ELECTROCHIMICA ACTA
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2020
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IF 6.215
Shifu Wang,Zuoyi Xiao,Shangru Zhai,Guoxiang Wang,Wensha Niu,Longfei Qin,Zhongcheng Li,Qingda An
Efficient pseudocapacitive energy storage devices have attracted considerable attention due to the growing demand of electrical power supply. Still, the design and fabrication of electrode materials with high power and energy densities is challengeable. Herein, an in-situ reduction and competitive cross-linking strategy is presented to construct a novel Sn–Mo bimetallic oxide nanoparticle-grown on P-doped hierarchical porous carbon (SnMo–O@P-HPC). The attractive electrochemical performance of SnMo–O@P-HPC composite with an ultrahigh specific capacitance of 2121.3 F g −1 and excellent cycle stability of 92.5% over 5000 cycles is resulted from unique active component, abundant active sites, and well-organized 3D porous structure. An asymmetric supercapacitor composed of activated carbon and SnMo–O@P-HPC displays an amazing specific energy density of 114.9 W h kg −1 at 515.5 and 98.8 W h kg −1 even at 20,900 W kg −1 . Importantly, it also displays a wonderful stability with excellent capacitance retention of 92.5% after 5000 cycles. The work will provide an effective and novel method to obtain the promising electrode materials for supercapacitors .
研究领域:
材料科学
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电化学
✓ 已验证
产品关联
DOI
高影响因子
APPLIED CATALYSIS A-GENERAL
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2019
·
IF 4.63
Zhiguo Zhu,Haikuo Ma,Mingtong Li,Ting Su,Hongying Lü
Sn-containing Beta (Sn-Beta) zeolite is extensively applied in industrially-relevant reactions as a highly active and robust Lewis acid heterogeneous catalyst. Nonetheless, environmentally-unfriendly fluoride is generally required to the directly hydrothermal synthesis of Sn-Beta. In this work, an innovative strategy of interzeolite transformation with steam-assisted conversion is provided to directly synthesize Sn-Beta zeolite in the absence of fluoride. Silica source of FAU and steam-assisted conversion were two necessary factors for the successful synthesis of Sn-Beta zeolite. It was found that highly crystallized Sn-Beta zeolite with isolated framework Sn ions was hydrothermally synthesized via degradation of siliceous FAU zeolite and recrystallization of degraded silicate species. As far as we know, the crystal of Sn-Beta in this work was minimum in size among all present directly hydrothermal synthesized ones. More importantly, the Sn contents in Sn-Beta could achieve to 2.39 wt % (Si/Sn = 81), breaking through the Sn content restriction of conventional fluoride-mediated method. In addition, the hydrophobicity of this resultant Sn-Beta zeolite was slightly inferior to Sn-Beta-F obtained via traditional fluoride-assisted route. Whereas the smaller crystal size of this Sn-Beta gave rise to relatively good diffusion performance for organics, which made it reveal high activities in the Baeyer-Villiger oxidant of ketones in particular employing bulky tert -butyl hydroperoxide as the oxidant. The current strategy provides an alternative and environmentally-friendly method for the hydrothermal synthesis of Sn-Beta without the assistance of fluoride and alkali metal ions, which can guide further development in metallosilicates crystal engineering in terms of greenization.
研究领域:
材料科学
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催化
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环境化学
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无机化学
✓ 已验证
产品关联
DOI
高影响因子
BIOMASS & BIOENERGY
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2022
·
IF 5.774
Jiawen Hao,Wei Mao,Guirong Ye,Yi Xia,Cui Wei,Ling Zeng,Jinghong Zhou
5-hydroxymethylfurfural (HMF) is considered a promising platform chemical, from which numerous chemicals can be produced. Hence, developing an efficient catalytic system to convert glucose into HMF has drawn considerable attention. In this study, a series of Lewis acidic Sn–Cr bimetallic metal–organic frameworks, MIL-101(Cr, Sn), with different Sn ion loading were synthesized hydrothermally using acetic acid as the mineralizer and water as the solvent. The resulting MIL-101(Cr, Sn) was systematically analyzed as a catalyst for the conversion of sugar to HMF. Moreover, the effects exerted by various reaction parameters on HMF yield and selectivity were investigated. With glucose as the substrate and 0.5-wt% H 2 SO 4 as a catalyst, an 85.75% glucose conversion with 22.64% HMF yield and 26.41% selectivity was achieved. Meanwhile, these parameters were improved via addition of MIL-101(Cr, Sn)-0.1. That is, glucose conversion, HMF yield, and selectivity were increased to 86.36%, 60.75%, and 70.35%, respectively, when using MIL-101(Cr, Sn)-0.1 and H 2 SO 4 as the catalyst under the same reaction conditions. The MIL-101(Cr, Sn) structure enabled high stability of the catalyst in aqueous solutions with different pH values, while improving its thermal stability. Moreover, the catalyst could be reused several times despite a slight reduction in its catalytic activity . The current results illustrate that MIL-101(Cr, Sn) is an excellent acid and sustainable catalyst for the production of HMF from fructose, glucose, and starch .
研究领域:
化学工程
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催化
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材料科学
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生物化学
✓ 已验证
产品关联
DOI
高影响因子
Drug Delivery and Translational Research
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2024
·
IF 5.7
Hou Xuyang,Wei Zuxing,Qi Xiaoyan,Liu Dekun,Sun Yin,Jiang Yuhong,Liu Chao,Zhou Weihan,Yang Leping,Liu Kuijie
SN-38 is the active metabolite of irinotecan and acts as an effective topoisomerase I inhibitor with therapeutic effects on many malignant tumors, including some drug-resistant cancers. However, the poor solubility, low bioavailability, and severe dose-dependent toxicity limits the clinical application of SN-38. Currently, emerging macrophage membrane-coated nanoparticles provide an efficient biomimetic approach to develop novel SN-38 formulations for the reduction of its side effects. Photothermal therapy (PTT) is a promising methods in tumor treatment to thermally ablate tumors using various materials such Prussian blue nanoparticles (NPs) and can combined with chemotherapy to synergistically work. There is no report that combined SN38 and photothermal therapy for the treatment of colorectal cancer (CRC). SN38-PB@CM NPs were constructed by loading SN-38 into macrophage cell membrane-coated hollow mesoporous Prussian blue (PB) NPs. The morphology, size and zeta potential were evaluated by transmission microscopy and dynamic light scatter (DLS). Coomassie bright blue staining was performed to assess total protein profile. The photothermal properties of it were also investigated via near-infrared imaging. CCK8 and calcein-AM/PI staining were used to evaluate cell viability. Flow cytometry was performed to assess cell apoptosis. The fluorescent microscopy was used to observe cellular uptake of SN38-PB@CM NPs to assess its internalization in vitro. The biodistribution, tumor-targeting efficacy, antitumor efficacy and safety of SN38-PB@CM NPs in vivo were assessed in CT26 tumor-bearing mice via In Vivo Imaging System. SN38-PB@CM NPs were successfully constructed and exhibited a uniform size distribution (140.5 ± 4.3 nm) and an excellent drug-loading capacity (5.61 ± 0.64%). SN38-PB@CM NPs showed stable release properties within 72 h. It can also enhance the selective intracellular delivery of SN38 in vitro and showed good near-infrared (NIR) photothermal properties. And the NPs showed excellent tumor targeting, effective photothermal therapy, improved biosafety and antitumor efficacy on CT26-bearing mice. Multifunctional SN38-PB@CM NPs could achieve improved biosafety, great tumor-targeting, high-efficiency PTT and excellent antitumor efficacy, which provided a promising and attractive combination therapy for the treatment of CRC. Graphic Abstract
研究领域:
纳米医学
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癌症研究
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药学
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生物医学工程
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材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
CHEMOSPHERE
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2023
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IF 8.8
Anqi Li,Xuening Bai,Yuting Xie,Pengyang Xia,Hebin Bao,Miao He,Xuzhong Zeng,Wenjing Yang,Xueming Li
To overcome the limitations imposed by Sn–Sb electrodes, the titanium foam (PMT)-TiO 2 -NTs@NiO–C/Sn–Sb composite electrodes with cubic crystal structure are synthesized by introducing NiO@C nanosheet arrays interlayer on the TiO 2 -NTs/PMT matrix through hydrothermal and carbonization process. Then a two-step pulsed electrodeposition method is used to prepare the Sn–Sb coating. Benefiting from the advantages of stacked 2D layer-sheet structure, the obtained electrodes exhibit enhanced stability and conductivity. Synergy of inner and outer layers fabricated by different pulse times strongly influence the electrochemical catalytic properties of the PMT-TiO 2 -NTs@NiO–C/Sn–Sb (Sn–Sb) electrode. Hence, the Sn–Sb (b0.5 h + w1 h) electrode is the optimal electrode to degrade the Crystalline Violet (CV). Next, the effect of the four experimental parameters (initial CV concentration, current density, pH value and supporting electrolyte concentration) on the degradation of CV by the electrode are investigated. The degradation of the CV is more sensitive to alkaline pH, and the rapid decolorization of CV when the pH is 10. Moreover, the possible electrocatalytic degradation pathway of CV is performed using HPLC-MS. Results from the tests show that the PMT-TiO 2 -NTs/NiO@C/Sn–Sb (b0.5 h + w1 h) electrode is an interesting alternative material in industrial wastewater applications.
研究领域:
环境科学
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材料科学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
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2018
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IF 4.229
Zhaomin Wang,Lu Yu,Limin Chang,Limin Wang,Yong Cheng
Owing to its high capacity of 994 mAh g −1 , low cost, and environmental friendliness , tin (Sn) is considered as an advanced anode material for high-capacity lithium-ion batteries (LIBs). Here, a facile strategy to fabricate core-shell structured Sn@NC composites with one-step and large-scale production is introduced in a liquid-phase reaction under room temperature . When used as anode materials for LIBs, the optimal Sn@NC composite delivers a high reversible discharge capacity of 761.2 and 476 mAh g −1 at a current density of 200 and 1000 mA g −1 after 200 cycles, respectively. A high capacity of 328.3 mAh g −1 can also be obtained even at a current density of 2000 mA g −1 . The excellent cycling stability and rate performance of the composite can be ascribed to the synergistic effect of the nanometer size of Sn powder and porous structure of the carbon shell, both of which can effectively reduce the absolute volume change of electrode during the repeated charge-discharge cycles, and thus lead to excellent electrochemical performances at both rate capability and cycling life.
研究领域:
材料科学
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电化学
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能源存储
✓ 已验证
产品关联
DOI
高影响因子
APPLIED SURFACE SCIENCE
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2020
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IF 6.182
Lu Yue,Maleraju Jayapal,Xinli Cheng,Tingting Zhang,Junfeng Chen,Xiaoyan Ma,Xin Dai,Haiqin Lu,Rongfeng Guan,WenHui Zhang
High theoretical capacity and low discharge platforms of Sn and Sb-based materials are an auspicious anode material for sodium ion batteries. Although, their large volume change before and after sodium insertion during cycling leads to unstable electrode structure and poor cycle performance. In view of the above, a thermo chemical strategy by a simple one-pot for producing 3–6 nm diameter homogeneously dispersed Sn/SnSb nanoparticles on a nitrogen-doped graphene sheet with a large-scale and low-cost feature for high performance sodium ion battery is reported. Highly dispersed nano Sn-SnSb alloy/graphene composite electrode not only had good stress adaptability and good integrity protection to prevent agglomeration and polarization during cycling, and also provided the rapid Na + diffusion and electronic transfer channels, thus showing high rate and ultra-stable cycle performance. The as-prepared electrode could maintain the super stable reversible capacities of 251.8, 146.2 and 60.2 mAh g −1 at 1, 4 and 10 A g −1 over 1000 cycles, respectively.
研究领域:
材料科学
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能量存储
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纳米技术
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF HAZARDOUS MATERIALS
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2023
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IF 13.6
Ruixia Li,Minghui Shang,Taotao Zhe,Mingyan Li,Feier Bai,Zhihao Xu,Tong Bu,Fan Li,Li Wang
Developing electrode materials with excellent electrocatalytic properties for detecting pesticide residues plays a vital role in the safety of agricultural products and environmental applications. Herein, we designed a new electrochemical sensor on the basis of N-doped carbon hollow nanospheres modified with Sn/MoC Schottky junction (Sn/MoC@NC) for methyl parathion (MP) detection. The Sn/MoC@NC was prepared by self-assembled polymerization-anchoring strategy and high-temperature carbonization design. Sn/MoC Schottky junction and hollow nanosphere structure endow Sn/MoC@NC with a larger surface area, more active sites, and faster electron transfer , which is beneficial to enhancing its electrocatalytic performance. The structural characterizations and physicochemical properties of Sn/MoC@NC were explored through various microscopy, spectroscopic and electrochemical techniques. The experimental results confirmed that the calibration curve for current and MP concentration (0.05–10 μg/mL) was available under optimized conditions, and the sensitivity and detection limit were respectively determined to be 9.02 μA μM 1 cm 2 and 8.9 ng/mL. Furthermore, the constructed sensor displayed excellent selectivity , repeatability, and stability, which qualified it for use in detecting MP in grapes and tap water with satisfactory recovery. This work may provide some interesting prospects for constructing high-performance electrocatalysts for MP detection.
研究领域:
电化学
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材料科学
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环境科学
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分析化学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
NEW JOURNAL OF CHEMISTRY
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2022
·Vol. 46
·期 18
·8739-8751
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IF 3.925
Quansheng Wu,Songhua Zhou,Chengbing Fu,Jiesong Zhang,Bo Chen,Hongyan Pan,Qian Lin
For the mono-metal Pd based catalysts, the O–O bond in O2 and H2O2 is easily dissociated due to the higher energy sites of Pd, which decreases the selectivity and productivity of H2O2. To address this issue, non-noble metals M (M = Sn, Fe, Co, Ni) were doped into palladium precursors to create a series of yolk–shell structure bimetallic catalysts Pd–M@HCS (H = hollow; C = carbon; S = sphere) with Pd–M as the core and porous carbon as the shell. The results indicated that the catalyst Pd–M@HCS doped with Sn, Fe, Co, and Ni has a weak dissociation ability for O2, and both the adsorption and dissociation ability for H2 are improved. Of these catalysts, the catalyst Pd–Sn@HCS gives the best performance, which is benefited by the suitable Pd–Sn nanoparticle size and the best Pd2+/Pd0 ratio. The influence of the nPd/nSn ratio in the Pd–Sn@HCS system on catalyst performance was further explored, and the findings revealed that Pd–Sn@HCS had the best catalytic activity and stability when the nPd/nSn ratio was 2. The catalyst's H2 conversion, H2O2 selectivity, and productivity were 35%, 97%, and 3961 mmol gPd−1 h−1, respectively. After 10 cycles, the H2O2 productivity of this catalyst remained at 92.1%, which was greater than the H2O2 productivity of the typical Pd-based catalyst Pd/C, which stayed at 37% under the same conditions.
研究领域:
催化
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化学工程
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材料科学
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无机化学
✓ 已验证
产品关联
DOI
高影响因子
APPLIED SURFACE SCIENCE
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2025
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IF 6.9
Zhaoxiang Qi,Yan Zhang,Junzi Huang,Wenjun Zhang,Ying Wang,Ying Qi,Shu Yin,Hongyu Mi,Yahong Xie
The integration of environmental remediation with green hydrogen production bifunctional water electrolysis in hypersaline industrial effluents requires catalysts that simultaneously address efficiency-stability trade-offs. This study presents a self-supported P-SnCoFe-LDH/NF architecture engineered through dual-ion co-doping, demonstrating unprecedented performance in chloride-rich alkaline oilfield wastewater. The optimised catalyst achieves overpotentials of 253 mV for oxygen evolution reaction (OER) and 187 mV for hydrogen evolution reaction (HER) at 10 mA cm −2 with 12-h stability, representing a 4 and 41 % performance retention improvement over conventional CoFe-LDH in aggressive media. Mechanistic studies reveal dual electronic modulation: Sn-doping induces d-band center downshifting while P-incorporation generates electron-deficient metal centers. This synergy establishes optimal adsorption–desorption equilibrium, evidenced by 21 % reduced OER charge transfer resistance and 56 % enhanced HER Volmer kinetics. The symmetric electrolyser (P-SnCoFe-LDH/NF||P-SnCoFe-LDH/NF) maintains <2 % voltage decay during continuous operation. This work presents a new paradigm for multifunctional electrocatalysis in complex aqueous matrices.
研究领域:
环境科学
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电化学
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材料科学
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能源技术
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催化
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水处理
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纳米技术
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF THE ENERGY INSTITUTE
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2024
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IF 5.6
Haonan Shi,Sihao Shu,Zhongze Wang,Xing Zhang,Xiaoyu Gu,Jixiang Chen
Deoxygenation of fatty acid esters in aqueous phase using in-situ generated H 2 has emerged as a promising approach to producing sustainable diesel-like hydrocarbons. In this study, we employed a solvothermal method to synthesize novel Ni–Sn metal–organic frameworks (MOFs) with a homogeneous distribution of Ni and Sn elements. Subsequently, various Ni–Sn intermetallic compounds (IMCs) encapsulated with a porous carbon layer (<3 nm) (Ni–Sn IMC@C) were prepared through the facile pyrolysis of metal–organic frameworks under a controlled N 2 atmosphere. Applying methyl palmitate as model reactant and methanol as hydrogen donor, Ni 3 Sn 2 IMC@C gives approximately 100% conversion and 93% yield towards n-C 15 and n-C 16 alkanes at 330 °C, without significant deactivation during the recycling for five times. The deoxygenation pathway is dominated by decarbonylation (DeCO) on Ni–Sn IMCs. In Ni–Sn IMCs, the oxophilic nature of Sn, along with its charge transfer with Ni, enhances the adsorption of an η 2 (C, O)-aldehyde configuration. The strategic isolation of adjacent Ni by Sn effectively inhibits methanation and C–C bond hydrolysis, reducing H 2 consumption and increasing carbon yield. Moreover, the ultrathin porous carbon encapsulation not only prevents the loss and sintering of Ni 3 Sn 2 IMC under harsh hydrothermal condition but also mitigates mass transfer limitation. Surface oxidation of Ni 3 Sn 2 IMC, particularly the formation of SnO 2 , is detrimental to deoxygenation. Additionally, Ni 3 Sn 2 IMC@C exhibits high hydrocarbon yields (>89.6%) in in-situ aqueous phase deoxygenation of methyl laurate, methyl stearate and methyl oleate. These findings highlight the remarkable potential of MOF-derived catalysts for hydrothermal deoxygenation.
研究领域:
材料科学
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催化
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化学工程
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可持续能源
✓ 已验证
产品关联
DOI
高影响因子
InfoMat
·
2024
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IF 22.7
Huan Li,Yu Gao,Xin Hong,Kanghui Ke,Zilong Ye,Siwei Zhang,Kefei Shi,Zhuo Peng,Hao Yan,Man-Chung Tang,Youwei Yao,Ben Zhong Tang,Guodan Wei,Feiyu Kang
Broadband photodetectors (PDs) capable of multi-wavelength detection have garnered significant interest for applications in environmental monitoring, optical communication, spectral analysis, and imaging sensing. Low-bandgap Pb–Sn hybrid perovskite photodetectors can extend the spectral response from the ultraviolet–visible (UV–vis) range to the near-infrared (NIR) and reduce the toxicity associated with Pb 2+ . The strategic introduction of Sn 2+ into Cs 0.15 FA 0.85 Pb x Sn 1− x I 3 ( x = 1, 0.8, 0.6, 0.5, 0.4, 0.2, and 0) not only preserves the cubic crystal structure with conformal multigrain growth but also broadens the film's absorption spectrum from 800 to 1000 nm NIR region. This indicates a well-controlled tunability of the Pb–Sn binary perovskite system. Specifically, the self-powered photodetector with a device structure of ITO/NiO x /PTAA/Cs 0.15 FA 0.85 Pb 0.5 Sn 0.5 I 3 /PCBM/BCP/Ag has shown remarkable optoelectrical properties. It exhibits a high external quantum efficiency (EQE) of up to 80% across the spectrum from 300 to 1000 nm, a responsivity ( R ) exceeding 0.5 A/W, and high detectivity ( D *) value of 1.04 × 10 12 Jones at 910 nm and 3.38 × 10 11 Jones at 1000 nm after weak attenuation. Intriguingly, the dark current of the Cs 0.15 FA 0.85 Pb 0.5 Sn 0.5 I 3 device is four orders of magnitude lower than that of devices made with pristine Pb or Sn only, strongly correlating with its significantly increased built-in potential and reduced trap density. Consequently, it demonstrates a −3 dB bandwidth of 2.23 × 10 4 Hz, fast rise and decay times of 61 and 30 μs, respectively, and a linear dynamic range (LDR) of 155 dB. Benefiting from its high sensitivity, a 5 × 5 PD array for NIR imaging and non-invasive pulse detection for photoplethysmography applications has been successfully demonstrated, showcasing the prosperous potential of Pb–Sn hybrid perovskite in the NIR range.
研究领域:
材料科学
·
光电子学
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成像技术
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传感器与执行器
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）