JOURNAL OF ALLOYS AND COMPOUNDS
·
2018
·
IF 3.779
Ni Xiong,Rui Bao,Jianhong Yi,Dong Fang,Jingmei Tao,Yichun Liu
CNTs/Cu-Ti composites were fabricated successfully by spray pyrolysis , low energy ball milling and subsequent hot pressing (HP). Microstructure and mechanical properties of the composites were characterized by SEM, EDS, HRTEM , XRD, hardness and tensile tests. The results reveal that in situ generated nano-TiC particles, as a transition phase from CNTs to Cu-Ti matrix, which played a “rivet” role in enhancing the interfacial bonding between the CNTs and Cu-Ti matrix is formed in the composites. Consequently, mechanical properties of the CNTs/Cu-Ti composites are enhanced compared with alloy matrix, and an optimal balance between elevated ultimate tensile strength and impressively larger plastic deformation is achieved by adding 0.4 wt% CNTs in the composites. (ultimate tensile strength (UTS) 352 MPa, elongation 28.2%, the UTS is 39% higher than that of the Cu-Ti alloy, and the ductility increased significantly by 62%.) Finally, strengthening and toughening mechanisms are discussed. This study provides new insights into the interface structure and strength-ductility in metal-matrix composites.
研究领域:
材料科学
·
力学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF ALLOYS AND COMPOUNDS
·
2017
·
IF 3.133
Li-Feng Zhu,Bo-Ping Zhang,Shun Li,Gao-Lei Zhao
The (1- x )Bi 1+ y (Fe 0.96 Mg 0.02 Ti 0.02 )O 3 - x BaTiO 3 (abbreviated as B 1+ y FMT- x BT) system was designed to explore the morphotropic phase boundary (MPB) separating rhombohedral ( R ) and tetragonal ( T ) phases, and the mechanism of performance enhancement. The phase structure of samples was discreetly investigated by X-ray diffraction, and Rietveld refinement results of the XRD data revealed that the B 1+ y FMT- x BT ceramics consist of an R phase at x = 0.24, two R and T phases at 0.26 ≤ x ≤ 0.32, and a single T phase at x = 0.34. Because of the MPB and the improvement of resistivity with adding excess Bi compensation, excellent piezoelectric properties of d 33 = 198 pC/N and k p = 30.9%, as well as high Curie temperature T C = 497 °C were achieved in the B 1+ y FMT- x BT system at x = 0.30 and y = 0.02. Here, the large d 33 = 198 pC/N which is the maximum value for the BF-BT-Bi(Mg,Ti)O 3 system so far, and high T C = 497 °C suggest that Bi(Fe,Mg,Ti)O 3 -BaTiO 3 ceramics have good prospects in high-temperature piezoelectric devices.
研究领域:
材料科学
·
物理学
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产品关联
DOI
高影响因子
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
·
2022
·
IF 5.141
Zekai Sheng,Fengming Hou,Leilei Zou,Yihang Li,Jiaxin Li,Jin Li,Libang Ai,Wei Wei,Ang Wei
Aspergillus fumigatus ( A. fumigatus ) is a representative significant pathogenic fungus and its spores are arduous to inactivate. Herein, an efficient and environmental-friendly photocatalytic method to eliminate A. fumigatus spores was demonstrated. Zn-Ti layered double hydroxide (Zn-Ti LDH), showed the admirable activity with above 99.34% disinfection rate under visible light illumination for 6 h. The compelling sterilization activities were ascribed to the potent synergistic effect of zinc ions (Zn 2+ ) and reactive oxygen species (ROS). The attack of these species caused the eradication of fungal cell structure, and resulting in the leakage of cytoplasmic as demonstrated by scanning electron microscope, confocal laser scanning microscope and potassium ions (K + ) leakage test. In addition, Zn-Ti LDH released Zn 2+ and ROS only under visible light irradiation, which endows the material light-triggered bactericidal property. Overall, these findings not only provide a green and sustainable way to control A. fumigatus contaminations, but also can be as an example to control other toxic fungi in future study.
研究领域:
微生物学
·
环境科学
✓ 已验证
产品关联
DOI
高影响因子
Chem
·
2023
·
IF 23.5
Yibo Wang,Rongpeng Ma,Zhaoping Shi,Hongxiang Wu,Shuai Hou,Ying Wang,Changpeng Liu,Junjie Ge,Wei Xing
The acidic oxygen evolution reaction (OER) faces great difficulty in concurrently addressing the site-specific activity and stability of the up-to-date choice Ir-based catalysts. Herein, we adopted a new inverse doping strategy to devise a Ti atomic doping into the surficial IrO x /Ir matrix to investigate the boosting effect of Ir-O-Ti motifs toward OER. Notably, only 1.92 wt % Ti introduction leads to 3.6 times and an order of magnitude improvement in intrinsic activity and stability, respectively, ascribed to the creation of abundant Ir-O-Ti motifs. While the Ti sites donate electrons to weaken the Ir-O interaction and thereby ignite Ir sites activity via adsorbate evolution mechanism (AEM), the restricted O–O bond formation in the lattice oxygen mechanism (LOM) and the widened stable region of Ir species help enhance the stability. This work provides a novel insight into the reactivity of atomic-level interface motifs in heterogeneous components, which inspires further design of advanced catalysts.
研究领域:
材料科学
·
电催化
✓ 已验证
产品关联
DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2020
·
IF 10.652
Zhu Gao,Jiaxing Wang,Yaseen Muhammad,Yibo Zhang,Syed Jalil Shah,Yang Hu,Zhe Chu,Zhongxing Zhao,Zhenxia Zhao
High photo-catalytic activity and stable recycling performance under high humidity are main hindering factors in practical applications of metal organic frameworks (MOFs) for volatile organic compounds (VOCs) degradation. In-situ co-doping strategy of pyrrolic N/Zn was proposed to enhance surface charge separation and cycling stability of MIL-125(Ti) for degradation of vaporous acetaldehyde under highly humid conditions. Characterizations results show that pyrrolic N/Zn co-doped MIL-125(Ti) exhibited an integrated crystal structure and high surface area (1415 m 2 /g). The constructed Ti/Zn-N/O clusters narrowed band gap (from 3.40 to 1.85 eV) of MIL-125(Ti) and boosted electron conductivity. Also, it was proved to enhance surface alkalinity and hydrophobicity of MIL-125(Ti), which would strengthen MOFs selective adsorption towards CH 3 CHO and accelerated the transfer of degradation product CO 2 from catalytic active sites in MIL-125(Ti) under high humidity. As a result, synergistic effect of N/Zn co-doping exhibited an enhanced the ability of activating oxygen and H 2 O molecules into superoxide radical ( O 2 − ) and hydroxy radical ( OH), showing 10 times faster reaction kinetics for CH 3 CHO degradation under humid air compared to MIL-125(Ti). Moreover, co-dopant of N/Zn into MIL-125(Ti) has significantly promoted the recycling stability of MIL-125(Ti) under high humidity. According to the work, co-dopant elemental strategy to modify MOF surface can provide the synergistic effect for efficient degradation of aldehyde VOCs under humid conditions.
研究领域:
材料科学
·
环境科学
✓ 已验证
DOI
高影响因子
JOURNAL OF CHROMATOGRAPHY B-ANALYTICAL TECHNOLOGIES IN THE BIOMEDICAL AND LIFE SCIENCES
·
2021
·
IF 3.205
XinHui Wang,JiaLin Yu,HaoDing Yang,Jian Shen,HaiLong Liu,JiaHong Zhou
Ti-based immobilized metal affinity chromatography (IMAC) nanomaterial has shown high potential in phosphoproteome mass-spectrometric (MS) analysis. However, the limited surface area and poor solubility will greatly restrict its use in phosphoproteome research. To overcome these two key drawbacks, a novel Ti-based IMAC nanomaterial was prepared by Ti-bonded β-cyclodextrin (β-CD) anchored on the surface of carbon nanotubes (CNTs) (denoted as COOH-CNTs-CD-Ti) and successfully applied as a biofunctional adsorbent for selectively enriching trace phosphopeptides. In the selective enrichment process, CNTs provided greater surface area for the absorption of phosphopeptides, while β-CD also offered a greater opportunity for the interaction between phosphopeptides and Ti 4+ . COOH-CNTs-CD-Ti with the aforementioned properities exhibited higher selectivity for phosphopeptides from the standard protein digests, the tryptic digests of nonfat milk and human serum, showing a great selective enrichment capability towards complex biological samples.
研究领域:
生物化学
·
纳米生物学
·
蛋白质组学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
SEPARATION AND PURIFICATION TECHNOLOGY
·
2023
·
IF 8.6
Rui Cao,Langlang Wang,Xueqian Wang,Yibing Xie,Xiang Li,Ping Ning
The low-temperature conversion of corrosive carbonyl sulfide (COS) in steel by-product gas is essential for the clean utilization of this gas. Herein, La-Ti@K catalysts doped with La nanoparticles were shown to exhibit significant photopromoted thermocatalytic activity and stability under UV light irradiation. At a reaction temperature of 60 °C, the TOF value increased from 4.84 × 10 -4 s −1 (TiO 2 , thermal treatment) to 8.43 × 10 -4 s −1 (La-Ti@K, photothermal treatment), and the H 2 S selectivity exceeded 99%. This was because La doping increased the density of basic sites on TiO 2 , which promoted the continuous dissociation of H 2 O in the system and the regeneration of –OH under UV irradiation. Moreover, the photogenerated electrons from TiO 2 were transferred to La to maintain the metallic La nanoparticles, as well as to ensure the activation and photothermal hydrolysis of COS. The presence of a suitable electron-metal-support interaction (EMSI) between the electron-rich La nanoparticles and TiO 2 might be responsible for these phenomena. In addition, theoretical calculations revealed that light-induced electron transfer was conducive to H 2 O dissociation and COS activation, while La doping reduced the free energy of the hydrolysis reaction. This work demonstrates the effectiveness of La-Ti@K catalyst in COS photothermal hydrolysis and provides a theoretical basis for further understanding of the photothermal catalytic mechanism.
研究领域:
环境科学
·
催化化学
·
材料科学
✓ 已验证
产品关联
DOI
高影响因子
Journal of Materials Chemistry A
·
2025
·
IF 9.5
Chen Su,Mingyu Li,Shuai Zhang,Weiqing Liu,Yuanzhang Wang,Peipei Li,Huanran Feng,Ming-Shui Yao,Weiwei Wu,Lu Zhang
The development of multifunctional hydrogels with enhanced mechanical, electrical, and electromagnetic properties has become a key focus in various advanced applications, including wearable electronics, strain sensors, and electromagnetic interference (EMI) shielding. However, challenges remain in achieving a balanced integration of stretchability, conductivity, and broadband microwave absorption within a single material. This study addresses these limitations by introducing a novel dual-crosslinked Ti₃C₂Tx MXene-based hydrogel designed for wearable sensor and EMI shielding applications. The PVA/MXene/PSS hydrogel is synthesized via a freeze-thaw crosslinking method to create a three-dimensional (3D) conductive network. Water retention and conductivity are enhanced through the synergistic effect between sodium chloride (NaCl) and formic acid (HCOOH), addressing key challenges such as water evaporation and MXene dispersion. The resulting hydrogel exhibits impressive mechanical stretchability (369% tensile strain), long-term stability (6000 s under 25% strain), and ultra-high strain sensitivity with a minimum detectable strain of 1%. It demonstrates gauge factors of 0.78 and 0.51 in the transverse and longitudinal directions for strains below 50%, respectively, and 0.28 and 0.37 for strains between 50% and 100%. Moreover, it demonstrates exceptional broadband microwave absorption with a peak reflection loss of −55.5 dB at 10.73 GHz, with an effective absorption bandwidth of 6.34 GHz. The combination of excellent mechanical, electrical, and microwave properties, along with superior stretchability and durability, makes this hydrogel a promising candidate for next-generation wearable sensors, flexible electronics, and electromagnetic interference shielding.
研究领域:
材料科学
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电子工程
·
传感器技术
✓ 已验证
产品关联
DOI
高影响因子
CATALYSIS LETTERS
·
2019
·Vol. 149
·期 9
·2586-2596
·
IF 2.372
Shen Xiaohua,Wang Jingjing,Liu Miaoqing,Li Mengzhe,Lu Jianjun
Abstract A new route to synthesis hierarchical Ti-rich TS-1 with uniform intracrystalline mesopores, uniform crystal size and the higher Ti content has been developed by using the environmental-friendly and cheap surfactant Triton X-100 as the assisted template agent and (NH 4 ) 2 CO 3 as crystallization-mediating agent. In this way, the surface area and pore volume of the resulting materials can be adjusted by the Triton X-100 content. The catalytic properties of the Nano-size hierarchical Ti-rich TS-1 were investigated by hydroxylation of benzene to phenol with H 2 O 2 as oxidizing agent and deionized water as solvent. Due to the combination of hierarchical pores and high titanium content, the hierarchical Ti-rich TS-1 shows improved catalytic activity in the oxidation of benzene. Graphical Abstract
研究领域:
材料科学
·
催化化学
✓ 已验证
产品关联
DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2017
·
IF 6.216
Haiyan Song,Jiang-An You,Bin Li,Chunxia Chen,Jie Huang,Jin Zhang
Novel titanosilicate composites with bimodal mesopores using molecular sieves Ti-HMS and Ti-KIL-2 as structural components were successfully synthesized by two-step and dual-template methods in a comparative study. The as-synthesized Ti-HMS/KIL-2 samples were characterized by a series of techniques including X-ray diffraction, UV–vis, N 2 sorption and scanning electronic microscopy, and their performance was tested in adsorptive denitrogenation for model fuel containing pyridine or quinoline. Although Ti-HMS/KIL-2 composites were constructed following the different pathway of self-assembly, most of them obtained coexisting properties and structures of Ti-HMS and Ti-KIL-2, as well as the intact framework Ti in tetrahedral coordination. A key finding is that the mesopores size of Ti-KIL-2 component in the composite can be regulated via the introduction of Ti-HMS precursor or organic template dodecylamine. Especially, the composites of dual-template method presented hierarchical mesopores with obvious bimodal distribution. In addition to constructing the hierarchical structure, introduction of Ti-HMS into Ti-KIL-2 matrix improved the adsorptive denitrogenation performance, which was influenced by the synthetic strategy of Ti-HMS/KIL-2. The target adsorbates achieved the best match with the adjustable pores of Ti-HMS/KIL-2. Therefore, (0.6 D )Ti-HMS/KIL-2 and (0.5 T )Ti-HMS/KIL-2 as the optimized adsorbents obtained remarkable adsorption efficiency respectively for pyridine and quinoline. Essence of the adsorptive denitrogenation process was revealed via the adsorption isotherms and the adsorption thermodynamics. Finally, Ti-HMS/KIL-2 composites achieved the improvement in hydrothermal stability and recyclability during adsorption of pyridine and quinoline, and exhibited the potential of industrial application.
研究领域:
材料科学
·
化学工程
·
环境科学
✓ 已验证
产品关联
DOI
高影响因子
MICROCHEMICAL JOURNAL
·
2023
·
IF 4.8
Xixiang Meng,Caizhi Lv,Xiaohui Wen,Xiandeng Hou,Chenghui Li,Juan He
A new bimetallic-centered MOFs, NH 2 -MIL-125(Ti/Ce), was synthesized by partially replacing Ti with Ce. The doping of Ce endowed the MOFs oxidase-like activity and enabled the construction of a ratiometric fluorescence sensing system in combination with o-phenylenediamine (OPD) for detecting trace Cu 2+ with a limit of detection of 16 nM and a linear range of 0.02–50 μM. Trace Cu 2+ was successfully quantified in real water samples. The doping of Ce also increased the photocatalytic capability of the MOFs by about 2 times, achieving excellent reduction of Cr(Ⅵ) under natural light conditions.
研究领域:
材料科学
·
环境科学
·
分析化学
✓ 已验证
产品关联
DOI
高影响因子
APPLIED CATALYSIS A-GENERAL
·
2024
·
IF 4.7
Meidan Que,Yabo Wang,Ruochen Shi,Xun Sun,Jun Xu,Peihong Ma,Yanbo Sun,Jing Guan,Shengxia An
MIL-125(Ti) is well known for having stable structure, tunable electron structure, and multiple active sites, which is commonly studied in the field of photocatalysis . In this work, a series of rare earth (RE) doped MIL-125(Ti) (RE=Ce, Pr, Tm, Dy, Eu, and Sm) are prepared via the one-step hydrothermal method . Notably, Pr-MIL-125 displays a significantly enhanced catalytic performance than other RE-doped MIL-125, resulting in a maximal CO and CH 4 yield of 13.30 and 0.87 µmol·g −1 ·h −1 , respectively, which are 2.53-fold and 4.14-fold of the pristine MIL-125. The layered morphology endows Pr-MIL-125 with more active sites and facilitates the reaction of photoreduction CO 2 . Furthermore, the promoted photoactivities attributed to Pr ion dopant can act as electron transfer bridge and suppress charge recombination. This work would provide insight and guidance for designing RE-MOF based photocatalysts and enhancing the performance of photoreduction CO 2 .
研究领域:
材料化学
·
光催化
·
环境科学
·
无机化学
·
能源化学
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）