RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
·
2014
·Vol. 40
·期 10
·764-767
·
IF 0.629
Li G. B.,Wang S. X.,Su W. Y.,Pan R. K.,Liu K. D.,Liu S. G.
A new cationic complex, [Co(Bpbp) 2 ](ClO 4 ) 2 · DMF · H 2 O, was synthesized by treatment Co(ClO 4 ) 2 · 6H 2 O with 2,6- bis (1-phenylbenzimidazol-2-yl)pyridine (Bpbp) in DMF solvent at room temperature. Its structure was characterized by element analysis, IR, and X-ray single crystal structure analyses (CIF file CCDC no. 970498). For complex, crystal system, triclinic, space group, \(P\bar \imath\) , a = 11.585(13), b = 13.939(16), c = 19.236(2) \(\mathop {\AA}\limits^\prime\) , α = 97.938(2)°, β = 102.814(2)°, γ = 90.556(2)°, V = 2861.1(6) Ǻ 3 , Z = 2. The Co 2+ ion octahedral geometry is coordinated by six nitrogen atoms from two ligand (Bpbp). The antiproliferative activities of the complex were screened by MTT assay against HepG2, Huh7, Eca109 and Eca9706 cancer cell. The complex exhibits inhibition on Eca9706 and Eca109 cancer cell but no HepG2 and Huh7 cancer cell.
研究领域:
无机化学
·
药物化学
·
肿瘤学
✓ 已验证
DOI
高影响因子
Optical Materials Express
·
2019
·Vol. 9
·期 9
·3835-3842
·
IF 2.673
Xianshun Lv,Xianshun Lv,Xianshun Lv,Ping Wang,Huajian Yu,Huajian Yu,Yanyan Hu,Yanyan Hu,Huadi Zhang,Huadi Zhang,Chengcheng Qiu,Chengcheng Qiu,Jing Li,Jing Li,Jing Li,Xuping Wang,Xuping Wang,Bing Liu,Bing Liu,Yuanyuan Zhang,Yuanyuan Zhang,Yuanyuan Zhang
A colorless crystal of Ba2Mg(BO3)2 about 37 × 25 × 17 mm3 has been grown successfully by the Kyropoulos method. Thermal analyses results show that Ba2Mg(BO3)2 melts congruently. The phase purity of the raw materials and the grown crystals were confirmed by powder X-ray diffraction. Ba2Mg(BO3)2 exhibits a low UV cutoff of 187 nm and high transmittance below 3000 nm. The refractive indices of the crystal have been measured and the the least-squares fitting method was used to obtain the Sellmeier dispersion equations. The results indicate that Ba2Mg(BO3)2 is a potential birefringence crystal with large birefringence of 0.10422 at 546 nm.
研究领域:
材料科学
·
光学
✓ 已验证
DOI
高影响因子
TEXTILE RESEARCH JOURNAL
·
2016
·
IF 1.299
Yangyi Chen,Jie An,Qi Zhong,Peter Müller-Buschbaum,Jiping Wang
The smart control of cotton fabric comfort by cross-linking thermo-responsive random copolymer is investigated. The monomers 2-(2-methoxyethoxy) ethoxyethyl methacrylate (MEO2MA) and ethylene glycol methacrylate (EGMA) with a molar ratio of 17:3 are selected to synthesize the thermo-responsive random copolymer poly(2-(2-methoxyethoxy) ethoxyethyl methacrylate-co-ethylene glycol methacrylate), abbreviated as P(MEO2MA-co-EGMA). By using citric acid as a cross-linking agent, the obtained P(MEO2MA-co-EGMA) is successfully immobilized onto cotton fabrics. Smart control is achieved from the thermo-responsive behavior of the copolymer. Cross-linked P(MEO2MA-co-EGMA) will collapse when the ambient temperature exceeds its transition temperature. Therefore, the formerly compact P(MEO2MA-co-EGMA) layer will switch to a porous structure, and the air/moisture permeability of the textiles is enhanced. As the comfort of the textiles is closely related to the air/moisture permeability, a smart control of the cotton fabric comfort can be realized. In addition, the softness of cotton fabrics with and without thermo-responsive polymers does not show a prominent change, even when the applied solution concentration is as high as 16% (wt%). On the contrary, the stiffness of the cotton fabric coated with poly(N-isopropylacrylamide) (PNIPAM) is significantly higher than the original cotton fabric, indicating that homo PNIPAM is less suitable for textiles used in daily lives. Moreover, the whiteness and mechanical properties are studied and stay unchanged after cross-linking. As a consequence, the introduction of P(MEO2MA-co-EGMA) into textiles can provide textiles with smart control of cotton comfort, and it will not influence the wearabilities of the textiles.
研究领域:
纺织科学
·
聚合物化学
·
材料科学
✓ 已验证
DOI
高影响因子
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY
·
2020
·
IF 4.192
Jian Zhou,Min Li,Jiaqian Li,Zixuan Shao,Yiman Liu,Tiecheng Wang,Lingyan Zhu
As emerging alternatives of legacy perfluoroalkyl substances, 6:2 fluorotelomer sulfonate (6:2 FTS), 6:2 chlorinated polyfluoroalkyl ether sulfonates (6:2 Cl-PFESA), and perfluorophosphinates (C6/C6 and C8/C8 PFPiAs) are supposed to be partitioned to soil and highly persistent in the environment. The uptake of novel per- and polyfluoroalkyl substances (PFASs) by plants represents a potential pathway for their transfer in the food chain. In this study, the bioavailability of these four novel PFASs in soil and the bioaccumulation characteristics in greenhouse-grown wheat (Triticum aestivum L.), maize (Zea mays L.), soybean (Glycine max L. Merrill), and pumpkin (Cucurbita maxima L.) were investigated. The results indicated that these novel PFASs with higher hydrophobicity were more easily sequestrated in soil, and the fractions extracted by methanol could well describe their bioavailability, which could be stimulated by low-molecular-weight organic acids at rhizospheric concentrations. A negative relationship was found between root soil concentration factors (RSCFs) and hydrophobicity (log Kow) of the target PFASs. This correlation was also found in the translocation factors (TF) from roots to shoots. Furthermore, the uptake and transfer of the target PFASs were regulated by the protein contents in plant roots and shoots.
研究领域:
环境科学
·
农业
·
毒理学
·
植物生理学
✓ 已验证
DOI
PubMed
高影响因子
Soft Matter
·
2017
·Vol. 13
·期 19
·3514-3520
·
IF 3.889
Huifang Xu,Na Du,Yawen Song,Shue Song,Wanguo Hou
In the current work, the microviscosity, encapsulation, and permeability of 2-ketooctanoic acid (KOCOOH) vesicle membranes were investigated by steady-state and time-resolved fluorescence techniques, using 1,6-diphenyl-1,3,5-hexatriene (DPH), riboflavin, and calcein as fluorescence probes. Our results show that the microviscosity of KOCOOH membranes is similar to that of common bilayer aggregates, the KOCOOH vesicles have the ability to encapsulate hydrophilic guests, and the KOCOOH membranes are permeable to ions. The permeation of OH− across KOCOOH membranes can be well described using a first-order kinetic model. The KOCOOH vesicles may be a good alternative protocell model that possesses some functional properties necessary for early cell membranes. To the best of our knowledge, this is the first report on the characteristics of vesicle membranes of single-tailed keto-acid amphiphiles.
研究领域:
生物物理化学
·
膜生物学
·
化学生物学
·
原始细胞研究
·
分子自组装
·
前生命化学
✓ 已验证
DOI
高影响因子
RESEARCH ON CHEMICAL INTERMEDIATES
·
2017
·Vol. 43
·期 8
·4353-4368
·
IF 1.369
Yuan Hong,He Jie,Li Ruilan,Ma Xiaoqin
The solid acid catalysts SO 4
2− /TiO 2 were prepared by the impregnation technique under two preparation conditions which were different in calcination temperature and concentration of impregnation solution of H 2 SO 4 . The characterization was carried out by using Fourier transform infrared spectrometer (FTIR), X-ray diffraction (XRD), temperature programmed desorption of NH 3 (NH 3 -TPD), N 2 -BET, X-ray fluorescence and thermal gravity (TG)–differential scanning calorimetry (DSC). The characteristic peaks in the FTIR spectrum were essentially the same within the calcination temperature range of 400–600 °C. The XRD results indicated that the sample could show partial specific peaks of the anatase phase as the calcination temperature was higher than 400 °C. The obvious strong acid and superacid sites of the prepared SO 4
2− /TiO 2 were conformed by the NH 3 -TPD results. The BET surface areas of 102–206 m 2 /g were measured by the N 2 -BET method, and the pore size distributions were essentially mesoporous. The TG–DSC results showed that SO 4
2− /TiO 2 would decompose at about 500 °C in the air. The solid acid SO 4
2− /TiO 2 were used for the epoxidation of castor oil. The lowest iodine value of the product was 52.65/100 g when the reaction temperature was 65 °C, reaction time was 10 h and catalyst loading was 15 wt.%.
研究领域:
化学工程
·
催化材料科学
✓ 已验证
DOI
高影响因子
SENSORS
·
2025
·Vol. 25
·期 6
·1637
·
IF 3.5
Jincai Yang,Zunquan Zhao,Tianyi Ma,Jialei Bai
Point-of-care (POC) antigen detection plays a crucial role in curbing the spread of viruses. Paper-based fluorescence aptasensors are expected to offer a low-cost tool to meet the needs of decentralized POC diagnosis. Herein, we report on a fluorescent paper-based sensing system for detecting the SARS-CoV-2 spike protein. The sensing system was constructed by loading multi-layer Nb2C MXene nano-quenchers and carbon-dot-labeled aptamer (G-CDs@Apt) probes onto a mixed cellulose ester (MCE) paper substrate. On the Nb2C MXene/G-CDs@Apt sensing paper, abundant G-CDs@Apt probes were attached to the multilayer MXene nano-quenchers and kept in a fluorescence-off state, while recognition of the target detached the G-CDs@Apt probes formed the nano--quenchers, resulting in fluorescence recovery of the sensing paper. The developed paper-based sensor performed well in the one-step detection of the SARS-CoV-2 S1 protein with a detection limit of 0.067 ng/mL (0.335 pg/test). The assay exhibited good selectivity and anti-interference in the detection of the SARS-CoV-2 S1 protein in artificial saliva. Moreover, the paper-based aptasensor was successfully used to detect the SARS-CoV-2 S1 protein in actual environmental samples with recoveries of 90.87–100.55% and relative standard deviations of 1.52–3.41%. The proposed technology provides a cost-effective alternative to traditional antibody test strips for a wide range of POC diagnostic applications.
研究领域:
生物传感技术
·
医学诊断
·
病毒学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
Environmental Science-Nano
·
2022
·Vol. 9
·期 8
·2653-2664
·
IF 9.473
Guofang Zhang,Guoli Cao,Rong-Hua Luo,Qingle Song,Yanqiao Zeng,Ke Liu,Jing Qu,Xian Lin,Feng-Liang Liu,Guocheng Wang,Hongchang Li,Liang Li,Yong-Tang Zheng,Diana Boraschi,Lidong Wu,Yan-Zhong Chang,Yang Li
Microplastics (MP) pollution is a global issue that raises concerns about potential toxicity for environmental and human health. The notion that SARS-CoV-2 is more stable when adsorbed on plastic surfaces urged us to examine whether the virus can attach to MP, which may facilitate infection upon inhalation or ingestion. Here, we describe that MP can bind SARS-CoV-2 pseudovirus on their surface and enhance infection of human cells in vitro. This enhanced in vitro infectivity was confirmed with authentic SARS-CoV-2, in parallel with increased expression of inflammation-related caspase-3, IL-8 and TNF-α genes. These results suggest that the presence of MP in the environment or in our respiratory or gastrointestinal tracts has the potential to interact with SARS-CoV-2, and potentially increase viral infectivity and spreading.
研究领域:
环境科学
·
病毒学
·
毒理学
·
细胞生物学
✓ 已验证
DOI
高影响因子
CLAYS AND CLAY MINERALS
·
2024
·Vol. 66
·期 5
·415-425
·
IF 2
Honghai Wu,Zhenhao Song,Meixiang Lv,Dan Zhao,Guangping He
Many types of oxidative pollutants are dangerous chemicals and may pose a health risk, but an inexpensive and effective method for mitigating those risks would offer significant advantages. The objective of this study was, therefore, to investigate the potential for Fe-pillared montmorillonite to fill that gap. Surface mediated reduction reactions by ferrous species often play an important role in governing the transport, transformation, and fate of hazardous oxidative contaminants. Compared to the untreated montmorillonite (Mnt), the synthetic polyhydroxyl-Fe pillared montmorillonite (Fe-Mnt) was found to be somewhat similar to goethite in promoting the ability of specifically adsorbed Fe(II) to reductively transform 2-nitrophenol (2-NP). The 2-NP was efficiently removed within 30 min from solutions at the optimum neutral pH in a mixed reduction system of Fe(II)/Fe-Mnt under an anoxic atmosphere. This demonstrated that the specifically adsorbed Fe(II) of Fe-Mnt can enhance 2-NP reduction. The highly enhanced 2-NP reduction by Fe(II) through Fe-Mnt surface catalysis can, therefore, be ascribed to clearly increased amounts of an adsorbed Fe(II) species surface complex, which gave rise to enhanced Fe(II) reductive activity that enabled the rapid reduction of 2-NP. The reduction processes produced a faster transformation of 2-NP in a Fe-Mnt suspension than in a Mnt suspension. The transformation kinetics were described using pseudo-first-order rate equations. Moreover, in addition to the effects of mineral surface properties, the interactions were affected by the aqueous chemistry, and the removal rates of 2-NP were increased at pHs of 6.0–7.3. In the present study, the structure and surface reactivity of Fe-Mnt was characterized in depth. The polyhydroxyl-Fe added to Mnt and the pH were determined to be the two key controlling factors to mediate the reductive transformation of 2-NP in the presence of Fe-Mnt in comparison to goethite and Mnt. Finally, the catalysis mechanism responsible for the enhanced 2-NP reduction by Fe(II) was elucidated using cyclic voltammetry.
研究领域:
环境化学
·
催化科学
·
污染治理
·
材料化学
·
表面反应动力学
✓ 已验证
DOI
高影响因子
Food Bioscience
·
2020
·
IF 3.067
Liang Gao,Xinyi Cheng,Xuwei Yu,Xiaosan Wang,Qingzhe Jin,Xingguo Wang
1-Oleoyl-2-palmitoyl-3-linoleoylglycerol (OPL) is a critical structured lipid in human milk fat and it plays an important role in infants' health. The development of an efficient method for such compound preparation is necessary. In this study, one- and two-step methods for OPL production by enzymatic acidolysis of fractionated palm stearin with mixed acids were compared in solvent-free and solvent systems. The results demonstrated that in the solvent system, the OPL contents by the one- and two-step methods were 45.8% and 56.7%, respectively. In the solvent-free system, the one- and two-step methods resulted in the formation of 43.7% and 54.8% OPL, respectively. Subsequently, acidolysis conditions of the two-step method were optimized. Under the optimum conditions, the content of OPL was 57.7%, and 83.2% of palmitic acid was at the sn-2 position . The prepared OPL has potential to be applied in infant formulas.
研究领域:
食品科学
·
生物化学
✓ 已验证
DOI
高影响因子
ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY
·
2020
·
IF 4.872
Ruifen Kang,Aneela Perveen,Chunmei Li
T-2 toxin is a kind of group A trichothecenes mycotoxins , frequently detected in various foods and feeds, having high toxic effects on both humans and animals. The present study aims to investigate the toxic effects of T-2 toxin exposure to ICR mice during pregnancy and lactation on liver glycolipid metabolism of young mice. The pregnant mice were given 0, 0.005 and 0.05 mg of T-2 toxin/kg bw daily through oral gavage from late gestation (GD 14) to the lactation (LD 21). Liver and serum samples of the young mice were collected on postnatal day 21 (PND 21), PND 28 and PND 56. The results showed that T-2 toxin increased the contents of triglycerides (TG), total cholesterol (T-CHO) and glucose in serum of young mice on PND 21 and PND 28. In addition, obvious lipid droplets of liver in T-2 toxin treatment groups were observed, especially in 0.05 mg group of PND 21and PND 28. Compared with the control group, T-2 treatment also increased the expressions of genes associated with liver glycolipid metabolism, such as PEPCK , Glut2 , Fas , Acox1 , Hmgcr , PPARα , Srebp1 and CD36 . These results demonstrated T-2 toxin exposure to pregnant mice could cause liver glycolipid metabolism disruption in the young mice and the toxic effects weakened on PND 56.
研究领域:
毒理学
·
营养学
✓ 已验证
DOI
PubMed
高影响因子
DALTON TRANSACTIONS
·
2015
·Vol. 44
·期 41
·18012-18018
·
IF 4.197
Yongfeng Liu,Yaxiong Yang,Xin Zhang,You Li,Mingxia Gao,Hongge Pan
The thermal dehydrogenation process of the KOH-containing Mg(NH2)2–2LiH system was systematically investigated by identifying changes in the structure and composition of its components by XRD and FTIR. During ball milling, the added KOH reacts with Mg(NH2)2 and LiH to produce MgO, KH and Li2K(NH2)3. During the initial heating process (<120 °C), the newly formed KH and Li2K(NH2)3 react with Mg(NH2)2 and LiH to yield MgNH, LiNH2 and Li3K(NH2)4 along with hydrogen release. Raising the temperature to 185 °C results in a reaction between Mg(NH2)2, MgNH and LiH that gives Li2Mg2N3H3 as the product and further releases hydrogen. As the temperature is increased to 220 °C, Li2Mg2N3H3 reacts with LiNH2 and LiH to produce Li2MgN2H2 and H2. Meanwhile, two parallel reactions between Li2Mg2N3H3, Li3K(NH2)4 and LiH also generate additional hydrogen. Specifically, the KH and Li2K(NH2)3, formed in situ during ball milling, serve as reactants in the dehydrogenation reaction of the Mg(NH2)2–2LiH system, which is responsible for the significantly improved thermodynamics and kinetics of hydrogen storage.
研究领域:
材料科学
·
化学工程
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）