosheets using reasonable hydrothermal reactions to optimize its poor impedance and enhance interfacial polarization. The MC-6 composite (mMoS2 : mCoFe2O4 = 6 : 1) exhibited excellent microwave absorption capability. The minimum reflection loss (RL) reached −55.3 dB at 16.24 GHz (Ku band) and the effective absorption bandwidth (<−10 dB) was measured to be 6.26 GHz (X band) with a thickness of 1.6 mm. This study confirms that optimizing impedance matching and interfacial polarization of MoS2-based composites play a key role in the microwave response. Moreover, the reasonable optimization of impedance matching enables regulation of the effective bandwidth and strong absorption intensity.
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