COMPOSITES COMMUNICATIONS
·
2025
·
IF 7.7
Kaifeng Wang,Siyu Liu,Hua Li,Xinke Liu,Yingxia Liu,Hezhou Liu
Thermal interface materials (TIMs) with excellent thermal conductivity are urgently required to tackle serious heat accumulation issues within the miniaturized electronic devices in electronic packaging field. Constructing thermal conductive network can enhance the thermal conductivity of polymer-based TIMs, but significantly restricted by the filler content and the orientation, thereby limiting the directional heat transfer behavior. In this work, BNNS@PVA aerogel with anisotropic thermal conductive network is proposed by sequential synthesizing routines, including the construction of PVA aerogel template by directional freeze-drying, surface assembly of BNNS-OH on the skeleton by dip-coating, and the alignment of the interconnected thermal conductive network by salting-out treatment. The relationship between the thermal conductive network microstructure and the thermal conductivity performance of BNNS@PVA is investigated by physiochemical characterizations and finite element simulation. By optimizing the filler content and the salting-out conditions comprehensively, the resulting aerogel with well-aligned microstructure achieves thermal conductivity of 4.63 W m −1 K −1 and anisotropic thermal coefficient of 473. Besides, the heat dissipation, compressive, and dielectric properties of the aerogels are performed. This research provides a promising strategy to enhance thermal conductivity performance by controlling the anisotropic alignment of the thermal conductive networks effectively, presenting great potential in the advanced polymer-based TIMs.
研究领域:
材料科学
·
电子工程
✓ 已验证
产品关联
DOI
高影响因子
RSC Advances
·
2013
·Vol. 4
·期 2
·794-804
·
IF 2.562
Han Zhu,Ming Zhang,ShengYing Cai,YingTing Cai,Pan Wang,ShiYong Bao,MeiLing Zou,MingLiang Du
A facile approach for the synthesis of uniform, small size and well-dispersed rhodium nanoparticles (RhNPs) on cross-linked polyvinyl alcohol–polyethyleneimine (PVA–PEI) nanofibers has been demonstrated. Various methods were firstly employed to cross-link PVA nanofibers and the cross-linked PVA–PEI nanofibers exhibited good water stability and porous structures after immersing in water for 72 h. Because of the strong chelate effects among the amine groups, hydroxyl groups and Rh3+ ions, uniform RhNPs with an average diameter of about 2.5 ± 0.2 nm can evenly and densely grow throughout the PVA–PEI nanofibers via an in situ reduction. Meanwhile, the better dispersion and smaller size of the RhNPs grown on the nanofibers in comparison with the pre-synthesized RhNPs directly deposited on the nanofibers exhibit the advantages of in situ reduction for size and dispersion control. The successful fabrication of the RhNPs/(PVA–PEI) nanofibers with various densities of well-dispersed RhNPs demonstrates that the strong chelate effects and stabilization of the PVA–PEI nanofibers also play an essential role in the size and dispersion control of RhNPs. The crystal structures, chemical bonding and interactions of the prepared nanofibers were verified using XPS and FTIR spectra and XRD patterns. These novel nanomaterials were fabricated as non-enzymatic electrochemical sensors and exhibit highly electrocatalytic activity towards H2O2.
研究领域:
材料科学
·
电化学
✓ 已验证
产品关联
DOI
高影响因子
Nanoscale
·
2017
·Vol. 9
·期 48
·19216-19226
·
IF 7.367
Bing Xiong,Weibing Zhong,Qing Zhu,Ke Liu,Mufang Li,Gang Sun,Dong Wang
The development of electronics towards a more functions-integrated, flexible and stretchable direction requires mechanically flexible substrates with high thermal and dimensional stability and optical transparency. Herein, rolls of an optically transparent PVA-co-PE nanofibrous membrane/epoxy composite with synergistically enhanced thermal stability, very low CTE, and outstanding mechanical properties are reported. The nanoscale size, the unique inter-stack structure, and the strong interfacial interactions between the PVA-co-PE nanofibers and the epoxy contribute to the synergistic effects. Because of the match between the refractive index (RI) of the PVA-co-PE nanofibers and the epoxy matrix, the visible light transmittance of nanocomposite film could be as high as 85% and the composite film was still optically transparent with a nanofiber loading content of up to 61.7 wt%. The break strength and compliance matrix of the composite film with a high fiber loading of 61.7 wt% increased by 2.3 times of that of the neat epoxy film and exceeded 3000 m2 N−1, respectively. PVA-co-PE nanofibers have a very low CTE value (3.634 × 10−6 K−1) and could be applicable as a reinforcement to reduce the thermal expansion of epoxy. Furthermore, we developed a flexible alternating current electroluminescent (ACEL) device based on the transparent composite film and the experimental results showed that the transparent composite film could serve as substrate for flexible electronic devices. In addition, their electrical and optical properties were evaluated.
研究领域:
材料科学
·
柔性电子学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
JOURNAL OF APPLIED POLYMER SCIENCE
·
2021
·Vol. 139
·期 17
·52049
·
IF 3.125
Xiangqian Jiang,Chuncheng Ban,Ling Li,Jiandong Hao,Ningqiang Shi,Weiping Chen,Peng Gao
In recent years, the thermoelectric properties of one-dimensional boron nitride nanomaterials have gradually attracted widespread attention of researchers in the world. In this paper, boron carbon nitrogen based composite nanofiber films were prepared by electrospinning. It is found that the diameter of nanofibers decreases in BCNNTs/PVA/PEDOT composite films when electrospinning voltage rises, while diameter increases as PVA and BCNNTs concentration increase of electrospinning precursor solution. Finally, thermoelectric power factor is investigated of the composite nanofiber films. It is verified that thermoelectric properties of the films closely related to electrospinning quality. However, fiber density of single-layer BCNNTs/PVA/PEDOT nanofiber film is too low, folding increase the density and thickness of multilayer BCNNTs/PVA/PEDOT nanocomposite fiber films, and the thermoelectric characteristics are significantly improved. The Seebeck coefficient can reach 3.62 mV/K and the power factor is 29.09 nW/mK 2 .
研究领域:
材料科学
·
纳米技术
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热电学
·
聚合物科学
✓ 已验证
产品关联
DOI
高影响因子
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
·
2022
·Vol. 77
·期 12
·1217-1222
·
IF 1.712
Song Xie,Yushan Liu,Hongliang Chen,Xiaozhan Yang,Wenlin Feng
A cadmium ion (Cd 2+ ) sensor based on polyvinyl alcohol (PVA)/tetraethyl orthosilicate (TEOS)/3-aminopropyl triethoxysilane (APTES) film integrated Mach–Zehnder interferometer was fabricated and evaluated. The three core fiber (TCF) is spliced with two single mode fibers (SMFs), one end of TCF and SMF are spliced with enlarged taper, and the other end of TCF is directly spliced with another SMF. PVA/TEOS/APTES composite film is coated on the surface of TCF. When the Cd 2+ is adsorbed by the sensing film, the relative refractive index of TCF cladding changes, the output interference trough wavelength shifts. By monitoring the wavelength shift information of the interference trough, the concentration of Cd 2+ will be obtained. In the concentration range of 0–0.4 μM, with the increase of Cd 2+ concentration, the interference trough shows a red shift. The sensitivity and the detection limit of the sensor are 7 nm/μM and 0.0143 μM (1.6 ppb), respectively. The sensor has excellent selectivity and good pH stability. It has the advantages of easy preparation, simple structure, and has potential application for the detection of trace Cd 2+ .
研究领域:
光学传感
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环境监测
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材料科学
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分析化学
✓ 已验证
DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2023
·
IF 15.1
Qinghong Ji,Xinxin Sheng,Xiaolong Li,Shuang Liu,Qiufei Chen,Pengzong Guo,Yabi Yang,Youyou Huang,Guoliang Zhang,Xiang Lu,Jinping Qu
Infrared stealth materials are in increasing demand with the development of infrared detection technology. However, most reported materials focus solely on emissivity control or temperature control, resulting in brief and less ideal infrared stealth effect. Herein, a double layer MXene@polyvinyl alcohol (PVA)/phase change capsules (PCC) aerogel composite inspired by the skin-fat structure of camel for infrared camouflage was successfully fabricated via a facile freeze-drying followed by spraying method. The PVA/PCC aerogel composite with high latent heat (155.2 J/g) and strong mechanical properties (772.6 kPa), obtained by an in-situ one-step method, is adopted as a temperature control layer, benefiting from the prominent thermal insulation of porous structure and effective heat absorption of PCC. The low emissivity (0.249) of the MXene layer on the surface of aerogel composite makes its radiation temperature recognized by the thermal imager much lower than its actual temperature. By integrating thermal insulation, heat absorption and emissivity reduction strategies, MXene@PVA/PCC aerogel shows no difference with the background in the infrared thermal imager (radiation temperature difference less than 10 °C), achieving superior infrared stealth for medium and low temperature scenarios, and provides novel ideas for developing more high-performance infrared stealth materials.
研究领域:
材料科学
·
纳米技术
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热工程
·
红外技术
✓ 已验证
产品关联
DOI
高影响因子
SEPARATION AND PURIFICATION TECHNOLOGY
·
2025
·
IF 9
Jingling Gong,Bin Xiang,Ruirui Jin,Zhaoyang Li,Weimin Liu,Jian Li
Membrane fouling is a key challenge to the sustainable operation of oil–water separation membranes. Constructing a stable hydration layer on the membrane surface as an oil-fouling resistance barrier by modulating the physicochemical structure of the membrane is one of the most effective strategies. Herein, inspired by the petal structure in nature, Cu 3 (PO 4 ) 2 and UiO-66-NH 2 particles were combined by a self-assembly strategy to construct CUP (Cu 3 (PO 4 ) 2 /UiO-66-NH 2 /PVA) composite membranes with anti-fouling capability against viscous crude oil. Benefiting from the petal structure and abundant polar groups within the membrane, the as-prepared membrane could easily combine with water molecules to form a stable hydration layer, which acted as a barrier to hinder the oil contamination of the membrane. Further, the hierarchical flower-like structure was conducive to the improvement of the emulsion breaking rate and permeation flux of oil-in-water emulsions. After 60 min continuous cross-flow separation, the obtained CUP composite membrane still remained prominent separation efficiency (99.6 %) and permeate flux (4685.96 LMH/bar). In addition, the CUP composite membranes showed outstanding resistance to acid and alkali as well as abrasion. This study provides an effective method for the advancement of high-performance membranes with high flux and anti-fouling capability in the flied of oily wastewater treatment.
研究领域:
膜科学
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材料工程
·
环境工程
·
分离技术
·
纳米技术
✓ 已验证
产品关联
DOI
高影响因子
ACS Applied Polymer Materials
·
2021
·
IF 4.089
Xu Yang,Baolong Wang,Di Sha,Yonggang Liu,Zhi Liu,Kai Shi,Wei Liu,Cong Yu,Xiangling Ji
Carboxylated poly(vinyl alcohol) (PVA-COOH) is prepared by modifying PVA with succinic anhydride. Then, poly(hexamethylene guanidine (PHMG) as a cross-linker and gallic acid (GA) as an antioxidant are added to obtain PVA-based composite hydrogel films (PVA-COOH-PHMG/GA). The as-prepared PVA-based composite films show hydrophilic surfaces, high swelling ratios of 600–700%, low water solubility for PVA-COOH-PHMG samples (about 10%), and good mechanical properties. Importantly, when the initial bacterial concentration is 107 CFU/mL, the antibacterial rate of PVA-based composite films against Escherichia coli and Staphylococcus aureus can reach 99.999%. When the initial bacterial concentration is 108 CFU/mL, the antibacterial rates of these composite films against E. coli and S. aureus can be 99.9999% and 99.988%, respectively. The antibacterial mechanism is also discussed via a live/dead bacteria assay. The cytotoxicity test reveals that the resultant PVA-COOH-PHMG composite hydrogel films without GA have good biocompatibility toward L929 cells, but PVA-COOH-PHMG/GA composite films with addition of GA decrease the cell viability. Interestingly, the PVA-COOH-PHMG/GA composite hydrogel films can scavenge 70% of 1,1-diphenyl-2-picryhydrazyl (DPPH) free radical because of the release of GA, indicating an excellent antioxidant efficiency. It is anticipated that the resultant PVA-based composite hydrogel films with an adequate amount of GA not only possess excellent antibacterial properties but also exhibit a good antioxidant activity. Therefore, they show potential for biomedical field applications as wound dressings.
研究领域:
材料科学
·
生物材料
·
生物医学工程
·
药学
✓ 已验证
产品关联
DOI
高影响因子
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
·
2025
·
IF 8.5
Qingsong Zheng,Shaoran Shi,Yang Gu,Pamela Owusu Osei,Lei Wang,Xiaorong Duan,Xiaomeng Wu,Xiaojun Liao
This study utilized deep eutectic solvents (DES) based on choline chloride/lactic acid (ChCl/LA) to deconstruct coconut fibers. The effects of DES with different temperatures and molar ratios on the yield of lignin, recovery rate of residues, structural changes in lignin and solid residues, and saccharification efficiency were investigated. The results showed that acidic DES treatment effectively deconstructed the coconut fibers, resulting in a high lignin yield of 68.51 % while enhancing the enzymatic saccharification of cellulose, reaching a glucose yield of 85.88 %. The structural characterization of lignin revealed that acidic DES primarily cleaved β-O-4 bonds, yielding coconut fiber lignin with lower molecular weight and higher phenolic hydroxyl groups. Uniform and smooth coconut fiber lignin nanoparticles (CFLNPs) with excellent antioxidant activity were finally obtained by antisolvent method. Furthermore, PVA/CFLNPs nanocomposite films were prepared based on acidic DES CFLNPs. The results of the structural and functional analysis showed that CFLNPs significantly improved the thermal stability, mechanical properties, hydrophobicity, antioxidant and antibacterial activity of the nanocomposite films. In general, this work achieved efficient deconstruction of coconut fibers, providing insights for biorefining in the future, and more importantly, the potential to use the CFLNPs as a choice for active food packaging.
研究领域:
材料科学
·
食品科学
·
生物化学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
·
2019
·Vol. 26
·期 23
·24062-24074
·
IF 2.914
Xu Sheng,Jiang Xinde,Liu Lingli,Wang Zhenxi,Zhang Xiaohang,Peng Yong,Cao Meng
Polyvinyl alcohol (PVA) filled with different kinds of ZnO whisker was prepared by chemical cross-linking reaction. It was found that the ZnO whiskers dispersed uniformly after being modified by 3-aminopropyltriethoxysilane (APTES). The PVA/tetrapod-shaped ZnO (PVA/tetra-ZnO) composites showed better adsorption performance than other kinds of PVA/ZnO composites. The framework-supported pore-channel structure was beneficial for the transmission and adsorption of heavy metal ions, and the formation of “brush” pore-channel of PVA/tetra-ZnO composites can effectively retain and capture the heavy metal ions. The PVA/tetra-ZnO composites presented well adsorption on Pb(II), Cd(II), and Cr(III) ions than Ni(II) and showed relatively selective removal on Pb(II) and Cr(III) ions. The adsorbed heavy metal ions presented gradient distribution with high content in the out layer and low content in the inner layer. Pb(II) adsorption capacity q e increased gradually with the increase of initial solution concentration and contact time which tended to be stable at 400 mg/L and 800 min. The maximal adsorption capacity q m obtained by nonlinear fitting reached to about 116 mg/g which was very close to the experiment data. Adsorption isotherm results indicated the monolayer adsorption process of the Langmuir model and the adsorption kinetics data fitted well to the pseudo-second-order model. The adsorption process was spontaneous and the high temperature was in favor of adsorption. The adsorption mechanism was explored as the combination of coordination and ion exchange. Besides, the PVA/tetra-ZnO composites exhibited better stress stability, thermo stability, and favorable regeneration than neat PVA.
研究领域:
材料科学
·
环境科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Journal of Coatings Technology and Research
·
2022
·Vol. 19
·期 3
·977-988
·
IF 2.339
Xu Xinmeng,Zhou Zhongqun,Qin Liangrong,Yu Caili,Zhang Faai
It is difficult to produce coatings that have good mechanical and self-healing properties. In this study, polyvinyl alcohol/polyurethane/polyurea (PVA/PU/PUA) microcapsules (MCs) loaded with isophorone diisocyanate (IPDI) as core materials were first prepared by interfacial polymerization in an oil-in-water emulsion using different PVA as an emulsifier. The MCs were then uniformly dispersed in the matrix. Optical microscopy and scanning electron microscopy revealed that the size of MCs decreased as alcoholysis and polymerization degree of PVA increased. Thermogravimetric analysis showed that the MCs prepared with the high polymerization or alcoholysis degree of PVA revealed outstanding thermal stability, and the initial decomposition temperature increased by approximately 100°C compared with IPDI. Furthermore, the self-healing performance of the two-component waterborne polyurethane (2K WPU) coating system containing MCs was investigated. The 2K WPU coatings with 9 wt% PVA/PU/PUA MCs exhibited excellent self-healing, mechanical properties, and corrosion resistance, and indicated a high potential for smart coating.
研究领域:
材料科学
·
化学工程
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
·
2024
·Vol. 35
·期 2
·1-13
·
IF 2.8
Liu Penghao,Yao Dahu,Lu Chang,Gao Xiping,Dong Panyi
The sensitivity of hydrogel-based strain sensors is generally lower than that of other elastomer-based strain sensors due to the mismatch between the change in electrical conductivity and hydrogel deformation. Therefore, the fabrication of highly sensitive hydrogel strain sensors is still a challenge. Here, a highly sensitive strain sensor based on poly (vinyl alcohol) (PVA) hydrogel was fabricated by constructing a tightly adhered graphene conductive layer on the surface of PVA hydrogel. The hydrogen bonding interaction between tannic acid (TA) and PVA as well as the strong π-π interaction between TA and graphene were utilized. Utilizing the stronger hydrogen bonding between TA and PVA, the surface layer crosslinking density of PVA hydrogel was greatly enhanced. Relying on the π-π interaction between TA and graphene, the conductive layer of graphene is firmly attached to the surface layer of the PVA hydrogel. Compared to the strain sensor with graphene uniformly dispersed in a PVA hydrogel matrix, the sensitivity was improved from 0.98 to 8.6. The high strain sensitivity allowed a lower detection limit of strain as low as 0.1%. The hydrogel has good tensile properties (maximum tensile stress of 0.38 MPa) and good fatigue resistance. It has excellent durability (over 1000 cycles) and fast response (227 ms).
研究领域:
材料科学
·
纳米技术
·
传感器
·
高分子科学
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）