JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
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2018
·Vol. 29
·期 7
·5814-5819
·
IF 2.324
Diao Chunli,Liu Hanxing,Hao Hua,Cao Minghe,Yao Zhonghua
Mn-doped barium strontium titanate Ba 0.4 Sr 0.6 TiO 3 - x mol%Mn ( x = 0, 1, 3 and 5; BSTM x ) thin films were deposited on Pt/Ti/SiO 2 /Si(100) substrates by spin-coating and annealed at 800 °C. X-ray diffraction patterns revealed that all the thin films were a typical cubic perovskite structure and no impurity peaks were observed. The effect of Mn doping on the ferroelectric properties and energy storage performance of the samples was investigated. The results showed that the recoverable energy storage density U rec and the difference ∆ P ( P max − P r ) between maximum polarization P max and remnant polarization P r firstly increased, then decreased with the increase of Mn doping amount. The optimized energy storage performance was obtained in Pt/BSTM3/Pt thin films: energy storage density of 8.48 J/cm 3 and energy storage efficiency of 42.4% at 1.63 MV/cm, electrical resistivity of 4.19 × 10 10 Ω cm and leakage current density of 7.77 × 10 −6 A/cm 2 at 163 kV/cm. Moreover, the effect of different top electrodes on energy storage performance was studied, which displayed that the energy density of Au/BSTM3/Pt films was higher than that of Pt/BSTM3/Pt films. The results indicated that Mn doping and Au electrodes could be effective ways to improve the energy storage properties of BST thin films.
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CHINESE JOURNAL OF POLYMER SCIENCE
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2018
·Vol. 36
·期 5
·584-591
·
IF 2.016
Luan Yi-Gang,Zhang Xiao-A,Jiang Sheng-Ling,Chen Jian-Huan,Lyu Ya-Fei
A self-healing supramolecular polymer composite (HSP-GO) was designed and prepared via incorporation of modified graphene oxide to hyperbranched polymer by hydrogen-bonding interactions. The polymer matrix based on amino-terminated hyperbranched polymer (HSP-NH 2 ) was synthesized by carboxylation, Curtius rearrangement, and amination of hydroxyl-terminated hyperbranched polyester (HP-OH), while the modified graphene oxide was prepared by transformation of hydroxyl to isocyanate and further to carbamate ester. Spectroscopic methods were utilized to characterize the obtained polymer composites. Stress-strain test was selected to carefully study the self-healing property of HSP-GO. It is found that a small amount of modified graphene oxide (up to 2 wt%) improves the glass transition temperature ( T g ), tensile strength, Young’s modulus, and self-healing efficiency of the polymer composites. After healed at room temperature for 10 min, the addition of modified graphene oxide improves the self-healing efficiency to 37% of its original tensile strength. The experiment result shows that the self-healing efficiency is related to the density of hydrogen bonding site and the molecular movement.
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Nanoscale Research Letters
·
2018
·Vol. 13
·期 1
·1-12
·
IF 3.125
Wang Qi,Ma Chunlei,Tang Jianke,Zhang Cuihong,Ma Lihua
Taking advantages of reticular proteins and reductive groups on the surface, eggshell membrane (ESM) was selected to synthesize MnO 2 nanoparticles from potassium permanganate through a super simple way in which ESM acted as both template and reductant. This process avoided harsh reaction conditions or complicated aftertreatments and thus owned the merits of green synthesis, handy operation, low cost, and easy purification. The ESM-templated MnO 2 nanoparticles (MnO 2 NPs/ESM) were characterized, and the content of nanomaterials on the template was tested. MnO 2 NPs/ESM showed a good capacity for decontamination of tetracycline hydrochloride (TCH). The macroscopical materials can be separated easily by taking the membrane out to stop the degradation instead of centrifugation or filtration. It was studied that 72.27% of TCH (50 mg/L) was decontaminated in 20 min by 0.1920 g/L MnO 2 nanoparticles, and removal efficiency could reach 83.10% after 60 min under buffered condition. The kinetics was studied with or without buffer, and it was concluded that the degradation process followed a pseudo-second-order model. The facile synthesis of materials and effective degradation would facilitate the nano-MnO 2 -based decontamination applications.
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高影响因子
NPG Asia Materials
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2018
·Vol. 10
·期 7
·618-629
·
IF 7.208
Fu Gengtao,Jiang Xian,Chen Yifan,Xu Lin,Sun Dongmei,Lee Jong-Min,Tang Yawen
The development of highly active air-cathodes with robust stability and a low price is of crucial significance for rechargeable Zn–air batteries and remains a great challenge. Herein, for the first time, we report a “rigid and flexible” material consisting of three-dimensional (3D) porous nickel-manganese oxide (Ni 6 MnO 8 ) coupled with 1D ultrathin Au nanowires (Au-NWs) as an efficient bifunctional oxygen electrocatalyst, adopting α-naphthol-Au(III) as a precursor of Au-NWs and pre-formed Ni 6 MnO 8 as a support. Ni 6 MnO 8 acts not only as a robust carbon-free support that is stable in alkaline electrochemical conditions, but also as a highly active component for the oxygen evolution reaction (OER), while flexible Au-NWs contribute to the excellent oxygen reduction reaction (ORR) activity and act as a flexible conductive electronic network. The coupling of Ni 6 MnO 8 and Au-NWs plays a complementary role in the two types of oxygen electrocatalytic reactions. Accordingly, their advantages have been optimally harnessed while overcoming their deficiencies. Moreover, a Zn–air battery assembled with such a rigid and flexible air-cathode has lower charge and discharge overpotentials and a higher cyclic stability than those with a mixed Pt/C+RuO 2 catalyst.
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CELLULOSE
·
2018
·Vol. 25
·期 7
·4133-4144
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IF 3.809
Geng Aobo,Meng Liang,Han Jingquan,Zhong Qiang,Li Meirun,Han Shuguang,Mei Changtong,Xu Lijie,Tan Lin,Gan Lu
Abstract There is an urgent need to explore alternatives to replace traditional carbonaceous materials because of dwindling oil reserves and increasing atomospheric carbon dioxide. In the present study, the cellulose derived carbon nanofibers (CCNF) were prepared and used to hybridize with bismuth oxybromide to prepare novel photocatalyst composites (CCNF/BiOBr). The structural properties of the prepared composites were then characterized. Afterwards, the photocatalytic performance of the CCNF/BiOBr composites was investigated through degrading rhodamine B (RhB) under continuous visible light irradiation. The results indicated that the pyrolysis process could convert the cellulose to carbon nanofiber with high graphitization degree. The photocatalytic performance of the CCNF/BiOBr composite was better than that of the pure BiOBr, which was ascribed to the introduction of the CCNF into the composite system. The present work provides a promising way to design new photocatalyst composites with desirable carbon alternatives from biomass materials for effective treatment of organic contaminants in water media. Graphical Abstract
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WATER AIR AND SOIL POLLUTION
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2018
·Vol. 229
·期 6
·1-11
·
IF 1.769
Wang Jian,Yan Yanan,Tian Lili,Wang Qinmei,Zhang Yan,Cao Weiqin,Yang Chun
Reactive Red 141 (RR 141) was efficiently adsorbed and enriched from an aqueous solution by oppositely charged cryogels. The cryogels were prepared with acryl amide (AAm) and dimethyl diallyl ammonium chloride (DDAC) as the monomers, along with N,N′-methylene-bis acrylamide (MBA) as the cross-linker. In the presence of DDAC, the prepared macroporous cryogels hold a strong affinity to the reactive dye. The elasticity and mechanical properties of the cryogels were improved when the mass ratio of the monomer and the cross-linker was 2:1. A maximum adsorption capacity was achieved with 21 wt% of DDAC in reactants. The impacts of conditions of non-aqueous electrolysis such as solvent types, electrolytic voltages, and electrolyte concentrations were investigated. When subjected to non-aqueous electrolysis in organic media of N-methyl pyrrolidone (NMP), propylene carbonate (PC), and ethylene carbonate (EC), the cryogel-adsorbed dye underwent a quick and efficient degradation. Higher Faradaic efficiencies were obtained compared with that from the same operations in aqueous media. The specific degradation rate of RR 141 in a non-aqueous electrolysis is substantially larger than that reported. In addition, both the cryogel and the organic solvents can be repeatedly used, making it a sustainable method to deal with related pollution problems of reactive dyes.
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Natural Products and Bioprospecting
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2018
·Vol. 8
·期 6
·413-418
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IF 0
Wang Xia,Peng Xing-Rong,Lu Jing,Hu Gui-Lin,Qiu Ming-Hua
Abstract In present study, four new dammarane-type triterpenoids, namely caffruones A–D ( 1 – 4 ), were isolated from the cherries of Coffea arabica . Their structures were elucidated by extensive spectroscopic analysis including 1D, 2D NMR (HSQC, HMBC, 1 H– 1 H COSY, and ROESY), HRMS and IR spectra. This is the first time that tetracyclic triterpenes have been reported in genus Coffea . Graphical Abstract
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MICROCHIMICA ACTA
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2018
·Vol. 185
·期 9
·1-9
·
IF 5.705
Wang Jing,Li Haigang,Li Tingting,Ling Liansheng
A one-step, one-tube colorimetric assay is described for the detection of bacterial double-stranded DNA (dsDNA). It utilizes a G-quadruplex DNAzyme produced by an asymmetric polymerase chain reaction (As-PCR) that catalyzes the oxidation of cysteine to form cystine. This results in the formation of oligonucleotide-modified gold nanoparticles via triplex formation, and eventually in a color change from red to blue that occurs within about 10 mins. This can be measured by ratiometric colorimetric (at 525 and 600 nm). The limit of detection (LOD) for the model analyte (dsDNA of Staphylococcus aureus ( S. aureus )) is as low as 0.28 pg per 0.05 mL with a good linear response ranging from 16.0 fg·μL −1 to 1.6 ng·μL −1 . This is much lower than previously reported LODs. The assay is highly selective for S. aureus dsDNA over a range of other bacterial DNAs. Conceivably, it provides an attractive alternative tool for rapid detection of bacterial dsDNA as required in pathogen screening in the food industry.
Schematic presentation of a colorimetric assay for bacterial DNA. It is based on the catalytic activity of a G-quadruplex DNAzyme that is formed by an asymmetric PCR involving triplex DNA formation and gold nanoparticle (AuNPs) aggregation.
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高影响因子
NEUROCHEMICAL RESEARCH
·
2018
·Vol. 43
·期 7
·1439-1453
·
IF 2.772
Jia Jingjing,Zhang Ting,Chi Jieshan,Liu Xiaoma,Sun Jingjing,Xie Qizhi,Peng Sijia,Li Changyan,Yi Li
CeO 2 nanoparticles (nanoceria) have been used in many studies as a powerful free radical scavenger, and LXW7, a small-molecule peptide, can specifically target the integrin αvβ3, whose neuroprotective effects have also been demonstrated. The objective of this study is to observe the neuroprotective effect and potential mechanism of CeO 2 @PAA-LXW7, a new compound that couples CeO 2 @PAA (nanoceria modified with the functional group of polyacrylic acid) with LXW7 via a series of chemical reactions, in H 2 O 2 -induced NGF-differentiated PC12 cells. We examined the effects of LXW7, CeO 2 @PAA, and CeO 2 @PAA-LXW7 on the viability of primary hippocampal neurons and found that there was no significant difference under control conditions, but increased cellular viability was observed in the case of H 2 O 2 -induced injury. We used H 2 O 2 -induced NGF-differentiated PC12 cells as the classical injury model to investigate the neuroprotective effect of CeO 2 @PAA-LXW7. In this study, LXW7, CeO 2 @PAA, and CeO 2 @PAA-LXW7 inhibit H 2 O 2 -induced oxidative stress by reducing the production of reactive oxygen species (ROS) and regulating Bax/Bcl-2, cleaved caspase-3 and mitochondrial cytochrome C (cyto C) in the apoptotic signaling pathways. We found that the levels of phosphorylation of focal adhesion kinase (FAK) and of signal transducer and activator of transcription 3 (STAT3) increased significantly in H 2 O 2 -induced NGF-differentiated PC12 cells, whereas LXW7, CeO 2 @PAA, and CeO 2 @PAA-LXW7 suppressed the increase to different degrees. Among the abovementioned changes, the inhibitory effect of CeO 2 @PAA-LXW7 on H 2 O 2 -induced changes, including the increases in the levels of p-FAK and p-STAT3, is more obvious than that of LXW7 or CeO 2 @PAA alone. In summary, these results suggest that integrin signaling participates in the regulation of apoptosis via the regulation of ROS and of the apoptosis pathway in H 2 O 2 -induced NGF-differentiated PC12 cells. LXW7, CeO 2 @PAA, and CeO 2 @PAA-LXW7 can play neuroprotective roles by counteracting the oxidative stress and apoptosis induced by H 2 O 2 in NGF-differentiated PC12 cells. CeO 2 @PAA-LXW7 exerting a more powerful synergistic effect via the conjunction of LXW7 and CeO 2 @PAA.
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Scientific Reports
·
2018
·Vol. 8
·期 1
·1-10
·
IF 4.122
Yang Aili,Zhu Yukuan,Huang C. P.
To overcome the limits of low adsorption capacity and the separation difficulty of solid from liquid phase for graphene oxide (GO), a novel nanocomposite graphene oxide-manganese oxide (GOMO) was facilely fabricated under ultrasonic radiation. The structures and micro-morphology of the products were characterized by fourier transform infrared (FT-IR) spectroscopy, raman shift spectroscopy, X-ray diffraction (XRD) pattern and scanning electron microscopy (SEM). The effect of solution pH, adsorbent dose, contact time, initial uranium concentration, ionic strength and temperature on uranium removal efficiency was studied by batch adsorption experiments. The product GOMO was used to examine the feasibility of the removal of high salt content in uranium-containing wastewater. The adsorption results were fitted using the Langmuir and Freundlich isotherm models. The kinetic parameters in the adsorption process were measured and fitted. Five adsorption/desorption cycles were performed using 3 M HNO 3 as the regenerant in order to evaluate the reuse of GOMO.
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JOURNAL OF POLYMER RESEARCH
·
2018
·Vol. 25
·期 7
·1-12
·
IF 1.434
Hu Yan,Zhang Shangwen,Han Dandan,Ding Zongxian,Zeng Suying,Xiao Xincai
We prepared a hydroxypropyl methyl cellulose-sodium alginate (HPMC-SA) composite hydrogel with a membrane covering the semi-interpenetrating network based on a semi-synthetic polymer hydroxypropyl methyl cellulose (HPMC) and a natural polymer sodium alginate (SA) by Ca 2+ crosslinking and polyelectrolyte complexation with chitosan (CS) covering the hydrogel surface. The physiochemical properties of HPMC-SA hydrogels were evaluated by scanning electron microscopy, infrared spectrum, X-ray diffraction, and thermogravimetric analysis. The swelling ratio of the HPMC-SA composite hydrogel in simulated gastrointestinal fluid was measured. The drug release behavior of the HPMC-SA composite hydrogel for macro-molecular and small-molecule drugs was evaluated by using bovine serum albumin, metformin hydrochloride, and indomethacin as model drugs. The results showed that the HPMC-SA hydrogel had good water absorption and degradability, an increased swelling ratio of 55, and a prolonged time for maximum swelling degree of 50 h. Moreover, the hydrogel exhibited higher drug-loading capacity and improvements in the sustained release of bio-macromolecules, demonstrating its potential as a drug carrier for biomedical applications.
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IONICS
·
2018
·Vol. 24
·期 12
·3975-3982
·
IF 2.347
Wang Lu,Luo Hang,Zhou Xuefan,Wei Anqi,Zhou Kechao,Chen Zhuo,Zhang Dou
As the electronic industry developed rapidly, greater demands are required on the performance of dielectric composites, such as high permittivity, low dielectric loss, and high-energy density. Improving the compatibility of fillers in polymer matrix and uniform distribution of the electric field could increase the permittivity of such composites. Therefore, BaTiO 3 nanoparticles were coated by TiO 2 sol to fabricate BaTiO 3 @TiO 2 core-shell structured fillers in this paper. BaTiO 3 @TiO 2 fillers with gradient permittivity were firstly modified by dopamine in order to disperse in the composites homogeneously and adhere to poly(vinylidene fluoride- co -hexafluoropropylene) (P(VDF-HFP)) matrix tightly. At 1 kHz, the permittivity of the composite with 20 vol% BaTiO 3 @TiO 2 was 32.15, obviously larger than that of pure P(VDF-HFP) (6.92), and the dielectric loss was just 0.052. Consequently, the discharged energy density of the composite was enhanced to 0.23 J/cm 3 at 40 kV/mm, which was two times higher than that of pure P(VDF-HFP). This work provides a feasible approach to prepare high-performance dielectric composites.
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