AICHE JOURNAL
·
2019
·Vol. 66
·期 2
·e16841
·
IF 3.463
Chong Shen,Minjing Shang,Hong Zhang,Yuanhai Su
In this work, we report a simple and inexpensive UV-LEDs based photomicroreactor assembly constructed by commercially available components. The photoisomerization of norbornadiene to quadricyclane was selected to validate this novel photomicroreactor design. Mass transport limitation was eliminated and indicated by dimensionless numbers Fo and Da II , and photons loss was evaluated considering the absorption and reflection of the microreactor walls. The solvents, photosensitizers, and light sources selections were optimized for achieving better photochemical performance and mechanistic insights. The detailed comparison between the high-pressure mercury arc lamp and the UV-LEDs strip revealed great potential of UV-LEDs as appealing light source for photochemical transformations. Moreover, the reaction mechanism was thoroughly discussed and illustrated by the Jablonski diagram indicating electronic states transitions. According to possible intermediate steps, a kinetic model was proposed with the reaction rate constant being correlated with the photon flux, which is valuable for process optimization and further understanding reaction mechanisms.
研究领域:
化学工程
·
光化学
·
反应动力学
✓ 已验证
DOI
高影响因子
Optical Materials Express
·
2020
·Vol. 10
·期 10
·2480-2490
·
IF 3.064
Meng Wang,Meng Wang,Meng Wang,Shaolong Huang,Yu-Jia Zeng,Ruqing Huang,Dalin Sun,Meng Wang,Jihong Pei,Shuangchen Ruan,Shuangchen Ruan
Wideband optical saturable absorbers (SA) are an ideal laser component for pulse laser generation in different wavelengths, which has attracted tremendous attention in recent years. Herein, a MoO3-x-based novel wideband optical SA has been demonstrated by utilizing it for ∼1/1.5/2 μm Q-switched pulses generation. After separately integrating the MoO3-x-SA into Yb-, Er- and Tm-doped fiber lasers, passively Q-switched pulses with pulse durations of ∼1.5/2.2/1.6 μs, repetition rates of several tens kilohertz at corresponding wavelengths of ∼1038/1562.9/1910 nm are obtained. Our work firstly reveals the remarkable wideband optical saturable absorption of the MoO3-x, which strongly implies the potential application in infrared photonics devices. It may also provide new opportunities for wideband optical SA based on oxygen-deficient metal oxides.
研究领域:
光学
·
材料科学
·
激光技术
✓ 已验证
DOI
高影响因子
DYES AND PIGMENTS
·
2018
·
IF 3.767
Peng Li,Linna Guo,Zongxue Zhang,Tiesheng Li,Penglei Chen
A series of Bi 2 O 3 :Yb 3+ /Er 3+ phosphors with different phases and morphologies were obtained by tuning doping ions, which played a vital role in the upconversion luminescence (UCL). Both Er 3+ single doped and Yb 3+ /Er 3+ co-doped samples exhibit narrow, nearly pure red emission whether excited by 980 nm or 1550 nm. Compared to the sum of emission intensities excited by two single-wavelength (980 nm and 1550 nm) separately, the red emission from Bi 2 O 3 :Yb 3+ /Er 3+ with uneven distributed nanometer or micron blocky particles structure excited by two-wavelength simultaneously was enhanced by a factor of 2.41. To further improve the UCL intensity, optical-inert ions such as Na + , Ca 2+ and Gd 3+ were doped into this system. Compared to the optical-inert ions free sample (Bi 2 O 3 :15% Yb 3+ , 2% Er 3+ ), the pure red UCL in Bi 2 O 3 :15% Yb 3+ , 2% Er 3+ with 6% Na + , 2% Ca 2+ and 4% Gd 3+ doping is enhanced by 223.83 or 203.73 times under 980 or 1550 nm excitation, respectively. Meanwhile, the UCL mechanism under the multiwavelength was investigated in detail and its model of UC emission process was proposed.
研究领域:
材料科学
·
光学
✓ 已验证
DOI
高影响因子
OPTICS LETTERS
·
2015
·Vol. 40
·期 15
·3576-3579
·
IF 3.292
Jin-hui Chen,Guo-qing Deng,Shao-cheng Yan,Cheng Li,Kai Xi,Fei Xu,Yan-qing Lu
Based on the liquid exfoliated method, we obtained the few-layer molybdenum disulfide (MoS2) nanoplates solution. By thermal evaporation method, we directly deposited MoS2 thin film onto the facet of a fiber patch cord. The modulation depth of the film is as high as 29%, and a Q-switched fiber laser was achieved. We also provided a new method to continuously tune the output laser with a tuning sensitivity of ∼5.5 nm/(1% strain) by controlling the cavity loss with a strained microfiber coupler (MFC).
研究领域:
光学
·
材料科学
✓ 已验证
DOI
PubMed
高影响因子
JOURNAL OF POLYMER RESEARCH
·
2022
·Vol. 29
·期 4
·1-9
·
IF 3.061
Zhang Andong,Hao Jingyi,Hou Sen,Shi Ge,He Yanjie,Cui Zhe,Liu Minying,Qiao Xiaoguang,Fu Peng,Pang Xinchang
Aggregation-induced emission (AIE) has already been applied for in-situ monitoring living radical polymerization process. Here we utilized functionalized monomer TPEE as fluoresce probes for the in-situ monitoring of photo-induced RAFT-PISA process. Hydrophilic POEGA macro chain transfer agent (Macro-CTA) was first prepared with light sensitive CTA 4-Cyanopentanoic acid dithiobenzoate, and (2-(4-vinylphenyl)ethene-1,1,2-triyl)tribenzene (TPEE) was copolymerized with styrene to form the hydrophobic block under UV irradiation. The growth of hydrophobic block induced the self-assembly of polymer chains and the emission signal could be observed by naked eyes afterwards. The PL intensity increased with the increase of particle size, as well as the monomer conversion and molecular weight, owing to the enhancement of AIE monomer in the self-assembly latex particles. This no-invasive and facile approach to in-situ visualization and continuously monitoring of the photo-induced RAFT-PISA process might be helpful for both scientific research and commercial application.
研究领域:
高分子化学
·
材料科学
✓ 已验证
DOI
高影响因子
RSC Advances
·
2021
·Vol. 11
·期 25
·14957-14969
·
IF 3.361
Chentao Hou,Huayang Liu,Yijie Li
A kind of high-efficiency photocatalyst of the three-dimensional flower-like TiO2/TiOF2 was synthesized by a one-step hydrothermal method. XRD, FE-SEM, EDS, HTEM, BET, XPS, PL, and UV-Vis-DRS were utilized to characterize the photocatalyst. The photocatalyst of TiO2/TiOF2 shows a narrow band gap of 2.8 eV. The generation of Ti3+ and an oxygen vacancy (Ov) in the photocatalyst are helpful to increase the absorption of visible light, and to inhibit faster charge recombination by capturing photogenerated carriers. Through the degradation of tetracycline hydrochloride (TCH) under simulated sunlight, the photocatalytic activity and stability of the synthesized samples were investigated. The results showed that the removal rate of tetracycline hydrochloride was 59% only in 0.5 h of dark reaction and 85% in 0.5 h of simulated sunlight. The removal efficiency of the photocatalyst for the adsorption and photocatalytic degradation of TCH is higher than that of the single TiO2, TiOF2, and Degussa P25. The synthesized three-dimensional flower-like TiO2/TiOF2 has great application potential in the treatment of antibiotic wastewater.
研究领域:
材料科学
·
环境科学
✓ 已验证
DOI
高影响因子
ELECTROPHORESIS
·
2015
·Vol. 36
·期 20
·2509-2515
·
IF 3.028
Haiyun Zhai,Kaisong Yuan,Xiao Yu,Zuanguang Chen,Zhenping Liu,Zihao Su
A novel fluorescence detection system for CE was described and evaluated. Two miniature laser pointers were used as the excitation source. A Y-style optical fiber was used to transmit the excitation light and a four-branch optical fiber was used to collect the fluorescence. The optical fiber and optical filter were imported into a photomultiplier tube without any extra fixing device. A simplified PDMS detection cell was designed with guide channels through which the optical fibers were easily aligned to the detection window of separation capillary. According to different requirements, laser pointers and different filters were selected by simple switching and replacement. The fluorescence from four different directions was collected at the same detecting point. Thus, the sensitivity was enhanced without peak broadening. The fluorescence detection system was simple, compact, low-cost, and highly sensitive, with its functionality demonstrated by the separation and determination of red dyes and fluorescent whitening agents. The detection limit of rhodamine 6G was 7.7 nM (S/N = 3). The system was further applied to determine illegal food dyes. The CE system is potentially eligible for food safety analysis.
研究领域:
分析化学
·
生物医学工程
·
食品安全
·
分子检测技术
✓ 已验证
DOI
高影响因子
Journal of Materials Chemistry B
·
2017
·Vol. 5
·期 26
·5128-5136
·
IF 4.543
Yike Fu,Heng Liu,Zhaohui Ren,Xiang Li,Jie Huang,Serena Best,Gaorong Han
Photodynamic therapy (PDT) and photothermal therapy (PTT) have been explored widely for application in cancer treatment. In this work, we describe the synthesis of CaTiO3:Yb,Er (CTO) nanofibers co-conjugated with Rose Bengal (RB) and gold nanorods (AuNRs), which offer the potential for combined upconversion photoluminescence (UCPL) and enhanced, synergistic PDT and PTT. Based on this delivery platform, RB and AuNRs served as the PDT and PTT agents, respectively. RB and AuNRs have strong and well-matched absorption with the green and red emissions of UCPL CTO nanofibers respectively, hence a single 980 nm continuous wave laser with deep tissue penetration can be employed to allow PDT and PTT to occur simultaneously. The nanocomposite can effectively convert the near-infrared (NIR) radiation from the laser into a combination of targeted hyperthermia and generation of reactive oxygen species (ROS). In comparison with PDT or PTT alone, the combined PDT/PTT treatment showed significantly enhanced suppression of the viability of Hep G2 cells in vitro, demonstrating its potential for use in oncology.
研究领域:
肿瘤学
·
生物医学工程
·
纳米医学
·
光动力治疗
·
光热治疗
✓ 已验证
DOI
高影响因子
POWDER TECHNOLOGY
·
2020
·
IF 4.142
Yong Yang,Heng Pan,Xiaocui Zhang,Tongyu He,Zhuo Hou,Zhiping Yang,Dawei Wang,Li Guan,Xu Li
Cubic phase Ca 9-x Al 6 O 18 :xEu 3+ red phosphors have been successfully fabricated using the hydrothermal assisted solid state method. The atomic site occupation of the matrix, morphology, luminescent properties, quenching mechanisms, and thermal stabilities are investigated. The possible sites of Eu 3+ in a matrix crystal lattice are investigated via formation energy using first principle calculations . Under 395 nm excitation, Ca 9-x Al 6 O 18 :xEu 3+ shows a red emission at 618 and orange emission at 594 nm and the optimal Eu 3+ ion concentration is x = 0.06. The effect of the reaction solution composition on the morphology and emission spectra are investigated using SEM and photoluminescence (PL) spectrum measurements. The results reflect that the samples have different morphologies in different reaction solutions. Additionally, the PL intensities of Ca 8.94 Al 6 O 18 :0.06Eu 3+ decreased to 80.6% as the temperature increased from room temperature to 150 °C. Ca 9 Al 6 O 18 :Eu 3+ phosphors may potentially be used for white LEDs.
研究领域:
材料科学
·
光学
✓ 已验证
DOI
高影响因子
CERAMICS INTERNATIONAL
·
2022
·
IF 5.532
Yong Liu,Shuai Cheng,Shengchun Yang,Zongtao Li,Zhenjuan Duan,Zhanjiang Hu,Zhengui Li,Yuehua Li,Lili Yu,Anzhong Peng,Xiaodong Wen
A series of Mn 4+ doped cubic phase Cs 2 KInF 6 red phosphors (abbreviated here as CKIFM) were obtained through a typical co-precipitation route. The optical and structural properties of this material were researched in more detail using X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence (PL) and photoluminescence excitation (PLE), diffuse reflectance spectroscopy (DRS), temperature-dependent PL and lifetimes. Interestingly, the as-prepared CKIFM phosphors have a strong and broad absorption band in the blue area with a peak at 468 nm, and bright narrow-band red fluorescence with high colour purity. Furthermore, the optimum quenching concentration, crystal field parameters (CFPs), internal quantum efficiency (IQE), and the corresponding concentration quenching mechanism are discussed and analyzed in detail. Finally, the WLED backlight using the obtained CKIFM red-emitting phosphor and β-SiAlON:Eu 2+ (β-Sialon:Eu 2+ ) green-emitting phosphor demonstrates a wide color gamut (∼101.7% National Television System Committee standard (NTSC)), revealing the title phosphor is an attractive red component for backlight displays.
研究领域:
材料科学
·
光学
✓ 已验证
DOI
高影响因子
ACS Applied Materials & Interfaces
·
2021
·
IF 9.229
Hui Peng,Xinxin Wang,Ye Tian,Bingsuo Zou,Fan Yang,Tao Huang,Chengyu Peng,Shangfei Yao,Zongmian Yu,Qingrong Yao,Guanghui Rao,Jianping Wang
Zero-dimensional lead-free organic–inorganic hybrid metal halides have drawn attention as a result of their local metal ion confinement structure and photoelectric properties. Herein, a lead-free compound of (Gua)3Cu2I5 (Gua = guanidine) with a different metal ion confinement has been discovered, which possesses a unique [Cu2I5]3– face-sharing tetrahedral dimer structure. First-principles calculation demonstrates the inherent nature of a direct band gap for (Gua)3Cu2I5, and its band gap of ∼2.98 eV was determined by experiments. Worthy of note is that (Gua)3Cu2I5 exhibits a highly efficient cool-white emission peaking at 481 nm, a full-width at half-maximum of 125 nm, a large Stokes shift, and a photoluminescence quantum efficiency of 96%, originating from self-trapped exciton emission. More importantly, (Gua)3Cu2I5 single crystals have a reversible thermoinduced luminescence characteristic due to a structural transition scaled by the electron–phonon coupling coefficients, which can be converted back and forth between cool-white and yellow color emission by heating or cooling treatment within a short time. In brief, as-synthesized (Gua)3Cu2I5 shows great potential for application both in single-component white solid-state lighting and sensitive temperature scaling.
研究领域:
材料科学
·
光学
✓ 已验证
DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
·
2021
·
IF 13.273
Jiawei Jiang,Peisheng Zhang,Le Liu,Yuqi Li,Yubin Zhang,Tiancheng Wu,Helou Xie,Chonghua Zhang,Jiaxi Cui,Jian Chen
Stimuli-responsive fluorescent materials that can alternate their emission states on-demand are always desired in many applications. In this study, novel photoswitchable multistate fluorescent polymer (PMFP) was prepared via simple free-radical copolymerization of butyl acrylate (BA) and styrene (St) with two photochromic fluorescent monomers, i.e. sulfonyl diarylethylene-linked 4-hydroxybutyl acrylate (SDTE) and spiropyran-linked methacrylate (SP8). The PMFP displays excellent processability, due to its rational feed ratio of BA and St which result in the relative low glass transition temperature. By changing irradiation light, the non-fluorescent ring-closed spiropyran units and ring-opened diarylethylene moieties in PMFP can be selectively converted into their corresponding luminescence states. Furthermore, as a result of the controllable fluorescence resonance energy transfer (FRET) from the excited diarylethylene to the spiropyran moieties, the emission of the polymer in solution or film can be reversibly switched among distinguishable no-emission, red, and green fluorescence states. Moreover, the PMFP exhibits high brightness, high contrast, rapid photoresponse, and excellent photoreversibility. We also demonstrated that PMFP can be directly used for advanced high-density data storage, multilevel information encryption, and multicolor photorewritable pattern, as well as high-level anticounterfeiting.
研究领域:
材料科学
·
光学
·
信息存储技术
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）