JOURNAL OF APPLIED POLYMER SCIENCE
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2014
·Vol. 131
·期 18
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IF 1.64
Qiheng Tang,Yun Song,Jiyu He,Rongjie Yang
A series of thermoplastic poly(imide-urethane)s (TPIUs), based on 4,4′-diphenylmethane diisocyanate (MDI) and pyromellitic anhydride (PMDA) as hard segments and poly(tetrahydrofuran) (PTMG) as soft segments, has been prepared by a two-step polymerization process. The objective of this study is to prepare a type of intrinsically flame-retardant polyurethane by incorporating PMDA as a flame retardant in the main chains. The thermal behavior and flame retardancies of the TPIUs have been characterized by thermal gravimetric (TG) analysis and limiting oxygen index (LOI), UL-94 vertical burning, cone calorimeter tests. The results indicate that the TPIUs display outstanding performance. The temperature at 5% mass loss ( T 5% ) and LOI value increase with the hard-segment contents, while the total heat released (THR) and peak heat release rate (p-HRR) show the opposite trend. Furthermore, the T 5% of TPIU211 (molar ratio: MDI : PTMG : PMDA = 2 : 1 : 1) is 33.2°C higher than that of the conventional thermoplastic polyurethane TPU211 (molar ratio: MDI : PTMG : 1,4-butanediol = 2 : 1 : 1), and the THR and p-HRR of TPIU211 are 14.62% and 64.02% lower than the respective parameters of TPU211. In addition, UL-94 vertical burning tests show that the TPIUs exhibit excellent antidripping effects. The ultimate tensile strengths of the TPIUs reached 23.1−37.6 MPa with increasing hard segment contents, which meets the requirement of mechanical properties with regard to practical use. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 40801.
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高影响因子
JOURNAL OF APPLIED POLYMER SCIENCE
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2014
·Vol. 131
·期 18
·
IF 1.64
Yan Zhou,Jianping Zhang,Xuegang Luo,Xiaoyan Lin
A novel adsorbent for Hg(II), mercapto-functionalized alkali lignin (AL-SH) was synthesized by Friedel–Crafts alkylation reaction and nucleophilic substitution reactions. The adsorbent was characterized by the techniques of Fourier transform-infrared spectroscopy (FT-IR), elementary analysis and thermogravimetric analysis, and N 2 adsorption techniques. The effect of various parameters on Hg(II) adsorption process such as initial pH, contact time, ionic strength, initial Hg(II) concentration, temperature, and adsorbent dosage were investigated in detail through batch static experiments. The results indicated that the adsorption process of Hg(II) on AL-SH was mainly dependent on the pH and the optimal pH value was at pH ranging from 4.0 to 6.0. The adsorption process was found to follow pseudosecond-order kinetics and the main process was chemical adsorption, which equilibrated at 8 h. The adsorption isotherm was better described by Langmuir and Temkin isotherm equations compared to Freundlich isotherm equation and the maximum adsorption capacity obtained was 101.2 mg g −1 (pH = 4.0, 20°C, initial Hg(II) concentration was 200 mg L −1 ). The thermodynamic parameters of and were positive while was negative, revealed that the adsorption of Hg(II) onto AL-SH was a spontaneous and endothermic process with increased entropy. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 40749.
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高影响因子
JOURNAL OF APPLIED POLYMER SCIENCE
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2014
·Vol. 131
·期 17
·
IF 1.64
Fang Ping Wang,Jun Ying Zhang,Hu Po Mu,Wan Xia Li,Ting Yuan,Xin Zhen Du
A pH-sensitive hydrogel [P(CE- co -DMAEMA- co -MEG)] was synthesized by the free-radical crosslinking polymerization of N,N -dimethylaminoethyl methacrylate (DMAEMA), poly(ethylene glycol) methyl ether methacrylate(MPEG-Mac) and methoxyl poly(ethylene glycol)-poly(caprolactone)-methacryloyl methchloride (PCE-Mac). The effects of pH and monomer content on swelling property, swelling and deswelling kinetics of the hydrogels were examined and hydrogel microstructures were investigated by SEM. Sodium salicylate was chosen as a model drug and the controlled-release properties of hydrogels were pilot studied. The results indicated that the swelling ratios of the gels in stimulated gastric fluids (SGF, pH = 1.4) were higher than those in stimulated intestinal fluids (SIF, pH = 7.4), and followed a non-Fickian and a Fickian diffusion mechanism, respectively. In vitro release studies showed that its release rate depends on different swelling of the network as a function of the environmental pH and DMAEMA content. SEM micrographs showed homogenous pore structure of the hydrogel with open pores at pH 1.4. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 40737.
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高影响因子
JOURNAL OF APPLIED POLYMER SCIENCE
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2014
·Vol. 131
·期 17
·
IF 1.64
Chunjiang Zhang,Yongfeng Xia,Kaihui Zuo,Yu-Ping Zeng
Novel composite polyethylene (PE) separators were prepared via thermally induced phase separation using SiO 2 as the inorganic dopant and dioctyl phthalate as solvent. Through the control of silica content, the microstructure, thermal and crystalline properties, electrolyte uptake, thermal stability, and mechanical properties of the as-prepared separators were investigated. The results showed that the doped silica particles favored the formation of the large pore size. The crystalline degree of PE was enhanced when doping silica in the ternary system below 3 wt %. The liquid electrolyte uptake was increased from 30.2% to 63.2% with doping silica content at 5 wt % in the mixed system, which benefits from the large pore size structure and the hydrophilicity of silica. The thermal decomposition temperature of the composite PE separators is 40°C higher than the pure PE separator due to the steric stabilization and the more stable space structure induced by the doped silica. The tensile strength was increased from 12 MPa to 13.3 MPa when doping 1 wt % silica, but decreased with further silica addition. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 40724.
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高影响因子
JOURNAL OF APPLIED POLYMER SCIENCE
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2014
·Vol. 131
·期 17
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IF 1.64
Chun-Hui Du,Xu-Min Ma,Chun-Jin Wu,Mei-Qiang Cai,Li-Guang Wu
A poly(methyl methacrylate) (PMMA)- b -poly[2-( N,N -dimethylamino) ethyl methacrylate] (PDMAEMA) block copolymer was successfully synthesized by a reversible addition–fragmentation chain-transfer method. The resulting copolymer was used to prepare poly(vinylidene fluoride) blend membranes via a phase-inversion technique. The polymorphism, structure, and properties of the blend membranes were investigated by Fourier transform infrared spectrometry, scanning electron microscopy (SEM), ζ potential analysis, and filtration. The results indicate that PMMA- b -PDMAEMA could migrate onto the surface of the membrane during the coagulation process, and more of the β-crystal phase appeared with the increase of the block copolymer in the membranes. The surface morphology and cross section of the membranes were also affected by the copolymer, as shown by SEM. The ζ-potential results show that the surface charges of the membrane could be changed from positive to negative at an isoelectric point as the pH increased. The blend membrane also exhibited good pH sensitivity, and its water flux showed a great dependence on pH. The filtration experiment also indicated that the blend membrane had good hydrophilicity and antifouling properties. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 40685.
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高影响因子
JOURNAL OF APPLIED POLYMER SCIENCE
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2014
·Vol. 131
·期 17
·
IF 1.64
Hongming Yuan,Zaochuan Ge,Shaojun Chen,Shiguo Chen,Haipeng Yang,Haitao Zhuo
This article demonstrates a comparative investigation about the effect of diisocyanate on pyridine containing shape memory polyurethanes (Py-SMPUs), which are synthesized with N , N -bis(2-hydroxylethyl)isonicotinamide (BINA) and four different diisocyanates: 1,6-hexanediisocyante (HDI), isophorone diisocyanate (IPDI), methylene diphenyl diisocyanate (MDI), and tolylene diisocyanate (TDI). Results show that all BINA–SMPU systems have amorphous reversible phase. Comparatively, the MDI–BINA and TDI–BINA systems show higher T g ; and the HDI–BINA and IPDI–BINA systems show better thermal stability. In addition, the HDI–BINA and the IPDI–BINA systems exhibit good thermal-induced shape memory effect and good moisture-sensitive shape memory effect due to their better moisture absorption properties. Particularly, the HDI–BINA system has better response speed and better shape recovery. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 40721.
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高影响因子
JOURNAL OF APPLIED POLYMER SCIENCE
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2014
·Vol. 131
·期 17
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IF 1.64
Jin Luo,Yanhua Wang,Rong Ren,Weilin Sun,Zhiquan Shen
The layer-by-layer self-assembly technique was used to fabricate a series of multilayer thin films with poly[4′-(4-methacryloyphenyl)-2,2′:6′,2″-terpyridine] (PmPhtpy), polycyanofullerenes, and transition metals (Ni 2+ and Co 2+ ). The polymer PmPhtpy was prepared by free-radical polymerization, and this was confirmed by Fourier transform infrared (FTIR) and 1 H-NMR spectroscopy. The polycyanofullerenes, which were characterized by FTIR, ultraviolet–visible (UV–vis), and 13 C-NMR spectroscopy, was synthesized via the bromination of fullerene and then substitution with a nucleophilic reagent [potassium cyanide (KCN)]. The optical properties of the films were measured by attenuated total reflection infrared and UV–vis spectroscopy, and the results indicate that the driving force of the fabrication of the multilayer film was the coordination interaction. The magnetic behavior was examined as a function of the magnetic field strength at 5 K and the temperature (5–300 K). The magnetic hysteresis loops of the films showed a typical S shape at 5 K; this suggested soft ferromagnetic properties. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 40681.
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高影响因子
JOURNAL OF APPLIED POLYMER SCIENCE
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2014
·Vol. 131
·期 17
·
IF 1.64
Yan Song,Lige Wang,Xiuling Wang,Kun Bian,Qingbiao Yang,Yaoxian Li
A new superhydrophobic nanofiber membrane with certain mechanical strength was prepared by electrospinning the polystyrene (PS) with ester modified silicone oil (EMSO). To increase the roughness and tensile strength, the EMSO with low energy as hydrophobic macromolecular substance was added into PS precursor solution. Then during the process of electrospinning, some of the ester modified silicone oil was distribution on the surface of substrate (PS) fiber films to generate double structure which leaded to the superhydrophobicity. We probed into the relationship between the surface wettability, morphologies, mechanical property, and the mass ratios of ester modified silicone oil /PS, and with the increasing of EMSO, the water CA value increased from 135 ± 0.5° to 152 ± 0.2°and the tensile strength grown from 0.23 MPa to 0.92 MPa. The film shows a network structure consisting of numerous randomly oriented fibers, the diameters of which changed from 0.5 μm to 2.0 μm belong to relatively big diameter fibers, which has great significance to the research of superhydrophobic membrane with big diameter fibers and also this method is easy, convenient and environment friendly. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 40718.
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高影响因子
JOURNAL OF APPLIED POLYMER SCIENCE
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2014
·Vol. 131
·期 16
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IF 1.64
Shengguo Lu,Fang Luo,Xujia Duan,Chen Jia,Yuwang Han,He Huang
Hybrid nanoparticles composed of polydiacetylene (PDA) and magnetite (Fe 3 O 4 ) were fabricated by a double-emulsion method. The structure and composite form of the hybrid nanoparticles were investigated with transmission electron microscopy, scanning electron microscopy, Fourier transform infrared spectroscopy, and dynamic light scattering. The successful incorporation of magnetism to an attractive class of colorimetric PDA sensors was demonstrated. Compared with the PDA vesicles, the hybrid nanoparticles showed better colloidal stability with ethanol stimuli. In this study, we explored the colorimetric sensing ability of the hybrid nanoparticles in response to sodium cetyltrimethylammonium bromide (CTAB). The results show a high sensitivity to CTAB with a limit of detection at 30 μM. The biotin–streptavidin interaction was used as a sensing model to test ligand–receptor interactions on the hybrid nanoparticles' response. The concentration dependence of the chromic response was observed with the limit of visual detection at 20 μg/mL. The Fe 3 O 4 –PDA hybrid nanoparticles might have great potential applications in biosensing because of their advantages, including separation and sensing. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 40634.
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高影响因子
JOURNAL OF APPLIED POLYMER SCIENCE
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2014
·Vol. 131
·期 16
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IF 1.64
Xiu Qiang,Fang Chen,Xiao-Yan Ma,Xian-Bing Hou
Star-shaped polyhedral oligomeric silsesquioxane (POSS)–methacrylate hybrid copolymers with phenyl–triazole as terminal groups had been designed and synthesized via sequential atom transfer radical polymerization (ATRP), azidation, and phenylacetylene-terminated procedures, and the hybrid copolymers here could be denoted as POSS–(PXMA-Pytl) 8 , where X can be M, B, L, and S, represented four different methacrylate monomers, such as methacrylate (MMA), butyl methacrylate (BMA), lauryl methacrylate (LMA), and stearyl methacrylate (SMA), respectively. Thermal gravimetric analysis (TGA) and in situ Fourier transform infrared spectroscopy (FTIR) were applied for studying the thermal stability and degradation mechanism, and it was found that all of the POSS–(PXMA-Cl) 8 and POSS–(PXMA-Pytl) 8 copolymers exhibited excellent thermal stabilities, which had great potential in heat-resistant material application. Different tendencies of decomposition temperatures at 5% and 10% weight loss ( T 5 and T 10 ) dependent on the side-chain length and terminal group species were investigated respectively. The longer alkyl side chains of the monomers, the lower thermal stabilities, and enhanced T 5 and T 10 were also shown with the introduction of phenyl–triazole groups instead of chlorine groups. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 40652.
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高影响因子
JOURNAL OF APPLIED POLYMER SCIENCE
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2014
·Vol. 131
·期 16
·
IF 1.64
Shoulian Wei,Yong Liu,Tao Hua,Ling Liu,Hongwu Wang
A novel molecularly imprinted electrochemical sensor was developed for the sensitive and selective determination of ampicillin (AMP). The sensor was prepared on a platinum electrode modified with multiwalled carbon nanotubes (MWCNTs), gold nanoparticles (AuNPs), and a thin film of molecularly imprinted polymers (MIPs). MWCNTs and AuNPs were introduced to enhance the sensor's electronic transmission and sensitivity. The molecularly imprinted polymer (MIP) was synthesized using AMP as the template molecule, methacrylic acid as functional monomer, and ethylene glycol maleic rosinate acrylate (EGMRA) as cross-linker. The performance of the proposed imprinted sensor was investigated using cyclic voltammetry (CV), differential pulse voltammetry (DPV), and electrochemical impedance spectroscopy (EIS). The results showed that the imprinted film displayed a fast and sensitive response to AMP. Under optimal conditions, response peak current had a linear relationship with the concentration of AMP in the range of 1.0 × 10 −8 mol/L to 5.0 × 10 −6 mol/L and a detection limit of 1.0 × 10 −9 mol/L ( S/N = 3). This imprinted sensor was used to detect AMP in food samples with recoveries of 91.4–105%. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 40613.
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高影响因子
JOURNAL OF APPLIED POLYMER SCIENCE
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2013
·Vol. 131
·期 1
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IF 1.395
Lili Yu,Lin Yao,Jing You,Yihui Guo,Liyan Yang
A crosslinked amphiphilic copolymer [poly(ethylene glycol) (PEG)–poly(methyl methacrylate) (PMMA)–ethylene glycol dimethacrylate (EGDM)] composed of PMMA, PEG, and crosslinking units (EGDM) was synthesized by atom transfer radical polymerization to develop micelles as carriers for hydrophobic drugs. By adjusting the molar ratio of methyl methacrylate and EGDM, three block copolymer samples (P0, P1, and P2) were prepared. The measurement of gel permeation chromatography and 1 H-NMR indicated the formation of crosslinked structures for P1 and P2. Fluorescence spectroscopy measurement indicated that PEG–PMMA–EGDM could self-assemble to form micelles, and the critical micelle concentration values of the crosslinked polymer were lower than those of linear ones. The prepared PEG–PMMA–EGDM micelles were used to load doxorubicin (DOX). The drug-loading efficiencies of P1 and P2 were higher than that of P0 because the crosslinking units enhanced the micelles' stability. With increasing drug-loading contents, DOX release from the micelles in vitro was decreased, and in the crosslinked formulations, the release rate was also slower. An in vitro release study indicated that DOX release from the micelles for the linear samples was faster than that for crosslinked micelles. The drug feeding amount increased and resulted in an increase in the drug-loading content, and the loading efficiency decreased. These PEG–PMMA–EGDM micelles did not show toxicity in vitro and could reduce the cytotoxicity of DOX in the micelles; this suggested that they are good candidates as stable drug carriers. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131 , 39623.
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高影响因子
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