ACS Sustainable Chemistry & Engineering
·
2024
·
IF 7.1
Xiaohan Sun,Qianqian Yu,Fangmiao Wang,Miao Sun,Senwei Hu,Jinliang Zhu,Cong Li,Zhaolin Yang,Yifan Liu,Jiazuo Zhou,Yuan Yu,Zishuai Jiang,Yudong Li,Haiyue Yang,Chengyu Wang
Inflammable insulation materials cause fire hazards, especially in smoke harm. High-performance flame-retardant insulation materials are urgently needed to address these safety issues. Herein, a multiple flame-retardant strategy was proposed to prepare a novel eco-friendly tourmaline/metal–organic framework (MOF) lignocellulose aerogel (TMLA) from deep eutectic solvent (DES)-treated low-value wood with favorable flame retardancy, smoke suppression, and thermal insulation by directional freeze-casting. The combination of DES treatment, tourmaline, and MOF synergistically promotes the flame retardancy of TMLA. In addition, the total smoke release is reduced due to the sedimentation of negative oxygen ions. Compared with the lignocellulose aerogel, the heat release rate, total heat release, and total smoke release of TMLA were reduced by 55.37, 52.37, and 64.20%, respectively, and the limiting oxygen index was greatly enhanced by 30.25%. The directional structure of TMLA results in anisotropy, leading to ideal axial thermal insulation properties (28.13 mW/mK) and a favorable compression strength (1.83 MPa). Supported by the positive outcomes of the life cycle assessment, the prepared TMLA is eco-friendly and has superior flame retardancy and smoke suppression to pave the way for the sustainable production and use of insulation materials.
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DALTON TRANSACTIONS
·
2024
·Vol. 53
·期 31
·12936-12942
·
IF 3.5
Jiaqi He,Xin Deng,Wenting Sun,Wenjing Shang,Yongbing Lou,Jinxi Chen
To address the shortage of fossil energy, the development of affordable and efficient non-precious metal catalysts for oxygen evolution reaction (OER) from electrocatalytic water splitting is still a crucial challenge. Herein, the bimetallic NiFe metal–organic frameworks (MOFs) are synthesized by hydrothermal and electro-deposition. Benefiting from the synergistic effect of Fe and Ni, the catalyst demonstrates extraordinary activity, which exhibits favorable OER catalytic activity in 1 M KOH solution with an overpotential of 206 mV at 10 mA cm−2. Meanwhile, the obtained NiFe-NDC presents promising stability in the 20 h test at 50 mA cm−2.
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CHINESE CHEMICAL LETTERS
·
2024
·
IF 9.4
Yan-Kai Zhang,Yong-Zheng Zhang,Chun-Xiao Jia,Fang Wang,Xiuling Zhang,Yuhang Wu,Zhongmin Liu,Hui Hu,Da-Shuai Zhang,Longlong Geng,Jing Xu,Hongliang Huang
ABSTRACT The highly desired goal is to employ visible light for the photocatalytic reduction of toxic Cr(VI) to environmentally friendly Cr(III). Metal-organic frameworks (MOFs) are considered one of the most promising materials for the photoreduction of Cr(VI). Nevertheless, developing MOFs with high stability and activity is still challenging. Herein, we report a stable Zn-based MOF (named DZU-64 ) with an anthracene functionalized ligand, and its reduction of Cr(VI) under sunlight irradiation was investigated. DZU-64 exhibits excellent chemical stability in pH range of 2−14 aqueous solution, and remarkable thermal stability to 570°C. For the photoreduction of Cr(VI) under visible light irradiation, DZU-64 gives a record rate constant of 0.467 min −1 and a high Cr(VI) reduction rate of 6.68 mg Cr (VI) g −1 cata min −1 at pH 2. Moreover, under real solar light, DZU-64 can also efficiently reduce Cr(VI) to Cr(III) while retaining its catalytic activity throughout 5 cycles without any notable decline, further demonstrating its great application prospect. By combining the photovoltaic performance tests and electron spin resonance test, the possible photoreduction of Cr(VI) mechanism in DZU-64 was analyzed.
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MICROCHEMICAL JOURNAL
·
2025
·
IF 5.1
Zhi Luo,Jing Li,Shenglan Hu,Lingling Zheng,Lixin Xu,Biyang Deng
In this study, Ru(bpy) 3 2+ and oxalate (C 2 O 4 2− ) in Ru@Zn-MOF generated self-enhanced electrochemiluminescence (ECL). The self-enhanced ECL composite exhibited a short electron transfer distance and minimal energy loss, which ensured the high and stable luminescence efficiency of Ru@Zn-MOF. A MnO 2 @AuNPs nanocomposite was introduced into Ru@Zn-MOF via antigen–antibody interactions in the presence of squamous cell carcinoma antigen (SCCA). This significantly quenched the ECL signal due to the combined effect of the dual quenchers, MnO 2 NFs and AuNPs. A highly efficient ECL-RET immunosensor was constructed for the sensitive detection of SCCA in the linear range of 1 fg/mL to 100 ng/mL, with a limit of detection of 0.26 fg/mL (S/N = 3). This immunosensor has broad clinical applications for the quantitative detection of biomarkers.
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TALANTA
·
2024
·
IF 5.6
Yi Xiao,Pengcheng Huang,Fang-Ying Wu
α-Glucosidase, which directly involves in the metabolism of starch and glycogen and causes an increase in blood sugar level, is the major target enzyme for the precaution and therapy of type II diabetes. Based on the previous work, we adopted a post-synthetic modification method to encapsulate Tb 3+ into Ce-MOF nanozyme which owned mixed valence states. Tb@Ce-MOF displayed induced luminescence characteristic and exceptional oxidase-like activity that could oxidize colorless 3,3′,5,5′-tetramethylbenzidine (TMB) to blue ox-TMB. α-Glucosidase can hydrolyze the substrate l -ascorbic acid-2- O -α- d -glucopyranosyl (AAG) to generate ascorbic acid (AA), which could increase the Ce 3+ /Ce 4+ redox valence mode in Tb@Ce-MOF, leading to the inhibition of the allochroic reaction of TMB and the decreased absorption of ox-TMB at 652 nm. The energy transfer (EnT) process from Ce 3+ to Tb 3+ will enhance due to the increased Ce 3+ /Ce 4+ mode in Tb@Ce-MOF, which will result in an enhanced fluorescence signal of Tb@Ce-MOF at 550 nm. But the addition of inhibitor acarbose will inhibit the above process. We have constructed a dual-mode detection platform of α-glucosidase and its inhibitor via colorimetric and fluorometric method. The linear range of α-glucosidase were 0.01–0.5 U/mL (colorimetric mode) and 0.8–1.5 U/mL (fluorometric mode), respectively, with a detection limit as low as 0.0018 U/mL. Furthermore, our approach was also successfully employed to the analysis of α-glucosidase in serum samples.
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ACS Applied Materials & Interfaces
·
2025
·
IF 8.2
Dangge Gao,Fangxing Wang,Chi Zheng,Bin Lv,Jianzhong Ma
Cotton textiles with persistent antibacterial qualities are crucial in halting the spread of bacteria and other infections. However, fugitive bacteria and drug-resistant pathogens have rendered tremendous challenges in the development of cotton fabrics with long-lasting antibacterial efficacy. The work aimed to innovatively propose a functional cotton fabric integrating intelligent bacteria-capturing and dual antibacterial properties for efficacious personal health management. The functional cotton fabric was created by modifying the surface of cotton fabric with the quaternized carboxymethyl chitosan (Q-CF) and then covalently grafting the silver@Zr-based porphyrin metal–organic skeleton (Ag@MOF-545) prepared via the “bottle-around-the-boat” method on the surface of Q-CF (AM/Q-CF). In this process, the functional cotton fabric could capture bacteria via positive charges on the surface of the quaternized carboxymethyl chitosan. Due to the synergistic effect of broad-spectrum antibacterial silver nanoparticles (AgNPs) and the visible light-driven antibacterial Zr-based porphyrin metal–organic skeleton (MOF-545), the metabolism of bacteria and drug-resistant strains was well inhibited, which endowed the AM/Q-CF with lasting dual antibacterial properties. After repeated laundering cycles, abrasion cycles, simulated sweat soaking, and long-term storage, the antibacterial rates of AM/Q-CF were over 85%. Altogether, the results provided a potential antibiotic-free alternative for the preparation of durable antibacterial cotton fabrics.
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Nano Research
·
2024
·Vol. 17
·期 7
·5863-5871
·
IF 9.5
Ke Yanjing,Zhang Jiaxing,Peng Xin,Zhang Zhiyi,Wang Xu,Qi Wei,Wang Mengfan
Recently, many efforts have been dedicated to construct artificial catalysts with enzyme-like activity. However, it is still a big challenge to endow artificial catalysts with specific substrate selectivity. In this study, we developed a facile strategy to construct a MIL-53(Fe)-based nanocatalyst with designable selectivity in the degradation of oxytetracycline (OTC). Through the Fe–O–P conjunction, oxytetracycline aptamer (OA) can be easily anchored on MIL-53(Fe) to provide the specific site for OTC binding. We verified that the obtained MIL-53(Fe)-Apt nanocatalyst displayed enhanced catalytic ability in the degradation of OTC, whereas obvious suppression toward other substrate analogues. This performance therefore brings about an anticipated selectivity toward OTC. Moreover, we highlighted that the configuration of aptamers on MIL-53(Fe) can be modulated through varying conjunction mode. Structure–function analysis revealed that aptamer configuration affects the local concentration of substrate around catalytic site, which thus decides the catalytic performance toward OTC. This work presented a facile and promising strategy for developing artificial catalysts with designable selectivity.
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Nanoscale
·
2025
·
IF 5.1
Zhiguang Guo,Guangyi Tian,Changhui Fu
Water scarcity has become one of the largest crises in the world, especially for people living in arid areas. Among all water sources, atmospheric water has the advantages of less geographical limitation and less environmental impact of the water production process. The use of solar-powered atmospheric water harvesting (AWH) has become a viable solution to the problem of water scarcity in arid regions. MOF-303 is a robust and water-stable MOF that collects water at low relative humidity (RH ≤ 30%) and releases it under mild heating. However, its actual demonstrated water absorption remains unsatisfactory, which limits its application in the field of water harvesting. Here, we propose a high-performance composite adsorbent of hygroscopic salt-modified MOF, and obtain the composite adsorbent MOF-303@LiCl by confining LiCl in the pores of MOF-303. The composite adsorbent exhibited excellent water absorption of 0.61 g g-1 at low relative humidity (25℃, 30% RH) and high adsorption kinetics (adsorption saturated at 80 min). By adding a certain proportion of the photothermal material CB, MOF-303@LiCl could be heated up to 66.1℃ under one solar irradiation and achieved desorption within 60 min. The adsorption-desorption cycle of this composite adsorbent can be fed by natural sunlight without the need for optical focusing and additional energy input. The fast adsorption-desorption kinetics allow for multiple cycles of AWH in a single day, which has great potential in water harvesting.
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NEW JOURNAL OF CHEMISTRY
·
2025
·
IF 2.5
Qi Ye,Fei Ge,Xiaohui Yang,Minghao Zhou
The catalytic oxidative depolymerization of lignin and its dimers is key for the effective utilization of biomass. In this work, a metal–organic framework (MOF) was chosen as the precursor, and a series of nickel–manganese bimetallic catalysts with different metal ratios were prepared via a hydrothermal method using 1,3,5-tricarboxylic acid as the ligand. The effects of metal ratio and calcination temperature on the activity of the catalyst were considered, and the oxidative depolymerization of the lignin dimer (2-phenoxy-1-acetophenone) was investigated in detail. The selective conversion of 2-phenoxy-1-acetophenone was achieved over the Ni2Mn1-MOF catalyst in an oxygen atmosphere with methanol as the solvent. Through the optimization of different reaction parameters, including reaction temperature, oxygen pressure, reaction time and solvent, it was found that under optimal reaction conditions (140 °C, 4 h, 0.5 MPa O2), the Ni2Mn1-MOF catalyst exhibited a good catalytic performance for the efficient conversion of 2-phenoxy-1-acetophenone to phenol and methyl benzoate. Furthermore, its specific reaction mechanism was discussed based on the distribution of products in the lignin dimer oxidation process, which was useful for understanding the further oxidative depolymerization of lignin.
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Catalysis Science & Technology
·
2024
·Vol. 14
·期 12
·3436-3447
·
IF 4.4
Kok Bing Tan,Yiping Liu,Youting Wang,Sajid Ali,Wendong Wang,Jingru Li,Longmei Shang,Xing Yan,Xiaodong Zhang,Guowu Zhan
In this study, three different metal oxides derived from metal–organic frameworks (MOFs), including CeO2, ZrO2, and Fe2O3 were used as porous supports for loading Pt nanoparticles, and the supported catalysts (viz., Pt/CeO2, Pt/ZrO2, and Pt/Fe2O3) were evaluated for the catalytic deoxygenation of stearic acid to produce olefins by analytical pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). Interestingly, Pt/CeO2 and Pt/Fe2O3 catalysts demonstrated high selectivity for olefins or aromatics, respectively, with alkanes as minor products, while the Pt/ZrO2 catalyst demonstrated the lowest deoxygenation efficiency. Among them, the Pt/CeO2 catalyst demonstrated the highest deoxygenation efficiency due to its highest oxygen vacancy density and the largest specific surface area (53 m2 g−1). It also demonstrated the highest selectivity for olefins (41%) due to the in situ partial formation of the bimetallic PtCe phase during the catalytic reaction at high temperature, which facilitates the decarbonylation pathway and leads to the formation of olefins as the main product. In addition, experimental optimizations of the reaction parameters were conducted on the designed Pt/CeO2 catalyst to further enhance olefin selectivity. Importantly, the Pt/CeO2 catalyst also maintained high olefin selectivity and stearic acid conversion even after six consecutive cycles. Therefore, this work has provided an alternative route to produce olefins via the decarbonylation of stearic acid over a supported Pt/CeO2 catalyst.
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INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
·
2025
·
IF 8.5
Zuozhu Yin,Qingqing Yu,Hong Chen,Xiaoxiang Chen,Kaiyuan Liu,Min Li,Xiaoze Yang,Yuhua Chen,Yu Xie,Yidan Luo,Mingshan Xue
The discharge of oily wastewater and sewage in industry and life was increasing, seriously affecting the sustainability of the environment and ecosystem. In this work, a multifunctional superhydrophobic nanocellulose-based membrane was prepared by spraying Ce-MOF nanoparticles onto the nanocellulose membrane, which had a hydrostatic contact angle of up to 170°: (i) Resistance to harsh conditions (including high temperatures, abrasion, ultraviolet light exposure, bending, and self-cleaning); (ii) Achieve efficient separation of mixed oil and water. It has shown commendable efficacy in separating wastewater containing mixed oils. The separation flux of mixed oil wastewater was 179 L·m −2 ·h −1 (n-hexane and chloroform/water), and the separation efficiency was >94 % (n-hexane and chloroform/water); (iii) Efficient and rapid photocatalytic removal of pollutants, which is a useful property to prevent organic pollution; (iv) Effectively prevent biological pollutants adhesion, reducing the amount of microbial adhesion by 67.74 %. In many fields, such as industrial production and urban sewage treatment, wastewater treatment in harsh environments as well as the durability of materials has always been an issue. The appearance of this new material provides a feasible solution to this problem.
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Heliyon
·
2024
·
IF 3.4
Yige Yan,Mohan Huang,Yongsheng Wang,Dawei He,Jiaqi He
Metal-organic frameworks (MOF) have been wildly synthesised and studied as electrode materials for supercapacitors, and bimetallic MOF of Ni and Co has been broadly studied to enhance both specific capacitance and stability of supercapacitors. Herein, a best performance (about 320 F/g) of Ni–Co bimetallic MOF was found in a uniform preparation condition by adjusting the ratio of Ni to Co. Then tiny third metal ion was introduced, and we found that the morphology of material has a significant change on the original basis. Furthermore, certain ions (Zn, Fe, Mn) introduced make a huge improvement in capacitance based on Ni–Co MOF of 320 F/g. The result shows that Zn–Ni–Co MOF, Fe–Ni–Co MOF and Mn–Ni–Co MOF perform specific capacitance of 1135 F/g, 870 F/g and 760F/g at 1 A/g, respectively. Meanwhile, the asymmetric supercapacitor (ASC) was constructed by Zn–Ni–Co MOF as positive electrode and active carbon (AC) as negative electrode. The Zn–Ni–Co MOF//AC ASC possesses a energy density of 58 Wh/kg at a power density of 775 W/kg. This research provides a new methods to regulate the morphology of MOF and a novel viewpoint for assembling high-performance, low-price, and eco-friendly green energy storage devices.
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