MOLECULES
·
2021
·Vol. 26
·期 6
·1721
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IF 4.412
Yaru Wu,Zhucheng Yin,Xuejiao Qie,Yao Chen,Maomao Zeng,Zhaojun Wang,Fang Qin,Jie Chen,Zhiyong He
The interaction of soy protein isolate (SPI) and its hydrolysates (SPIHs) with cyanidin-3-O-glucoside (C3G) at pH 7.0 were investigated to clarify the changes in the antioxidant capacity of their complexes. The results of intrinsic fluorescence revealed that C3G binds to SPI/SPIHs mainly through hydrophobic interaction, and the binding affinity of SPI was stronger than that of SPIHs. Circular dichroism and Fourier-transform infrared spectroscopy analyses revealed that the interaction with C3G did not significantly change the secondary structures of SPI/SPIHs, while the surface hydrophobicity and average particle size of proteins decreased. Furthermore, the SPI/SPIHs-C3G interaction induced an antagonistic effect on the antioxidant capacity (ABTS and DPPH) of the complex system, with the masking effect on the ABTS scavenging capacity of the SPIHs-C3G complexes being lower than that of the SPI-C3G complexes. This study contributes to the design and development of functional beverages that are rich in hydrolysates and anthocyanins.Keywords:soy protein isolate;hydrolysate;cyanidin-3-O-glucoside;noncovalent interaction;antioxidant capacity
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POLYMER DEGRADATION AND STABILITY
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2020
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IF 4.032
Hongyan Li,Xianglin Hou,Lin Chai,Xiaojing Cui,Yingxiong Wang,Tiansheng Deng
The degradation and recovery of waste rigid polyurethane foam (RPUF) have confronted enormous challenge because of its three-dimensional network. An efficient strategy was developed for chemical recycling of high value-added aromatic polyamines and polyether polyols via selective cleavage of carbamate and urea bonds from RPUF and characterized by Nuclear Magnetic Resonance (NMR) and Fourier Transform Infrared Ray (FT-IR). The carbamate and urea bonds were readily cleaved using (NH 2 ) 2 CO/CH 3 CH 2 OH as degradation system at 180 °C for 10 h. Nevertheless, the C–C bonds and C–O–C of ether linkages as framework structure remained intact in the degradation process. Eventually, the high value-added products including aromatic polyamines and polyether polyols were retrieved. A feasible mechanism for degradation was proposed based on the NMR observations.
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HIGH PERFORMANCE POLYMERS
·
2019
·
IF 1.584
Yinhong Liu,Yuhan Wei,Yongshuang Bian,Shengjiao He,Xin Wang,Xin Liu,Chenglei Li,Qi Wu,Xianyin Zeng,Hanguang Wang,Kuan Liu
Design and synthesis of highly selective fluorine ion probes become particularly important owing to the specific role of fluorine ion in chemical and biomedical progresses. As a new-type of fluorescent material, conjugated polymers with unique photometric properties have been widely researched by scientists in the field of the fluorescence sensors. In this study, the polymer PBTPV-OSi containing benzothiazole moiety is synthesized via palladium-catalyzed Heck coupling reaction. This polymer not only exhibits good solubility in organic solvents but also shows high selectivity for fluorine ion detection in comparison to other anions. Upon addition of F− to PBTPV-OSi solution, Si–O cleavage of PBTPV-OSi leads to the fluorescence quenching of the polymer in tetrahydrofuran dramatically, and the detection limit is 8 × 10−6 mol/L. Moreover, besides detecting fluorine ion from organic phase, the probe can also effectively detect potassium fluoride from inorganic phase. More importantly, a naked-eye detectable chromogenic and fluorogenic dual response to fluorine ion (F−) can be visibly noted and the detection process of fluorine ion is relatively fast.
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TRANSACTIONS OF TIANJIN UNIVERSITY
·
2018
·Vol. 25
·期 2
·169-184
·
IF 0
Li Yingxia,Li Jiaxin,Yang Xiao,Wang Xitao,Xu Yanhong,Zhang Lihong
A series of PtCuCeMgAl quintuple hydrotalcite-like compounds with different Ce contents were synthesized by one-pot method. After calcining and reduction, CeO 2 -modified Mg(Al)O-supported Pt–Cu alloy catalysts were obtained. To understand the effect of Cu and Ce, the structure and physico-chemistry properties of the catalysts were characterized and analyzed, and the catalytic behaviors were investigated in a direct dehydrogenation of propane to propene. The results show that the Pt 4+ , Cu 2+ , and Ce 3+ ions can be incorporated into the brucite-like layers and the Ce content significantly affects the interaction strength between Pt and Cu and the dehydrogenation performance of propane. Under the reaction conditions, the highest propane conversion (45%) with 89% selectivity to propene and a 40% propene yield were achieved with a 0.3 wt% Ce-modified PtCu/Mg(Al)O catalyst. The improved catalytic performance is related to the easy formation of Pt–Cu alloy phase, excellent resistance to sintering, and coke deposits of active components modified by CeO 2 .
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SCIENCE OF THE TOTAL ENVIRONMENT
·
2016
·
IF 3.976
Hai-Ming Zhao,Huan Du,Jing Lin,Xue-Bin Chen,Yan-Wen Li,Hui Li,Quan-Ying Cai,Ce-Hui Mo,Hua-Ming Qin,Ming-Hung Wong
A newly isolated strain Agromyces sp. MT-O could utilize various phthalates and efficiently degraded di-(2-ethylhexyl) phthalate (DEHP). Response surface methodology was successfully employed for the optimization of culture conditions including pH (7.2), temperature (29.6), and inoculum size (OD 600 of 0.2), resulting in almost complete degradation of DEHP (200 mg L − 1 ) within 7 days. At different initial concentrations (50–1000 mg L − 1 ), DEHP degradation curves were fitted well with the first-order kinetic model, and the half-life of DEHP degradation ranged from 0.83 to 2.92 days. Meanwhile, the substrate inhibition model was used to describe the special degradation rate with q max , K s , and K i of 0.6298 day − 1 , 86.78 mg L − 1 , and 714.3 mg L − 1 , respectively. The GC–MS analysis indicated that DEHP was degraded into mono-ethylhexyl phthalate and phthalate acid before its complete mineralization. Bioaugmentation of DEHP-contaminated soils with strain MT-O has greatly enhanced DEHP disappearance rate in soils, providing great potential for efficiently remediating DEHP-contaminated environment.
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APPLIED CATALYSIS B-ENVIRONMENTAL
·
2024
·
IF 20.2
Beizhao Chen,Meng Zhang,Li Wang,Li Li,Qi Han,Xun Liu,Mengxia Wang,Bei Liu,Yi Jiang,Zhongying Wang
The singlet oxygen ( 1 O 2 )-based nonradical AOP process, realized in carbon materials after nitrogen and metal doping, has drawn much attention in recent years. However, the exclusive generation of 1 O 2 in the specialized two-dimensional (2D) catalytic membranes and the associated contaminant degradation mechanisms remain unclear. Herein, a Fe-doped crystalline carbon nitride (Fe-CCN) material without additional nitrogen doping was developed to preferentially initiate 1 O 2 -based nanoconfined oxidation of organic pollutants in the 2D Fe-CCN membrane/PMS system. Density functional theory calculation revealed that the Fe-O-N configuration formed after Fe doping altered the electronic structure of Fe centers, enhancing PMS adsorption and promoting the thermodynamically favorable generation of the –O* intermediate, leading to fast and highly selective 1 O 2 generation. EPR characterization and ROS quenching experiment also confirmed that the Fe-CCN activated PMS, generating nearly 100 % 1 O 2 . The Fe-CCN membrane/PMS system exhibited excellent resistance to natural organic matter (NOM) interference and dramatically increased Bisphenol A (BPA) degradation kinetics, approximately 590 times faster than in conventional batch systems. Enhanced 1 O 2 exposure concentration within the Fe-CCN membrane nanochannels was supported by EPR data and 1 O 2 exposure simulations. Furthermore, The Fe-CCN membrane/PMS system showed wide pH tolerance, excellent pollutant degradation performance, and high stability. This work underscores the practical significance of 1 O 2 -based oxidation reactions in membrane-confined AOPs for the rapid and efficient removal of organic contaminants from water.
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JOURNAL OF ALLOYS AND COMPOUNDS
·
2025
·
IF 6.3
Ting Xiang,Xiunan Cai,Zhongqiu Luo,Xintao Zhou,Cuirong Yan,Jinying Yu,Jiayi Ge,Yueying Li
Fe-based composites exhibit favorable photo-Fenton catalytic performance for environmental remediation, but restricted by high electron hole recombination rate, low reactivity, and instability. Herein, a strategy of mechanical activation-strengthened Mn doping was innovatively proposed to construct Fe 2 O 3 porous microspheres derived from copper slag (CS) base polymers (MA-Mn/CS-Fe 2 O 3 ), and used for highly efficient photo-Fenton degradation of chloromycin hydrochloride (CTC). Benefiting from the collision and shearing of mechanical forces, improved mechanical strength and defect-rich structure were realized in the porous microspheres. Experiments and DFT calculation results reveal that mechanical activation (MA) strengthened Mn to replace the cation vacancy sites and iron ion sites in the octahedron of Fe 2 O 3 , resulting in the formation of rich oxygen vacancies (O V ) and new electronic transmission channels of O V Fe Mn, which act as trapping sites to enhance carrier separation, accelerate the Fe 3 + /Fe 2+ redox cycle, and boost the generation and transformation of reactive oxygen species (ROS). The O V Fe Mn facilitates H 2 O 2 adsorption for its barrierless dissociation into •OH by forming a bridging Mn Fe O O Fe Mn bond. Moreover, the hollow porous structure provides confined space for organic degradation, reduces ROS migration distance, and improves light utilization. These specialties contribute to the superior performance of the MA-Mn/CS-Fe 2 O 3 /Vis/Fenton system for CTC removal (97.3 % within 45 min) in a wide pH range (3 −11), remaining above 93.1 % efficiency after five consecutive cycles. This environmentally-friendly method offers new insights into the harmless treatment and valorization of CS and large-scale production of catalyst.
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JOURNAL OF COLLOID AND INTERFACE SCIENCE
·
2025
·
IF 9.7
Chao Zhang,Yongsheng Gao,Haipeng Wang,Lulu Jiang,Delu Zhang,Shujun Ming,Guangying Fu,Chao Wang,Zhiguo Lv
The dry reforming of methane (DRM) could convert CH 4 and CO 2 into syngas, offering potential for greenhouse gas mitigation. However, DRM catalyst sintering and carbon deposition remain major obstacles. In this study, a highly dispersed PtNi alloy@Zr-doped 3D hollow flower-like MgAl 2 O 4 (AMO) spheres was prepared through a hydrophobic driving strategy. During a 50-hour test at 550 °C, the catalyst exhibited no significant decline in CH 4 and CO 2 conversion rates, demonstrating its excellent anti-sintering and anti-coking performance. The unique anti-coking performance can be attributed to Zr-induced oxygen vacancies, which enhance oxygen mobility and reduce carbon deposition. Besides, doped Zr increases basic active sites, enhancing CO 2 adsorption and activation, thus accelerating carbon species conversion. At 700 °C, the unique synergy between highly dispersed Pt and Ni enabled CH 4 and CO 2 conversion rates to reach 67.5 % and 73.8 %, respectively. The incorporation of Pt or Zr extends the Ni–Ni bond and partially coordinates with Ni, enhancing the stability of the Ni lattice. The reaction of CH 4 and CO 2 follows the Langmuir-Hinshelwood (L-H) mechanism, where both reactant molecules are adsorbed and activated on the metallic sites. Moreover, the effective energy barrier for the CH oxidation pathway is lower by 0.16 eV than that for the C oxidation pathway, which helps suppress the formation of carbon deposits.
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EUROPEAN POLYMER JOURNAL
·
2024
·
IF 5.8
Junyang Zhang,Wei Shi,Maoting Yang,Kaiping Huang,Yuanqiang Zhu,Zhengfeng Xie
With the continuous development of nuclear industry, the discharge of radioactive iodine ( 129 I and 131 I) become a potential danger to ecological environment. The development of high-performance iodine capture materials has important practical significance to reduce the harm of radioactive iodine. With the aim to construct new iodine-adsorbing polymer under the “bottom-up” structural designing guidance, using sulfur (S), branched polyethyleneimine (PEI) and 4,4’-oxybis(isocyanobenzene) (OBI) as starting substrates, a thiourea-modified PEI derivative (PEI-SIA) with abundant N/S/O-heteroatoms and aromatic molecular fragments was successfully prepared here via efficient sulfur-isocyanide-amine multicomponent polymerization (SIA-MCP). Characterization of PEI-SIA’s fundamental properties indicated that it is a new type of covalent organic polymer (COP). The iodine adsorption performance of PEI-SIA was systematically investigated. Experimental results showed that PEI-SIA can effectively adsorb iodine in steam (75 °C), cyclohexane, and aqueous phases, with the equilibrium adsorption capacities up to 6.48, 2.63, and 3.01 g g −1 , respectively. The iodine adsorption mechanism of PEI-SIA was characterized by experimental investigation and Density Functional Theory (DFT) calculation. The results revealed that PEI-SIA’s high iodine adsorption performance can be attributed to the synergistic effect brought by N/S/O-containing segments and the electron rich aromatic skeletons in PEI-SIA.
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ENVIRONMENTAL RESEARCH
·
2025
·
IF 7.7
Yehan Xiong,Bingchang Chen,Tiantian Xu,Yu Zhou,Pengcheng Gao,Jianguo Bao
Current research has found that C=O groups hold a significant position in the oxidation process of peroxymonosulfate (PMS) in the activated carbon system, influencing both the generation of reactive species and the degradation of organic contaminants. Quinone organic compounds, which are rich in C=O groups, exhibit high reactivity but also inherent toxicity. Additionally, these compounds decompose easily at high temperatures, complicating their use in carbon-based materials. This study introduces a novel approach to enhance the content of C=O groups in carbon materials by controlling the synthesis of sulfur heterocyclic organic quinone (SHQ) precursors. For the first time, we established a sulfur heterocyclic organic quinone-derived carbon (SHQC)/PMS system, where SHQC catalysts demonstrate remarkable catalytic efficiency in activating PMS for the degradation of organic pollutants. In different natural water matrices, the removal rate of tetracycline hydrochloride (TC) exceeds 90 % under optimized conditions (SHQC-9: 0.2 g L −1 , PMS: 1 mM, TC: 4.45 mg L −1 ). The C=O group was identified as the active site for PMS activation through a combination of quantitative structure-activity relationships, specific site blocking, and antithesis methods. The activation mechanism was elucidated through scavenger experiments and electron paramagnetic resonance (EPR) analysis. The results indicate that the superior catalytic performance of the SHQC-9/PMS system is due to a non-radical pathway, with singlet oxygen ( 1 O 2 ) being the primary species responsible for TC degradation. These findings offer a novel pathway for designing highly efficient, safe, and environmentally friendly carbon material catalysts.
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APPLIED SURFACE SCIENCE
·
2018
·
IF 4.439
Weiyuan Yao,Yue Liu,Zhongbiao Wu
A series of CeO 2 @Ce-O-P “multi-core@shell” catalysts were synthesized in this paper for selective catalytic reduction (SCR) of NO with NH 3 . The experimental results had showed that CeO 2 @Ce-O-P-30:3 yielded best SO 2 tolerance of an over 70% deNO x efficiency at 250 °C in the presence of 100 ppm SO 2 for 20 h, which was much higher compared to pure Ce-O-P and CeO 2 samples. Further characterization results indicated that Ce-O-P coating layer could somewhat inhibit sulfur depositing on the catalysts during SCR reaction in the presence of SO 2 , thereby protecting the active sites from SO 2 poisoning. Especially, O 2 -TPD results illustrated that a great amount of active oxygen species were retained on used CeO 2 @Ce-O-P catalyst after a long term reaction. The synergetic effect of “multi-core@shell” structure could be attributed to such enhanced performances. The “core” CeO 2 devoted abundant active oxygen sites to fulfill the SCR reaction. And the “shell” Ce-O-P could not only provide acid sites, but also protect the active oxygen species by avoiding the over-adsorption of SO 2 on the catalyst. This work could provide a new way to increase the sulfur resistance for low temperature SCR catalysts.
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LANGMUIR
·
2024
·
IF 3.7
Adugna Boke Abdeta,Feyisa Wedajo,Qinhan Wu,Dong-Hau Kuo,Ping Li,Hanya Zhang,Ting Huang,Jinguo Lin,Xiaoyun Chen
Cellulose plays a significant role in designing efficient and stable cellulose-based metallic catalysts, owing to its surface functionalities. Its hydroxyl groups are used as anchor sites for the nucleation and growth of metallic nanoparticles and, as a result, improve the stability and catalytic activity. Meanwhile, cellulose is also amenable to surface modifications to be more suitable for incorporating and stabilizing metallic nanoparticles. Herein, the Ag-/Bi-doped Mo(S,O)3 trimetallic sulfo-oxide anchored on B and N codoped cellulose (B–N–C) synthesized by a facile approach showed excellent stability and catalytic activity for PHER at 573.28 μmol/h H2 with 25 mg of catalyst under visible light, and 92.3% of the 4-nitrophenol (4-NP) reduction was achieved within 135 min by in situ-generated protons. In addition to B and N codoping, our use of the calcination method for B–N–C preparation further increases the structural disorders and defects, which act as anchoring sites for Ag-/Bi-doped Mo(S,O)3 nanoparticles. The Ag-/Bi-doped Mo(S,O)3@B–N–C surface active site also stimulates H2O molecule adsorption and activation kinetics and reduces the photogenerated charge carrier’s recombination rate. The Mo4+ → Mo6+ electron hopping transport and the O 2p and Bi 6s orbital overlap facilitate the fast electron transfer by enhancing the electron’s lifetime and photoinduced charge carrier mobility, respectively. In addition to acting as a support, B–N–C provides a highly conductive network that enhances charge transport, and the relocated electron in B–N–C activates the H2O molecule, which enables Ag-/Bi-doped Mo(S,O)3@B–N–C to have appreciable PHER performance.
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