SEPARATION AND PURIFICATION TECHNOLOGY
·
2023
·
IF 8.6
Meilin Yin,Zhen Li,LiPeng Wang,Shaokun Tang
The fabrication of structural stable metal organic frameworks (MOFs) with large pore size by facile, rapid and environmentally friendly synthetic method remains a serious challenge. Herein, it is the first time to develop a novel synthetic strategy that rapidly enlarges the pore size of microporous ZIF-8 by employing polyvinyl pyrrolidone (PVP) as a modulator to induce defect formation in environmentally friendly supercritical CO 2 (scCO 2 ). Notably, the high solubility and low mass transfer resistance of reactants in scCO 2 and low surface tension nature of scCO 2 are the key factors for the rapid preparation of structural stable PVP/ZIF-8 with hierarchically pores. And the PVP modulator as a weak ligand not only facilitates pore size but also perturbs coordination to form coordination defects, exposing more coordination metal sites. These characteristics are beneficial to fast diffusion and adsorption of CO 2 molecules. In addition, the influences of reaction conditions on the morphology, pore parameter and CO 2 adsorption performance of PVP/ZIF-8 are investigated. The result indicates that the PVP/ZIF-8 prepared with 1:1 of Zn/PVP mass ratio at 90 °C and 30 MPa in supercritical environment have the highest CO 2 adsorption equilibrium capacity (2.02 mmol CO 2 /g sorbent) and great cycle stability, which should be attributed to hierarchically porous structure with interconnected macropores and micropores.
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Journal of Environmental Chemical Engineering
·
2023
·
IF 7.7
Nuan Xu,Zhenhua Tang,Yan-Ping Jiang,Junlin Fang,Li Zhang,Xiaofang Lai,Qi-Jun Sun,Jing-Min Fan,Xin-Gui Tang,Qiu-Xiang Liu,Ji-Kang Jian
The widely used pesticide thiram is found in various environments and foodstuffs, posing a risk to human health and contaminating the environment. In this work, the novel SERS flexible sensor (FP/AgNWs@ZIF-8) consisting of silver nanowires and zeolite imidazole frameworks combined with filter paper was prepared for the sensitive and rapid detection of thiram on fruit peel surfaces. The effect that different coating cycles of ZIF-8 films exert on the Raman signal enhancement of the sensor was investigated. The results show that optimal Raman response to 4-Aminothiophenol (4-ATP) was demonstrated in the FP/AgNWs@ZIF-8(5) sensor, with a low LOD of 1.6 × 10 −15 M due to a coating period of 5. Furthermore, a novel SERS FP/AgNWs@ZIF-8 sensor with a porous and flexible structure on low-cost and eco-friendly paper was obtained, as to be immersed in a solution of thiram or wiped on a nectarine skin surface, and the highly sensitive LODs of 1.4 × 10 −12 M and 7.4 fg/cm 2 were achieved, respectively. Therefore, this facile, rapid, and sensitive flexible sensor at low-cost has excellent potential for pesticide residue detection and environmental toxicity analysis.
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ACS Omega
·
2023
·
IF 4.1
Jie Liang,Weiwei Zhang,Jun Wang,Wanzhen Li,Fei Ge,Weihao Jin,Yugui Tao
Recently, the combination of chemotherapy and chemodynamic therapy (CDT) has become a desirable strategy in the treatment of cancer. However, a satisfactory therapeutic outcome is often difficult to achieve due to the deficiency of endogenous H2O2 and O2 in the tumor microenvironment. In this study, a CaO2@DOX@Cu/ZIF-8 nanocomposite was prepared as a novel nanocatalytic platform to enable the combination of chemotherapy and CDT in cancer cells. The anticancer drug doxorubicin hydrochloride (DOX) was loaded onto calcium peroxide (CaO2) nanoparticles (NPs) to form CaO2@DOX, which was then encapsulated in a copper zeolitic imidazole ester MOF (Cu/ZIF-8) to form CaO2@DOX@Cu/ZIF-8 NPs. In the mildly acidic tumor microenvironment, CaO2@DOX@Cu/ZIF-8 NPs rapidly disintegrated, releasing CaO2, which reacted with water to generate H2O2 and O2 in the tumor microenvironment. The ability of CaO2@DOX@Cu/ZIF-8 NPs to combine chemotherapy and CDT was assessed by conducting cytotoxicity, living dead staining, cellular uptakes, H&E staining, and TUNEL assays in vitro and in vivo. The combination of chemotherapy and CDT of CaO2@DOX@Cu/ZIF-8 NPs had a more favorable tumor suppression effect than the nanomaterial precursors, which were not capable of the combined chemotherapy/CDT.
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PubMed
高影响因子
CERAMICS INTERNATIONAL
·
2023
·
IF 5.2
Yunhang Liu,Tingting Wu,Hongyuan Zhao,Gan Zhu,Fang Li,Meimei Guo,Qiwen Ran,Sridhar Komarneni
A sensitive carbendazim (CBZ) electrochemical sensor was designed by using Super-P carbon (SPCN) black@zeolitic-imidazolate-framework-8 (SPCN@ZIF-8) nanocomposite modified glassy carbon electrode (SPCN@ZIF-8/GCE). SPCN with pearl-chain nanostructure presented an integrated highly conductive carbon network, which significantly improved the charge transfer efficiency. ZIF-8 nanoparticles possessed high porosity and large specific surface area, which helped to realize the increasement of adsorption ability and accumulation capacity towards CBZ. Moreover, SPCN with excellent conductivity property not only inhibited the agglomeration of ZIF-8 nanoparticles but also compensated the non-conductive property of ZIF-8 nanoparticles. The functional integration of SPCN and ZIF-8 nanoparticles remarkably enhanced the electrochemical detection performance of the SPCN@ZIF-8/GCE sensor towards CBZ. A simple and sensitive CBZ detection could be achieved at the fabricated SPCN@ZIF-8/GCE sensor with low limit of detection of 7.79 nM (CBZ concentration: 0.01–30 μM). Moreover, the fabricated sensor showed good repeatability, reproducibility, and anti-interference performance. When used for the analysis of CBZ in real samples (tomato juice and apple juice), the SPCN@ZIF-8/GCE sensor showed good CBZ detection performance with acceptable recoveries of 99.1%–102.6% and low RSD values of 2.21%–3.27%. This work demonstrated that the SPCN@ZIF-8/GCE sensor may be a promising sensing platform for the rapid and sensitive detection of CBZ residue.
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JOURNAL OF POWER SOURCES
·
2023
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IF 9.2
Muhammad Irfan,Yuli Zang,Zeheng Yang,Weixin Zhang
Rechargeable solid-state lithium metal battery (LMB) is an important next-generation energy storage technology . Anion chemistry of sulfonates plays a vital role in dictating the electrochemical performance of conducting solid polymer electrolytes (CSPEs). CSPE is a crucial need for LMB, although, simultaneously achieving high ionic conductivity and greater cycling performance in LMBs is a huge challenge. Herein, we design and synthesize new sulfonate anions 2-((8-hydroxyoctyl)oxy)ethyl-sulfanetrione (HOEST) and 2-(4-hydroxybutaoxy)ethane-sulfonate (HBES), and a series of CSPEs via coupling of these anions by tetraethyl orthosilicate for LMBs. HOEST-V CSPE consists of HOEST with PVDF polymeric matrix that delivers higher ionic conductivity (3.17 × 10 −3 S cm −1 ) and outstanding cyclability (152 mAh g −1 ) at 25 °C for 1100 cycles. The excellent stability over 500 h of Li stripping/plating, high apparent diffusion coefficient (0.07177), and low activation energy (5.0251 Kj/mol) of HOEST-V impede the lithium dendritic growth for good compatibility with electrodes. The hydrophobic alkyl spacer of HOEST-V with anionic species and hydroxyl wing associated with ether spacer can dissociate and augment the Li + ions mobility resulting from their intramolecular and intermolecular interactions , hydrogen bonding , and ion-dipole interaction. This strategy is promising and opens a new avenue for developing safe and high-performance CSPEs in future.
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Journal of Materials Chemistry B
·
2023
·Vol. 11
·期 18
·4020-4027
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IF 7
Min Feng,Xiaofang Chen,Yuhang Liu,Yan Zhao,Pran Gopal Karmaker,Jia Liu,Ya Wang,Xiupei Yang
Single-atom catalysts with atomically dispersed sites have been widely used as nanozymes for colorimetric sensing because their tunable M–Nx active centers are similar to those of natural enzymes. However, their low metal atom loading leads to insufficient catalytic activity and affects the sensitivity of colorimetric sensing, which limits their further applications. Herein, multi-walled carbon nanotubes (MWCNs) are selected as carriers to reduce the aggregation of ZIF-8 and improve the electron transfer efficiency of nanomaterials. Meanwhile, MWCN/FeZn-NC single-atom nanozymes with excellent peroxidase-like activity were prepared by pyrolysis on ZIF-8 doped with a second metal Fe. Based on the excellent peroxidase activity of MWCN/FeZn-NCs, a dual-functional colorimetric sensing platform for Cr(VI) and 8-hydroxyquinoline was established. The detection limits of the dual-function platform are 40 nM for Cr(VI) and 55 nM for 8-hydroxyquinoline. This work provides a highly sensitive and selective strategy for the detection of Cr(VI) and 8-hydroxyquinoline in hair care products, which has great application prospects in the field of pollutant detection and control.
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PubMed
高影响因子
NANOTECHNOLOGY
·
2022
·Vol. 34
·期 8
·085401
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IF 3.953
Hongna Jia,Yao Wang,Shuya Zhao,Haipeng Wang,Na Ju,Xinyue Zhang,Hong Li,Zejun Sun,Hong-bin Sun
Carbon materials derived from metal-organic frameworks have attracted increasing attention as anodes for energy storage. In this study, Fe, Ni-doped ZIF-8 is carbonized at high temperature to obtain bimetallic Fe and Ni modified tension -relaxed carbon (FeNi@trC). Fe and Ni have opposite structural modification effects when the metal ions are doped into the ZIF-8 dodecahedron. The obtained carbon material maintains the regular dodecahedron morphology, which means the relaxation of tension and strong thermal stability during annealing. Moreover, the presence of nickel enhances the carbonization degree and electrochemical stability of FeNi@trC, while the calcination of the tensive ZIF-8 precursor offers more defect sites. The discharge capacities of FeNi@trC materials are stable at 182.9 mAh·g−1 and 567.9 mAh·g−1 for sodium-ion batterie (SIB) and lithium-ion batterie (LIB) at 0.05 A·g−1. Compared with the current density of 0.05 A·g−1, the discharge capacity of SIB and LIB attenuates by 29.4% and 55.9% at 1 A·g−1, respectively, and the FeNi@trC shows good performance stability in the following cycles.
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FOOD CHEMISTRY
·
2022
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IF 9.231
Qian Wang,Chengyi Xiong,Jingwen Li,Qianchun Deng,Xiuhua Zhang,Shengfu Wang,Miao-Miao Chen
Aflatoxin B1 (AFB1) that is prone to contaminate corns brings a serious threat to human health. Therefore, it is of great significance to construct novel detection methods for AFB1 tracing. Here, methylamine perovskite quantum dots (MP QDs) encapsulated by ZIF-8 metal–organic frameworks (MP QDs@ZIF-8) were prepared and then ultra-stable electrochemiluminescence (ECL) sensors were developed. By the confinement of cavities structure, multiple MP QDs were crystallized and embedded inside ZIF-8 to form MP QDs@ZIF-8, achieving stable and robust ECL responds in aqueous environment. Further combined with AFB1-imprinted polymer, the constructed ECL sensor showed good selectivity and ultra-sensitivity (the detection limit was 3.5 fg/mL, S/N = 3) with a wide linear range from 11.55 fg/mL to 20 ng/mL for AFB1 quantification. Satisfactory recoveries in corn samples indicated the reliable practicability of the proposed sensor for AFB1 assay. This work provided a novel pathway in designing high-performance ECL sensing platform for food safety.
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PubMed
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CHEMICAL ENGINEERING JOURNAL
·
2023
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IF 15.1
Xu Zhang,Tong Qi,Yu Sun,Xinran Chen,Pengxiang Yang,Shuai Wei,Xiyang Cheng,Xiu Dai
Nerve conduits have shown promise as alternatives to autologous nerves, but their repair effects need to be improved. The topographical guidance and functionalization of scaffolds are crucial in nerve repair. In this work, a chitosan-based nerve graft filled with guiding fibres modified by ZIF-8 nanoparticles (CS@ZIF-8) was fabricated for defective nerve repair. An in vitro study demonstrated that CS@ZIF-8 exhibited excellent cytocompatibility and could significantly promote Schwann cell proliferation. In vivo, nerve conduits filled with CS@ZIF-8 were observed to guide stronger axonal longitudinal elongation. Rats bridged with the conduit filled with CS@ZIF-8 showed significant morphological and functional improvements in terms of regenerated nerve density, the number of myelinated nerve fibres, the number of myelin layers, the thickness of myelin sheath, target muscle recovery and sensory function compared to those transplanted with the hollow conduit and the conduit filled with pure chitosan fibres. The repair effects achieved by using the conduit filled with CS@ZIF-8 were similar to those of autografts. Altogether, the data here show that nerve conduits filled with ZIF-8-loaded guide fibres provide a promising approach for repairing nerve defects.
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COMPOSITES PART B-ENGINEERING
·
2023
·
IF 13.1
Can He,Meng Cai,Yu Huang,Xiaoqiang Fan,Minhao Zhu
Despite Ti 3 C 2 T x MXene has certified tremendous promise for improving the anti-corrosion/wear of epoxy resin, it falls short of matching the protective standards under long-term extreme conditions. Herein, 2-methylimidazole zinc salt ZIF-8 was grown in-situ on amino-functionalized Ti 3 C 2 T x nanosheets and doped with cerium cations (P + -Ti 3 C 2 T x @ZCe). The Ti 3 C 2 T x -based composite was then parallel arranged within epoxy coating utilizing electrophoretic deposition technique to prepare a novel self-healing intelligent coating (PMX@ZCe). The encapsulation structure of P + -Ti 3 C 2 T x @ZCe was investigated by XRD , FTIR, XPS, FE-SEM, TEM, Zeta potential and TG techniques. Furthermore, the corrosion/wear resistance and self-healing performances of PMX@ZCe were discussed detailedly and the strengthening mechanism of P + -Ti 3 C 2 T x @ZCe was revealed. Results indicate that PMX@ZCe maintains the highest |Z| 0.01Hz value of 1.24 × 10 10 Ω cm 2 after 4 weeks of electrochemical test and exhibits excellent self-healing efficiency of 153 % under artificial scratch, which is ascribed to the release of Ce 3+ /Ce 4+ that could form insoluble protective films at the coating/metal interface. The wear rate of PMX@ZCe is 2.29 × 10 −5 mm 3 /N · m about 56 % lower than that of EP. PMX@ZCe possesses satisfactory corrosion/wear protection performance, thanks to the synergy of good interfacial interaction , parallel-aligned barrier effect and active-passive protection. This work provides a new design thinking for MXene-based intelligent protective coatings that can meet the demands of multi-service environments.
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Nano Research
·
2023
·
IF 9.9
Lei Miao,Cai Weiye,Zou Luetao,Yu Bin,Chen Lin,Cao Yang,Xiang Shanlin,Song Chao,Lei Jiandu,Jiang Wei,Hu Zhenming
Photothermal therapy (PTT) has been widely used in the treatment of tumors, but its efficacy is greatly limited by the inability of precise drug delivery and the increase of heat shock proteins (HSPs) caused by high temperature. This article describes a therapeutic strategy to enhance PTT with starvation therapy in conjunction with ferroptosis mechanism. A nanoparticle platform ZIF-8@GA was constructed by wrapping together glucose oxidase (GOX) and gold nanospheres (AuNPs) loaded with dihydroartemisinin (DHA) with zeolitic imidazolate framework-8 (ZIF-8). This platform can take advantage of the micro-environment of osteosarcoma (OS) cells, featuring low pH and high reactive oxygen species (ROS), for precision drug delivery. GOX can effectively catalyze glucose to produce gluconic acid and H 2 O 2 , and DHA can also induce ROS production in OS cells. ROS produced by GOX and DHA can further generate lipid peroxidation (LPO) and lead to ferroptosis of OS cells. At the same time, ROS and LPO produced can inhibit the expression of HSPs, thereby increasing the therapeutic effect of PTT. In vitro experiments show that the nanoparticles are pH and ROS responsive. 1 µg/mL GOX combined with 0.2 µg/mL DHA promotes ferroptosis of OS cells, and increases the killing effect of near-infrared (NIR) on OS cells. Further in vivo experiments showed that the nano drug-delivery platform combined with PTT can effectively inhibit the growth of OS cells. Meanwhile, this study provides a new idea for the treatment of OS with biomaterials combined with various treatment methods.
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MICROPOROUS AND MESOPOROUS MATERIALS
·
2023
·
IF 5.2
Zefen Wang,Siyuan Liu,Qian Zhou,Pengru Liu,Dankui Liao,Ping Lan,Bo Peng,Xiongdiao Lan
Immobilized angiotensin converting enzyme (ACE) utilizes specific interaction between ACE and ACE inhibitors to screen drugs for hypertension therapy, but traditional immobilized ACE is insufficient to achieve satisfactory effect for the poor immobilization efficiency and stability. In this work, mesoporous ZIF-8 (mZIF-8) coated with polydopamine (PDA) was developed as an enzyme-immobilization platform for the first time. Molecular docking was used to study the mechanism of ACE induced mZIF-8 synthesis. The immobilized enzyme ACE@mZIF-8/PDA were shown to possess mesoporous structures with ACE encapsulation efficiency of ∼90%. Compared with the free enzyme, ACE@mZIF-8/PDA exhibited enhanced tolerance to temperature, pH, unfolding and proteolytic agents, with excellent reusability (maintained 82.29% ± 4.11% of initial activity after being reused 10 times) and storage stability (retaining 93.12% ± 3.271% residual activity after 30 days). Molecular docking research conformed ACE induced the triggered nucleation of MOFs via binding with MOFs precursors. Moreover, ACE@mZIF-8/PDA was used as high-performance adsorbent for enrichment of ACE inhibitory peptides. The noncompetitive inhibitory peptide GF-6 and competitive inhibitory peptide VPP could be captured synchronously, which avoided the loss of active substances. These results indicated that the ACE@mZIF-8/PDA provides an evolutionary platform for rapid screening of inhibitory peptides.
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危险品化学品经营许可证（带存储）