JOURNAL OF ELECTROANALYTICAL CHEMISTRY
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2022
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IF 4.598
Xudong Zhao,Xiangxi Wang,Lei Chen,Xianglong Kong,Zhi Li,Ying Zhao,Zhuoyan Wu,Tingyu Wang,Zhiliang Liu,Piaoping Yang
Exploring low-cost and high-activity transition metal-based electrocatalysts for oxygen evolution reaction (OER) is critical toward mass hydrogen generation by water splitting. Herein, a cheap Fe element doped flower-like nickel sulfides catalyst (Fe-NiS/NiS 2 ) is designed and synthesized through facile electrostatic adsorption and sulfuration methods. It is investigated that the Fe doping effectively induces the lattice contraction of nickel sulfides and regulates the phase composition and heterogeneous interfaces, thus enabling high intrinsic OER activity. The Fe-NiS/NiS 2 catalyst shows a high electrochemically active surface area of 150 cm 2 , a small overpotential of 361 mV at 100 mA cm −2 and a low Tafel slope of 61.5 mV dec -1 . Furthermore, the Fe-NiS/NiS 2 exhibits a very excellent structure and performance stability without current attenuation for 24 h at 1.50 V versus reversible hydrogen electrode. This work provides an important insight for the exploitation of low-cost and high-performance OER catalysts with cheap Fe element doping metal sulfides.
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JOURNAL OF MOLECULAR STRUCTURE
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2022
·
IF 3.841
Wei Zhang,Yong-Zhuan Zhang,Ji-Min Yang
The separation of synthetic dyes from industrial wastewaters is an important objective in addressing water pollution. The removal of pollutant dyes from industrial wastewater prior to its release into the environment is an essential task; thus, synthesizing new adsorbent materials with superior adsorption efficiency is an important undertaking. Herein, we report the synthesis of MIL-100(Fe)@GO (graphene oxide) composites exhibiting superior adsorption performance toward methyl orange (MO), Congo red (CR), methylene blue (MB), and acid chrome blue K (AC). The room-temperature adsorption capacities of MIL-100(Fe)@GO-1 for these dyes were 533.7 (MB), 760.1 (MO), 1386.3 (AC), and 1786.6 (CR) mg g –1 , exceeding those values previously reported for pristine MIL-100(Fe) by 31.1%, 17.8%, 54.8%, and 8.9%, respectively. The adsorption behavior of the composites can be described on the basis of the structural and morphological characteristics and zeta potential of MIL-100(Fe)@GO and the adsorption capacity and structural characteristics of the dyes. The adsorption uptakes of MIL-100(Fe)@GO toward the pollutant dyes was controlled by the synergistic effects of the hydrogen-bonding, hydrophobic interactions, and π–π interactions and agglomeration pores of MIL-100(Fe)@GO. The obtained results revealed that the synergetic interplay of electrostatic, hydrogen-bonding, π–π, and hydrophobic interactions and adsorption space led to two distinct adsorption regimes for MO and AC depending on the adsorbate concentration.
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FUEL
·
2022
·
IF 8.035
Chengyan Wen,Ke Jin,Luying Lu,Qian Jiang,Jingcheng Wu,Xiuzheng Zhuang,Xinghua Zhang,Lungang Chen,Chenguang Wang,Longlong Ma
Direct conversion of syngas into aromatics (STA) on the tandem catalyst containing Fischer-Tropsch (F-T) synthesis catalysts and acid zeolites, especially Fe-based catalysts and ZSM-5, has been attracting significant attention due to the higher cost efficiency. Even though promoters have frequently been added into the Fe-based part to improve the performance of STA reaction, its motivating mechanism is still unclear in the tandem catalyst system. Herein, the influence of the Cu promoter was evaluated for the catalytic activity of Fe-based/zeolite tandem catalysts in the STA process. Moreover, the working mechanism of the Cu promoter had been systematically investigated by adding different copper amounts and deliberately designed experiments. It was demonstrated that the addition of copper could improve aromatic selectivity because the Cu promoter could facilitate CO to participate in the conversion of olefins into aromatics over the tandem catalyst. In addition, the Cu promoter doped into the Fe-based catalyst drastically suppressed methane formation and enhanced the stability of the catalyst in the STA reaction. These findings provide insights into the effect of the Cu promoter on producing aromatics from syngas over the Fe-based/zeolite tandem catalyst system.
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SEPARATION AND PURIFICATION TECHNOLOGY
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2022
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IF 9.136
Mingzhe Li,Wenli Yao,Min Yu,Changduo Sun,Xinquan Deng,Fengjuan Chen,Lei Zhou,Yian Zheng
Hydrogels possess 3D network with abundant reactive groups, and can bind with active metal ions within their confined 3D structure for fabricating functional materials . In this study, a chitosan grafted polyacrylic acid (CTS-g-PAA) hydrogel was prepared for loading Fe 2+ , which was then converted into magnetic Fe@C via subsequent pyrolysis process . In Fe@C activated peroxymonosulfate (PMS) (Fe@C/PMS) system, the degradation behaviors of ciprofloxacin (CIP) were systematically investigated, including influencing parameters, reactive oxygen species (ROSs), degradation mechanism and potential eco-toxicity of degradation intermediates. The results showed that CTS-g-PAA supported, in-situ derived magnetic Fe@C had not only stable catalytic ability at pH 3.0–9.0, but also high degradation efficiency in the presence of inorganic Cl − and HCO 3 − (5–20 mM) as well as organic humid acid (10 and 20 mg/L). Under the optimized conditions, the degradation efficiency of CIP could reach to 96.84 % within 1 h. In Fe@C/PMS system, the main ROSs involved free radicals SO 4 •− , •OH, O 2 •− and non-free radical 1 O 2 . Through free radical quantitative experiments, the concentration of SO 4 •− and •OH at 60 min was determined respectively to be 11.84 µM and 0.14 µM, proving the dominant role of SO 4 •− . By HPLC-MS analysis, the degradation products were proposed via four degradation pathways, including hydroxylation, defluorination and decarboxylation, as well as the ring opening of quinolone and piperazine. Finally, the potential eco-toxicity of CIP and its degradation intermediates was evaluated by using ECOSAR method based on quantitative structure–activity relationships analysis.
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SENSORS AND ACTUATORS B-CHEMICAL
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2022
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IF 9.221
Zhiwen Gan,Tian Zhang,Xuanxuan An,Qin Tan,Shujun Zhen,Xiaoli Hu
Numerous ratiometric fluorescence nanozyme sensors are developed, though, fluorescence-scattering ratiometric sensors based on nanozymes are hardly reported. First-order scattering (FOS) could be quenched due to inner filter effect of quenchers on scattering signals. Meanwhile, Second-order scattering (SOS) depended on FOS. Based on the principle, we designed a novel nanozyme sensor by coupling fluorescence (FL) and SOS. Specifically, Fe-N-C nanozyme (Fe-HCNP) was fabricated by doping Fe into carbon-nitrogen polymers via formamide condensations . Fe-HCNP possessed robust oxidase-like activity, effectively transforming O 2 into ·O 2 - and ·OH. Then, Fe-HCNP and o-phenylenediamine (OPD) severed as a hybrid system to construct an FL-SOS ratiometric sensor for ascorbic acid (AA). Fe-HCNP with large size possessed strong SOS. After being added into the Fe-HCNP/OPD system, AA could fast be oxidized to dehydroascorbic acid (DAA) due to Fe-HCNP as oxidase mimics. Subsequently, fluorescent quinoxaline derivative (DFQ) was produced after condensation reactions between DAA and OPD, causing an increase in fluorescence. Meanwhile, the intensity of FOS was reduced because FOS peaks of Fe-HCNP overlapped absorption bands of DFQ, causing a decrease in SOS. The FL-SOS ratiometric sensor for AA showed outstanding advantages of high specificity and fast. Overall, this work provided a new strategy for nanozyme ratiometric sensors.
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MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING
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2022
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IF 4.644
Meng Tan,Qiaoyuan Gao,Yangjie Fu,Youran Xu,Derek Hao,Bing-Jie Ni,Qi Wang
In this study, a new coordination polymer of Fe-2-methylimidazole (Fe-2MI) was successfully loaded onto F-doped tin oxide (FTO) via a one-pot solvothermal method, using Fe(NO 3 ) 3 and 2MI as raw materials. For X-ray diffraction patterns (XRD) and scanning electron microscope (SEM) analysis, it can be deduced that Fe-2MI assembles were evenly dispersed on the surface of FTO, and were partially encapsulated by tiny FeOOH particles. The as-prepared Fe-2MI film electrode was used as photoanode with titanium sheet (Ti) as the cathode. Simultaneous photoelectrocatalytic (PEC) removal of phenol and Cr(VI) can be effortlessly accomplished under noticeable light illumination. Meanwhile, the impact of initial Fe state was also investigated. Fe-2MI prepared with Fe(III) behaved better PEC performance than that with Fe(II). Furthermore, the Fe-2MI photoanodes were optimized by adjusting the initial concentration of Fe(III) and 2MI precursors. Besides, the application conditions were optimized at acidic pHs and 2.5 V bias voltage . Cr(VI) can be completely reduced with 80% removal of phenol after 5 h PEC reaction. After 5 successive cyclic runs, stable photocatalytic performance can still be observed. Therefore, Fe-2MI coordination polymer can be a promising candidate for preparing visible-light-active photoanode in the application of environmental remediation.
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FOOD CHEMISTRY
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2022
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IF 9.231
Wenzhi Tang,Yangchun Qi,Xuewei Yang,Jianlong Wang,Zhonghong Li
A multi-channel colorimetric device was developed for the low-cost and simultaneous determination of three important parameters in wine safety and quality— total iron (Fe), methanol (MeOH), and total phenols. The detection was performed by assembling light-dependent resistors and light-emitting diodes in a 3D printed chamber, which measured colorimetric signals horizontally transmitting through the microwells of an 8-well strip. This device demonstrated linear relationships (R 2 greater than 0.99) for all analytes with detection limits of 0.04 mg/L, 2.26 mg/L, and 3.40 mg/L for Fe, MeOH, and total phenols, respectively. Wine sample measurements showed that the multi-channel device was as accurate as the professional spectrophotometer and could simultaneously provide the three target concentrations to facilitate the analysis. With the merits of low fabrication cost and ease of use, this device could be used as a general platform for multiple-target detection, demonstrating great potential for application in food analysis.
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COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
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2022
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IF 5.518
Ming Xiao,Ruixue Li,Jinglin Yin,Junhui Yang,Xinyu Hu,Hongbo Xiao,Wenlei Wang,Ting Yang
The treatment of arsenite pollution in water has always been concerned. Oxidation of high toxic As(III) to relatively low toxic As(V) by efficient photocatalytic oxidation technology is a research hotspot. This paper is focused on the active photocatalyst of TiO 2 @Fe 3 O 4 composites synthesized by a simple hydrothermal method for the efficient photocatalytic oxidation of As(Ⅲ). The successful construction of Ti–O–Fe interface bonds between TiO 2 and Fe 3 O 4 significantly promoted the transfer efficiency of photo-generated carriers, and further rapidly improved the photocatalytic oxidation efficiency of As(Ⅲ). The application results showed that the constructed TiO 2 @Fe 3 O 4 photocatalyst with 0.10 g Fe 3 O 4 (TF-0.10) could complete the transformation from As(Ⅲ) (10,000 μg/L) to As(Ⅴ) within 4 min with a high oxidation ratio of 100% and maintained the good properties with unchanged crystal structure after five cycles. Furthermore, the photocatalytic properties of TiO 2 @Fe 3 O 4 composites were still stable under different pH values. Electron paramagnetic resonance (EPR) consequence displayed that the superoxide radical (‧O 2 — ) and hole (h + ) were the main intermediate product in the arsenic photocatalytic oxidation system, and hydroxyl radical (‧OH) had little effect on this oxidation system. The possible mechanism of As(Ⅲ) photocatalytic conversion was further explored based on the results of the data analysis. Furthermore, this work provides a potential new idea for the practicability of efficient photocatalytic arsenic oxidation.
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CHEMICAL RESEARCH IN CHINESE UNIVERSITIES
·
2022
·Vol. 39
·期 2
·219-223
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IF 2.726
Xiao Long,Wu Huirong,Zhang Yong,Sun Hao,Zhang Wenchao,Lyu Fenglei,Deng Zhao,Peng Yang
O xygen evolution reaction(OER) plays a key role in the electrochemical conversion and storage processes, but the sluggish kinetics of OER strongly impedes its large-scale applications. We herein reported the in situ growth of Fe-benzenedicarboxylate(Fe-BDC) on Co(OH) 2 nanoplates[Fe-BDC/Co(OH) 2 ] that showed remarkably enhanced OER activity than the pristine Co(OH) 2 . The incorporation of Fe species could enhance the intrinsic OER activity of Co and BDC could increase the electrochemically active surface area(ECSA), thus resulting in dramatically enhanced OER activity. In situ Raman spectroscopy characterization disclosed that Fe-CoOOH reconstructed from Fe-BDC/Co(OH) 2 was the real active site for OER. This work highlights the significance of rational tailoring of the nanostructure and electronic structure of Co(OH) 2 and provides more opportunities for its widespread applications.
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ChemPlusChem
·
2022
·Vol. 87
·期 10
·e202200312
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IF 3.21
Yujun Wang,Rongxiu Tu,Chuantao Hou,Zonghua Wang
Graphical A porous Fe−N−C aerogel catalyst was synthesized by pyrolysis of porous metal-organic aerogels. The Fe−N−C aerogel shows enhanced catalytic performance for oxygen reduction reaction (ORR) under alkaline condition. The markedly enhanced ORR performance for Fe−N−C aerogel can be assigned to the synergistic catalytic effect between Fe−N catalytic sites and graphitized carbon and excellent mass transport due to the unique hierarchically porous architecture. Synthesis of Fe−N−C electrocatalysts by pyrolysis of porous materials has been shown to be a promising pathway for the oxygen reduction reaction (ORR). Metal-organic aerogels (MOAs) with unique micropores and mesopores should provide an excellent precursor for Fe−N−C electrocatalysts. This work reports a Fe−N−C aerogel synthesized by pyrolysis of MOA. The Fe−N−C aerogel shows excellent ORR performance in alkaline condition with an onset potential of 0.96 V (vs. RHE) and a limiting current density of 5.02 mA cm −2 . The markedly enhanced ORR performance for Fe−N−C aerogel can be assigned to the synergistic catalytic effect between Fe−N catalytic sites and graphitized carbon and excellent mass transport due to the unique hierarchically porous architecture. In addition, satisfactory durability and methanol tolerance were obtained, demonstrating a promising material for ORR.
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JOURNAL OF ALLOYS AND COMPOUNDS
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2022
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IF 6.371
He Zhang,Jun-Ru Liu,Guo-Hua Zhang
In this paper, excellent performance W-Cu-Ni-Fe alloys with the addition of Ni and Fe (total content: 5 wt%) were successfully prepared by low temperature liquid-phase sintering, using the raw material of ultrafine W-Cu-Ni-Fe composite powder. Ultrafine W-Cu-Ni-Fe composite powder with high sintering activity and uniform composition distribution was prepared by a two-stage reduction method consisting of carbothermal reaction and hydrogen deep deoxidation. Additions of Ni and Fe not only improved the wettability between W and Cu two phases, but also improved the bonding strength of two-phase interface. All sintered samples had higher relatively densities to ensure that the samples have great comprehensive properties. When Ni and Fe were co-added in appropriate proportions, the highest tensile strength and elongation of W-Cu-Ni-Fe alloy samples were 497 MPa and 9.12 % for the composition: W-3.5 wt%Ni-1.5 wt%Fe-25 wt%Cu, respectively. Meanwhile, with increasing Ni content from 0 wt% to 5 wt%, the compressive strength and failure strain of alloy samples increased from 1160 MPa to 2376 MPa and from 53 % to 98 %, respectively. In addition, with the enhancement of the solid solution strengthening effects of Ni and Fe on Cu matrix, the bending strength and microhardness of the alloy samples increased to 1174 MPa and 361 HV for composition: W-3.5 wt%Ni-1.5 wt%Fe-25 wt%Cu, respectively. Although the additions of Ni and Fe made the Cu matrix network structure have a uniform distribution, it led to a decrease in the electron transfer ability of the alloy, and thus, there was a decrease in electrical conductivity .
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SCIENCE OF THE TOTAL ENVIRONMENT
·
2021
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IF 7.963
Jiayi Luo,Yunqiang Yi,Guangguo Ying,Zhanqiang Fang,Yifeng Zhang
The content of active components in magnetic biochar, especially Fe(II), is closely related to its activation performance. Therefore, improving Fe(II) content in magnetic biochar is an ideal strategy to enhance the activation performance of magnetic biochar. In this study, the potassium-doped magnetic biochar was prepared and employed to activate persulfate for degradation of metronidazole. The degradation efficiency of metronidazole in potassium-doped magnetic biochar/persulfate system was 98.4%, which was 13.1 times higher than that in magnetic biochar/persulfate system. Free radicals quenching experiments and electron spin resonance analyses confirmed that surface-bound free radicals were responsible for metronidazole degradation followed the order of 1 O 2 > ·OH > SO 4 · - > O 2 · − . The doping of magnetic biochar with potassium increased its Fe(II) content, approximately 3.1 times higher than that of pristine magnetic biochar. The differences in Fe(II) content between potassium-doped magnetic biochar and magnetic biochar were the key reasons for the activation performance differences. Based on the ultra-high pressure liquid chromatography-quadrupole tandem time-of-flight mass spectrometer , the primary degradation intermediates of metronidazole were identified, and possible degrading pathways were proposed. Overall, this work provides an effective strategy to improve the activation performance of magnetic biochar.
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