JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION
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2025
·Vol. 40
·期 2
·382-388
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IF 1.1
Cao Tian,Li Wei,Ren Lin,Song Tao,Song Jie,Lin Jiacheng,Yang Li,Liu Wenxiu,Wang Ping,Feng Shaojie
The adsorption of phosphate was conducted by the complex of chitosan/polyacrylamide/ferric(CS/PAM/Fe(III)) prepared. The SEM images and XPS spectra confirmed the successful adsorption of phosphate. The adsorption process was studied by varying the influencing aspects like pH, co-existing ions, contact time, and initial phosphate concentration. The experimental results indicate that the adsorptive capacity decreases with the increase of pH. However, it is commendable that there is still a adsorption capacity of more than 5 mg/g when the pH is 8–11. The adsorption kinetics can be accurately described by the pseudo-second-order model and is controlled by both chemisorption and surface diffusion. The adsorption process is a single layer adsorption. This paper proposed that the adsorption mechanism of CS/PAM/Fe(III) complex is the joint action of electrostatic attraction and ligand exchange.
研究领域:
环境科学
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材料科学
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高影响因子
JOURNAL OF MATERIALS SCIENCE
·
2025
·
IF 3.9
Sui Xingyu,Hu Zhengwen,Peng Lin,Shu Yong,Jiang Luming,Zhao Guixiang
With the rapid progress of urbanization and industrialization, water pollution has become an increasingly serious issue, particularly due to dye wastewater, which contains numerous harmful substances and is difficult to treat effectively. Dye wastewater contains many harmful substances and is difficult to treat effectively. Traditional treatment methods are often inefficient and economically unsustainable. In contrast, membrane separation technology offers high separation efficiency and environmental benefits, making it a promising approach for water purification. Therefore, in this paper, the hydrophilic modification of PVDF membranes was carried out by adding ZIF-8 and chitosan(CS), and at the same time, the membranes were endowed with the ability of light self-cleaning. ZIF-8, a metal–organic framework (MOF) material, was synthesized using water as the solvent through the reaction of zinc nitrate with 2-methylimidazole. The PVDF membranes were modified by physical co-mingling, and ZIF-8/CS/PVDF composite membranes with different contents of ZIF-8 and CS were prepared by the submerged precipitation phase transition method. The performance test results demonstrated that the composite membranes doped with ZIF-8 and CS exhibited significant improvements in water contact angle, pure water flux, and dye wastewater treatment performance. Notably, the modified membranes showed exceptional dye removal efficiency and enhanced resistance to membrane fouling. Furthermore, the results of photocatalytic self-cleaning experiments revealed that the modified membranes effectively degraded Congo red and methylene blue dyes under Xenon lamp irradiation, highlighting their excellent photocatalytic self-cleaning capability. These findings suggest that the ZIF-8/CS/PVDF-modified membrane holds great potential for water treatment and self-cleaning applications, achieving up to 93.06% dye rejection and a pure water flux of 95.89 L m −2 h −1 , more than double that of the pristine PVDF membrane.
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INORGANIC CHEMISTRY
·
2025
·
IF 4.7
Yu-Jie Zhang,Lin Cheng,Ze-Yu Wang,Ze-Jia Shen,Fei-Fei Wang,Jun-Zheng Wang,Zi-Xin Qiu,Shuaihua Wang,Kai-Yao Wang,Cheng Wang
A porous layered tin sulfide material, [(CH3)2NH2]2Sn3S7·0.4H2O (SnS-1), is developed for rapid Cs+ and Sr2+ removal from aqueous solutions. The alignment of hexagonal windows (8.3 × 8.3 Å2 in cross-section) across the stacked layers forms straight pseudochannels that enables effective ion diffusion and accommodation. SnS-1 exhibits outstanding ion exchange kinetics (k2Cs = 0.256 g mg–1 min–1; k2Sr = 0.272 g mg–1 min–1) and capacities (qmCs = 417.24 mg g–1; qmSr = 116.18 mg g–1), exceeding most chalcogenide-based exchangers. It exhibits acid–base resistance across a broad pH range (0–11) and remarkable selectivity for Cs+ and Sr2+ over various competing ions. Dynamic column filtration confirms the separation applicability of SnS-1, featuring sustained Sr2+ removal (RSr = 94.45–99.51%) against Cs+ (RCs = −20 ± 5%). The SnS-1/PTFE composite membrane can efficiently remove Cs+ and Sr2+ from continuous flow (2.0 mL min–1 cm–2), with removal efficiencies exceeding 91.71 and 98.91%, respectively. Moreover, the adsorbed Cs+ and Sr2+ ions can be readily eluted from the spent column and membrane using a 2 M NaCl solution. Combined with simple synthesis, radiolytic stability, and superior performance, microporous SnS-1 emerges as a promising candidate for nuclear wastewater remediation.
研究领域:
材料科学
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环境科学
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化学工程
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DOI
PubMed
高影响因子
Journal of Environmental Chemical Engineering
·
2024
·
IF 7.4
Kang Li,Chenxi Li,Yisa Liu,Jiong Dong,Lili Xu,Yanran Li,Ruixin Ma,Shina Li
The widespread application of nuclear energy has increased the risk of contamination by radionuclide 137 Cs. Prussian blue analogues are considered to be excellent materials for the removal of 137 Cs from wastewater due to their unique structure. In this work, Cs + adsorbent for PBAs with Fe-Co framework, potassium iron hexacyanocobaltate (PBA Fe ), was synthesized by room temperature precipitation method. Systematic structural characterization and performance results of PBA Fe showed that it has a specific surface area of 452.8 m 2 /g and an average pore size of 8.6 nm, providing more active sites for Cs + . The adsorption of Cs + on PBA Fe exhibited fast reaction kinetics (within 10 min) and high adsorption capacity (82.90 mg/g), and the removal rate of Cs + reached 98.57 %. The efficient removal of Cs + by PBA Fe in various real water environments showed its excellent selectivity and potential for practical application. In addition, adsorption mechanism studies showed that the adsorption of Cs + was achieved by ion exchange with K + in the PBA Fe lattice. PBA Fe has the advantages of simple synthesis and good selectivity, and has potential application in the harmless treatment of Cs + in radioactive wastewater.
研究领域:
环境科学
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材料科学
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高影响因子
Inorganic Chemistry Frontiers
·
2020
·Vol. 8
·期 6
·1468-1475
·
IF 5.958
Ying Hou,Bingbing Zhang,Hongping Wu,Hongwei Yu,Zhanggui Hu,Jiyang Wang,Yicheng Wu
Borophosphates are of current interest and great importance as ultraviolet (UV) and deep-UV optical functional materials. However, most of the borophosphates exclusively contain tetrahedral coordination of B and P atoms, i.e. BO4 and PO4. Few compounds contain mixed-coordinated groups, i.e. BO4, BO3 and PO4. A new strategy of large B/P ratios has been suggested to effectively synthesize three mixed-coordinated borophosphates, K3B4PO10 and K2MB4PO10 (M = Rb/Cs). Their structures all show 2D 2∞[B4PO10]3− sheets, which are separated by the alkali metal cations. The thermal behavior measurements indicate that K3B4PO10 and K2MB4PO10 (M = Rb/Cs) melt congruently and a crystal of K3B4PO10 with a size up to 4 × 2 × 1 mm3 has been grown. Property measurements show that they all possess deep-ultraviolet (UV) cut-off edges and a relatively large birefringence and are potential deep-UV birefringent crystals. In particular, the measured birefringence of K3B4PO10 is about 0.0445@532 nm, which is the largest in borophosphates with reported birefringence. This study indicates that B-rich borophosphates are promising systems to synthesize materials with large birefringence.
研究领域:
材料科学
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光学
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晶体学
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高影响因子
JOURNAL OF ALLOYS AND COMPOUNDS
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2020
·
IF 4.65
Xue Wang,Hanping Zhang,Quanguo Zhai,Yucheng Jiang,Mancheng Hu,Shuni Li
In this work, the high-quality protonated Ni-doped MnO 2 (H–Ni–MnO 2 NRs) nanorods with a mean diameter of about 15 nm were synthesized by a hydrothermal method , which was successfully applied to Cs + adsorption under electrochemical process. The as-prepared H–Ni–MnO 2 NRs showed high selectivity to Cs + adsorption in both acidic and neutral media. In particular, the amount of Cs + adsorption increased with increasing solution pH. The adsorption capacity of H–Ni–MnO 2 NRs for Cs + could reach up to 11.5 mmol·g −1 at pH 7, much higher than previous reports (0.06–6 mmol·g −1 ). The high adsorption of H–Ni–MnO 2 NRs ability could be attributed to their especial morphology, Ni doping, and Mn(III) amount enhancement induced by electrochemical reduction .
研究领域:
材料科学
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环境科学
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高影响因子
CATALYSIS TODAY
·
2020
·
IF 5.825
Hongqin Ma,Yanan Guan,Wenyao Chen,Zhijun Sui,Gang Qian,De Chen,Xinggui Zhou,Xuezhi Duan
In this work, the support effects on vapor-phase aldol condensation of methyl acetate (MeOAc) with formaldehyde (HCHO) over cesium catalysts are understood by the employment of Al 2 O 3 with different morphologies and crystal phases. The structural and electronic properties of these supported Cs catalysts are characterized by multiple techniques, such as XRD, HAADF-STEM, EDS-mapping, XPS, NH 3 -TPD and CO 2 -TPD. The Cs species are found to be highly dispersed on the Al 2 O 3 surfaces, and their compositions vary with the identity of Al 2 O 3 . A combined catalyst characterization and testing results indicates a balance between acidic and basic sites, i.e., an acid-base synergy, for the production of MA: the excess acidic sites lead to the lower MA selectivity due to the promoted further condensation, while the excess basic sites with the lower MeOAc conversion due to the insufficient activated HCHO species. These insights could be valuable for the design and optimization of catalysts for this reaction.
研究领域:
催化化学
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材料科学
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高影响因子
Soft Matter
·
2019
·Vol. 15
·期 38
·7686-7694
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IF 3.399
Mengmeng Shu,Shijun Long,Yiwan Huang,Dapeng Li,Haiyan Li,Xuefeng Li
We report a simple and facile self-assembly approach to fabricate polyelectrolyte complex (PEC) hydrogel films with positively charged chitosan (CS) and negatively charged heparin sodium (HS) by combining hydrogen bonding and electrostatic interactions. The CS/HS hydrogel films exhibited excellent tensile strength and toughness, good self-recovery ability, superior water absorbency, and pH-dependent surface charge characteristics. The gelation mechanism was investigated by zeta potential measurements. The CS/HS hydrogel films exhibited high antibacterial efficacy against E. coli at selected pHs or when coordinated with various metal ions and a significant effect on accelerating wound healing. The self-assembly approach presented in this work may serve as a generic strategy for the fabrication of novel multi-functional PEC hydrogels for broad biomedical applications.
研究领域:
材料科学
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生物医学工程
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药学
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DOI
PubMed
高影响因子
Materials Research Express
·
2022
·Vol. 9
·期 12
·125002
·
IF 2.025
Bochen Yang,Jing Wang,Le Kang,Xiaoping Gao,Ke Zhao
Since the outbreak of the COVID-19 epidemic, a large number of disposable protective masks have been manufactured and used, and the abandonment of masks has caused enormous pollution. In this paper the chitosan (CS), polyvinyl alcohol (PVA), and water were used as raw materials and the nanofiber membranes were prepared by electrostatic spinning. The CS/PVA fiber membranes were crosslinked by glutaraldehyde hydrochloric acid vapour. The fiber morphology, hydrolysis resistance, antibacterial properties, chemical structure, thermal stability and filtration performance of nanofiber membranes were characterized. Results shows that the antibacterial performance of the crosslinked composite nanofibers exceeds 97%, the thermal stability is improved, and the fiber morphology is not destroyed. The hybridized fiber membrane has high filtration performance, excellent antibacterial and hydrolysis resistance, which broadening the PVA fiber membrane application. It is expected to replace traditional protective materials and relieve environmental pressure.
研究领域:
材料科学
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环境科学
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生物学
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高影响因子
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
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2015
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IF 2.587
Jie Sun,Shaolong Wan,Fen Wang,Jingdong Lin,Yong Wang
A variety of catalysts for higher alcohol synthesis from syngas have been under development for potential commercial application, which are still facing challenges, including poor carbon efficiency due to low selectivity to desired products. In this contribution, we systematically studied the effects of temperature, loading of K and Cs, space velocity, and CO2 addition on the alkali-promoted Cu/ZnO/Al2O3 catalysts in order to achieve a high yield of desired higher alcohol products. Our particular focus was to maximize the carbon efficiency by restricting the amount of undesired byproducts, such as lower alkanes and CO2 that could be formed. Among K and Cs promoted Cu/ZnO/Al2O3 catalysts studied, Cs-promoted Cu/ZnO/Al2O3 catalysts exhibit better performance to higher alcohols and higher carbon efficiency than K-promoted counterparts under similar conditions studied. 1.64 mol % Cs-promoted Cu/ZnO/Al2O3 catalyst achieves the highest selectivity to higher alcohols (24.9%) at a CO conversion of 41.6% under 290 °C, 1875 mL g–1cat h–1, 5.4 MPa. The presence of a small amount of CO2 of 2.5 mol % in the feed has negligible effect on the productivity of higher alcohols but significantly suppresses the formation of CO2 byproduct. With the further increase of CO2 in the feed, the formation of CO2 can be further suppressed but at the expense of productivity loss of higher alcohols, which is probably due to the neutralization of surface Cs sites. The best carbon efficiency can be achieved at 8% mol CO2 in the feed.
研究领域:
化学工程
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催化科学
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高影响因子
Journal of Physical Chemistry C
·
2021
·
IF 4.126
Xiaomei Chen,Mu He,Sheng Huang,Lei Zhang,Haizheng Zhong
Here, we fabricated Cs-rich and Pb-rich Cs4PbBr6 samples with green photoluminescence emission and investigated the difference between them. Both Cs-rich and Pb-rich Cs4PbBr6 samples show strong green emissions at about 520 nm; however, the photoluminescence excitation properties of the green emission are greatly different from each other in the ultraviolet region. The photoluminescence excitation spectra of the Cs-rich sample have a broad excitation band from 334 to 500 nm. In comparison, the Pb-rich sample has two additional excitation bands of 250–300 and 324–334 nm. By correlating the experimental data with the theoretical calculations, the green photoluminescence emission can be attributed to the embedded CsPbBr3 nanocrystals, and the interlayer between Cs4PbBr6 and CsPbBr3 nanocrystals plays an important role in determining their photoluminescence excitation properties. It was proposed that the existence of the CsBr interlayer between the Cs4PbBr6 matrix and embedded CsPbBr3 nanocrystals block the electron transfer of excited Cs4PbBr6 and induce photoluminesence quenching under excitation of 250–300 nm.
研究领域:
材料科学
·
光学
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高影响因子
FIBERS AND POLYMERS
·
2023
·Vol. 24
·期 9
·3075-3084
·
IF 2.5
Ahmed Adnan,Zhang Meng,Li Siqi,Xu Lan
Chitosan (CS), as a biocompatible and biodegradable nature polymer, has excellent antibacterial property. Poly(ethylene oxide) (PEO), as a biomaterial with thermal stability, biocompatibility and biodegradability, has good spinnability. Anthocyanin, as a natural colorant agent with different molecular structures under different pH values, has good antibacterial and antioxidant properties and can be applied as a pH indicator. Electrospun nanofiber membranes (NFMs) show great application prospects in food packaging due to their unique structural and functional advantages. In this work, anthocyanin/CS/PEO nanofiber membranes (NFMs) for food packaging were batch prepared by the spherical section free surface electrospinning (SSFSE), and their yield reached 5.8 ± 0.4 g/h. The morphology, structure and properties of CS-based NFMs were explored, which showed that they were hydrophilic and had excellent antibacterial activity against Escherichia coli ( E. coli ) and Staphylococcus aureus ( S. aureus ). Among them, anthocyanin/CS/PEO NFMs exhibited better mechanical properties and high antioxidant activity. Furthermore, the color changes of anthocyanin/CS/PEO NFMs at different pH values were investigated, illustrating that they could be used as a visual monitoring food packaging, and their application effects in beef storage were studied.
研究领域:
材料科学
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食品科学
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生物医学
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高影响因子
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