INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
·
2025
·
IF 3.9
Yuhao Yang,Chunhua Wang,Jiani Cai,Ying-Ya Liu,Zhiquan Yu,Zhichao Sun,Yao Wang,Anjie Wang,Chong Peng
Selective hydrogenation of phenol to cyclohexanone is of great significance for the production of value-added chemical intermediates and products. Pd/MIL-100(Cr), featuring highly dispersed Pd nanoparticles (∼2.5 nm), were synthesized using a double-solvent impregnation method followed by NaBH4 reduction. During aqueous-phase phenol hydrogenation, the catalyst achieved full conversion with 98.3% selectivity toward cyclohexanone within 1 h at 0.1 MPa and 100 °C. The catalyst exhibited high stability, maintaining performance up to 5 cycles without deactivation. The Lewis acidity of MIL-100(Cr) significantly influenced the phenol hydrogenation selectivity. By incorporation of Al, V, and Ce species into the MIL-100(Cr) framework, cyclohexanone selectivity in phenol hydrogenation was found to increase with the amount of Lewis acid sites (LAS). The acid properties of the Pd/MIL-100 catalysts were investigated using NH3-TPD, pyridine-adsorbed FT-IR, and EPR probe molecules. The interaction between Pd nanoparticles and the coordinatively unsaturated sites from the trimeric clusters of MIL-100 was found to be crucial in determining the Lewis acidity of the Pd/MIL-100 catalysts. Demonstrating a synergistic effect between the Pd and LAS, Pd/MIL-100(Cr) emerges as a promising candidate for the selective hydrogenation of phenol to cyclohexanone.
✓ 已验证
产品关联
DOI
高影响因子
Biomedical Physics & Engineering Express
·
2024
·Vol. 10
·期 4
·045004
·
IF 1.3
Mingjia Feng,Yan Li,Yanfang Sun,Tianqi Liu,Khaydar E Yunusov,Guohua Jiang
The transdermal drug delivery based on microneedles (MNs) provides a suitable and painless self-administration for diabetic patients. In this work, the hydrogel-forming MNs were firstly fabricated using poly(vinyl alcohol) (PVA) and chitosan (CS) as matrix. A hypoglycemic drug, metformin (Met), had been loaded into MIL-100(Fe). Then, both of free Met and Met-loaded MIL-100(Fe) were integrated into hydrogel-forming MNs for regulation of blood glucose levels (BGLs) on diabetic rats. After penetrated into the skin, the free Met could be firstly released from MNs. Due to the absorption of interstitial fluid and subsequent release of loaded Met from MIL-100(Fe), leading to a sustainable and long-term drug release behaviors. A notable hypoglycemic effect and low risk of hypoglycemia could be obtained on diabetic rat models in vivo. The as-fabricated hydrogel-forming MNs expected to become a new type of transdermal drug delivery platform for transdermal delivery of high-dose drugs to form a long-term hypoglycemic effect.
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY
·
2024
·
IF 3.1
Tao Yang,Huiyang Yu,Zhi-Yong Zhu,Rui Ding,Jin Wang,Bi Zhu
Nickel isotopes have been employed to trace various processes such as the weathering of mafic and ultramafic rocks, mineral adsorption and co-precipitation, and the metabolism of methanogenic archaea. Nickel isotopes have displayed significant potential for application, regardless of whether the processes occur at high or low temperatures. However, the currently employed nickel isotope separation methods have certain limitations in terms of separation effectiveness, blank contribution, separation efficiency, and cost-effectiveness of the resin used. Therefore, in this study, we have devised a user-friendly three-step chromatographic procedure that relies on the Chelex-100 resin for the efficient isolation and purification of nickel from a wide array of geological samples. The three resins utilized in this procedure are Chelex-100, AGMP-1, and AGMP-50. It is worth noting that Chelex-100 has exhibited exceptional performance in eliminating alkali metals, alkaline earth metals, and iron. Following chromatographic separation, the recovery of nickel surpassed 96%, with a procedural blank below 1.2 ng. To evaluate the procedure's effectiveness, we conducted nickel isotope measurements on nine geological reference materials (BCR-2, GSR-3, GSP-2, NOD-A-1, GSMC-1, SGR-1, SDO-1, GSD-5, and GSD-23) using MC-ICP-MS. The obtained values were consistent with previously published data, confirming the reliability of our results. The findings of our study establish the applicability of the developed separation procedure for nickel isotope analysis in various geological samples.
✓ 已验证
产品关联
DOI
高影响因子
CHROMATOGRAPHIA
·
2024
·
IF 1.2
Shao Xiaozhen,Xu Guangfu,Chen Jiaquan,Miao Pandeng,Yang Ke,Du Yingxiang,Yu Tao
Metal–organic frameworks (MOFs) have a wide range of applications in separation and analytical sciences due to their unique structures. MIL-100(Fe) was immobilized on the inner wall of the capillary column based on the immobilized cysteine (Cys)-triggered in situ growth (ICISG) strategy. By applying this column to capillary electrophoresis, a novel enantioselective separation system based on MIL-100(Fe) nanomaterial was established. By utilizing lactobionic acid (LA) as the chiral selector and optimizing the experimental conditions such as buffer pH, LA concentration and the methanol addition ratio, the CEC system demonstrated a significantly enhanced enantioseparation ability for six basic drugs. The modified capillary column was characterized by scanning electron microscope (SEM), energy-dispersive X-ray spectroscope (EDS) and X-ray diffractometer. The experimental results showed that MIL-100(Fe) was successfully grown on the inner wall of the capillary column. In the present study, the repeatability of the coated column was investigated and the relative standard deviations (RSDs) of the resolution and the migration time for intra-day, inter-day and inter-column were within 8%, proving the good repeatability of the coated column.
✓ 已验证
产品关联
DOI
高影响因子
MICROCHIMICA ACTA
·
2025
·Vol. 192
·期 3
·1-10
·
IF 5.3
Han Hongyu,Huang Yiqun,Miao Junjian,Lai Keqiang
Surface-enhanced Raman spectroscopy (SERS) was combined with stoichiometric analysis to synthesize a AuNPs@MIL-100 (Fe) SERS substrate. This high-performance, and low-cost metal–organic framework-based SERS nano sensor is capable of detecting malachite green (MG) residues in fish. The minimum detectable concentration of MG in standard solutions is 0.1 μg/L, while in fish samples, the detection range spanned from 0.003–0.088 μg/kg. The partial least squares regression (PLSR) and support vector machine regression (SVR) were applied to model the SERS data, enhancing both the precision and reliability of the detection. The results show that compared with the traditional linear regression and PLSR models, the prediction accuracy of the SVR model is an improvement with higher stability. MG standard solutions and three fish samples can be analysed directly or after simple extraction. This method can be used to detect trace harmful substances in different aquatic products. Graphical
✓ 已验证
产品关联
DOI
PubMed
高影响因子
BIORESOURCE TECHNOLOGY
·
2025
·
IF 9
Hong-li Ma,Ming-fu Li,Ying-chuan Zhang,Qing-hua Huang,Li-qun Jiang,Zhen Fang
The hydrolysis of levoglucosan (LG)–the major component of biomass pyrolysis oil–is the crucial step to bridge pyrolysis and fermentation. This study reports a series of sulfonated carbon catalysts (SCCs) as sustainable Brønsted acids for LG hydrolysis, which exhibit an excellent glucose selectivity over other hydration products ( e.g., 5- hydroxymethylfurfural and light oxygenates). Notably, SCCs maintain a LG conversion rate of 95 % and a glucose yield of 90 % afterfour cycles of batch operations. Time-of-flight mass spectrometry and theoretical calculations further clarify the hydrolysis mechanism, as water-derived protons are activated by sulfonate groups of SCCs and hydrolyze LG through C O bond cleavage and hydration. Moreover, SCC-catalyzed hydrolysate is used in fermentation to produce bioethanol, enabling the maximal yield of ∼ 99 %, which is comparable to pure glucose commodity and much efficient than that from the aqueous acid hydrolysis. This study provides a sustainable alternative to mitigate the demand on heterogeneous catalysts for pyrolysis oil upgrading towards net-zero production of biofuels and biochemicals.
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF CATALYSIS
·
2025
·
IF 6.5
Qi Chen,Xingxing Huang,Cheng Liu,Yueling Chen,Jionghua Wu,Jimmy C. Yu,Ling Wu
The attainment of rapid charge mobility and effective N 2 activation is of critical importance for photocatalytic nitrogen fixation but it has always been a challenge. Such challenge may be met by the construction of a Type II MoS 2 nanoparticles/ MIL-100(Fe) heterojunction photocatalyst. The new material possesses charge migration channels that facilitate the separation of photogenerated carriers. This charge redistribution during photocatalysis is confirmed by experimental results showing a decrease of charge density on the Fe species and an increase of that on Mo. Moreover, DFT calculations show that the adsorption of N 2 and H 2 O is more likely to occur on Fe sites and Mo sites, respectively. These findings clearly suggest a drastically improved spatial isolation of reduction and oxidation sites on the photocatalyst as compared to pristine MIL-100(Fe). The optimized MoS 2 /MIL-100(Fe) exhibits a NH 4 + yield rate of 1.29 μmol·h −1 as excellent utilization of photoinduced electron-hole pairs and effective adsorption and activation of N 2 become possible. This work offers an insight on the synergy of heterojunction engineering with coordinated activation for photocatalytic ammonia synthesis.
✓ 已验证
产品关联
DOI
高影响因子
SEPARATION AND PURIFICATION TECHNOLOGY
·
2025
·
IF 9
Chiyu Wen,Chao Wang,Defang Liu,Zhuo Cheng,Jing Zhao,Hongli Zhang,Jun Wang,Guoxiang Zhu,Yongfa Zhu
Nitro-aromatic compounds constitute predominant explosive materials extensively utilized in military applications and industrial blasting operations. However, the manufacturing, consumption, and decommissioning of these explosives generate significant quantities of wastewater exhibiting both ecotoxicological hazards and explosive potential. Herein, an amino-functionalized MIL-100(Fe) (AFM) catalyst demonstrating simultaneously enhanced explosive capture and degradation is developed. The synergistic interplay of electrostatic attraction and hydrogen bonding between the amino groups of AFM and nitro groups of nitro-aromatic explosive confer exceptional binding affinity. The optimized AFM exhibits a remarkable 2,4,6-trinitrotoluene (TNT) adsorption of 14.93 mg/g, which is 3.6 times of unmodified MIL-100(Fe). In photo-Fenton reactions, the optimized AFM completely degrades TNT within 30 min, and achieves a mineralization efficiency as high as 96.7 %. Moreover, the AFM exhibits excellent stability, retaining a high TNT degradation efficiency of 97.7 % after five consecutive cycles. The currently designed AFM catalyst possessing fascinating explosive affinity and high explosive mineralization efficiency is expected to advance sustainable remediation of high-risk explosive wastewater.
✓ 已验证
产品关联
DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2025
·
IF 13.2
Dawei Song,Yukun Pan,Huan Chen,Yaqin Shi,Yanan Huang,Bo Niu,Donghui Long,Yayun Zhang
Singlet oxygen ( 1 O 2 ) plays a crucial role in environmental catalysis owing to its long lifetime, strong electrophilicity, and high selectivity, whereas selective generation of 1 O 2 with conventional catalysts remains challenges. Herein, we for the first time construct a FeS 2 -FeMoO 4 heterostructure supported on graphene oxide (FeMoS-GO), and subsequently evaluate its efficacy in peroxymonosulfate (PMS) activation for degrading organic pollutants. Compared with non-heterostructures, our catalyst alters the electron density and coordination environment of Fe and Mo, enhancing electron transfer and facilitating the cyclic conversion of Fe 2+ /Fe 3+ during PMS adsorption and activation. Experiments indicate that FeMoS-GO generates nearly 100 % 1 O 2 , with concentrations two to three orders of magnitude higher than those of •OH and SO 4 •- . Density functional theory (DFT) calculations and electrochemical tests also support the high efficiency of electron transfer and PMS adsorption by heterostructure. The degradation for phenol of FeMoS-GO is 100 times faster than that of the non-heterogeneous structure, and its degradation rate for various organic pollutants exceeds 90 %, while also demonstrating satisfactory performance in interference and stability tests. Our findings offer new insights and approaches for the efficient and controlled generation of 1 O 2 in water treatment and environmental remediation.
✓ 已验证
产品关联
DOI
高影响因子
ENERGY CONVERSION AND MANAGEMENT
·
2018
·
IF 6.377
Hui Li,Fengsheng Liu,Xiaoling Ma,Zhongjie Wu,Yan Li,Linhua Zhang,Shoujun Zhou,Yaxin Helian
Strontium oxide (SrO) is restricted by poor reusability and pore structure in catalyzing transesterification for biodiesel production. To address this problem, metal organic frameworks is employed as a carrier to support strontium carbonate by mechanical mixing method (MM) and in situ titration method (ST), and then calcined under inert atmosphere to obtain the catalyst of MM–SrO and ST–SrO. As a comparison, the reusability of pure SrO is compared and the homogeneous contribution of leached active sites for ST–SrO and MM–SrO are also assessed. The catalysts are characterized by TG, XRD, FTIR, EDS, Hammett indicator titration, nitrogen adsorption–desorption, and VSM. From the catalyst reusability, MM–SrO exhibits the excellent performance, where the maximum conversion of 96.19% is achieved at molar ratio of methanol to oil 12, catalyst addition 8 wt% (refer to oil), reaction temperature 65 °C within 30 min. And the conversion of 82.49% is still obtained at the third cycle, which could be easily separated from the mixture by external magnetic field after each cycle as well. In order to optimize the activation condition and investigate MM–SrO deeply, thermal characteristics of its corresponding precursor are further evaluated, where the TG experiments are conducted at heating rate of 20, 30, and 40 °C/min. and kinetic parameters are calculated through model–free method and Avrami theory, respectively.
✓ 已验证
DOI
高影响因子
Desalination and Water Treatment
·
2024
·
IF 1
Shanshan Chen,Kang Wen,Xiaoting Zhang,Ruize Zhang,Runping Han
Metal organic frameworks are attracting scientific interest in adsorption applications owing to their large surface area and controllable pore size or shape over both microporous and mesoporous domains. Based on this, an iron(III) trimesic acid MIL-100(Fe) was facilely synthesized by hydrothermal treatment and used as adsorbent to remove neutral red (NR) from aqueous solution. MIL-100(Fe) was characterized using X-ray diffraction, scanning electron microscopy and transform infrared spectroscopy. MIL-100(Fe) was studied in view of the adsorption isotherms, thermodynamics, kinetics, and regeneration of the adsorbent. The adsorption kinetics data of NR were found to be in agreement with pseudo-second-order model. Temkin model was observed to be more suitable than Freundlich and Langmuir models in describing the adsorption isotherm. The maximum adsorption quantity was 333 mg g –1 at 313 K from Langmuir model. Thermodynamic parameters indicated that the NR adsorption process was endothermic and spontaneous. The NR-loaded MIL-100(Fe) adsorbent was regenerated and reused using pH = 2, 75% ethanol. A single-stage batch design for NR adsorption onto MIL-100(Fe) was also presented based on Temkin isotherm model equation. Based on the findings, MIL-100(Fe) is a promising adsorbent for the removal of cationic dyes from solution and thus can be used in practical application.
✓ 已验证
DOI
高影响因子
Journal of Physical Chemistry Letters
·
2023
·
IF 5.7
Cheng Wang,Mingxue Deng,Yanfeng Tang,Tongming Sun,Minmin Wang,Jin Wang,Zhenzhen Zhou,Jiacheng Wang
Ultraviolet C (UVC) sterilization has the advantages of high efficiency, broad spectrum, and no secondary pollution. However, the emission wavelength of UVC phosphors still suffers from a large deviation from the golden sterilization wavelength of 265 nm and a low luminescence intensity. Herein, we report UVC emission near the golden sterilization wavelength as well as a long afterglow through crystal field engineering, which can lead to 100% sterilization efficiency. Combined with theoretical calculation and experimental studies, substitution of Ca2+ with large-sized Sr2+ could obtain slight expansion and distortion of cationic sites, resulting in a decrease in crystal field intensity and blue shift of Ca1.5Sr0.5Al2SiO7:1%Pr3+, and produce near golden UVC emission. Ca1.5Sr0.5Al2SiO7:1%Pr3+ phosphor can effectively inactivate Staphylococcus aureus within 10 min, showing more efficiency than the traditional mercury lamp. This work provides an effective solution for the design and preparation of UVC phosphors using crystal field engineering toward near golden UVC emission.
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）